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Ultrasound-Assisted Synthesis of Novel Nano 3D Supramolecular Lead(II) Metal–Organic Coordination System: A New Precursor to Produce Nano Lead Oxide

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Abstract

Novel nanorods of a lead(II) 3D metal–organic coordination system {[Pb(μ2-NO3)4].(hmta)2.H2O}n (1) (hmta = hexamethylenetetramine) were synthesized by a sonochemical method. The new nanostructure was characterized using scanning electron microscopy, X-ray photoelectron spectroscopy, X-ray powder diffraction, elemental analysis, and thermogravimetric analysis. The single-crystal X-ray structure shows that 1 is a three dimensional (3D) coordination compound. This is further self-assembled into a 3-D supramolecular structure by weak directional intermolecular interactions. The coordination number of the Pb(II) ions is eight (PbO8). PbO nanoparticles were obtained by the thermolysis of 1 at 180 °C using oleic acid as a surfactant. The average diameter of the nanoparticles was estimated by the Scherrer equation to be 30 nm. The morphology and size of the prepared PbO samples were also observed using SEM.

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Acknowledgements

The authors thank the University of Qom for all their support. This work was funded by the grant NRF-2015-002423 of the National Research Foundation of Korea. We also thank Dr. Jalil Assoud and the University of Waterloo for crystallography of the structure.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Qom, P.O. Box 37185-359, Qom, Iran

    Babak Mirtamizdoust & Mohamadhasan Nazari

  2. School of Mechanical Engineering, WCU Nano Research Center, Yeungnam University, Gyeongsan, 712-749, South Korea

    Younes Hanifehpour & Sang Woo Joo

  3. Department of Chemistry, University of Waterloo, Waterloo, ON, N2L 3G1, Canada

    Jalil Assoud

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  1. Babak Mirtamizdoust
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  2. Younes Hanifehpour
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  5. Sang Woo Joo
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Correspondence to Babak Mirtamizdoust, Younes Hanifehpour or Sang Woo Joo.

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Mirtamizdoust, B., Hanifehpour, Y., Nazari, M. et al. Ultrasound-Assisted Synthesis of Novel Nano 3D Supramolecular Lead(II) Metal–Organic Coordination System: A New Precursor to Produce Nano Lead Oxide. J Inorg Organomet Polym 27, 827–834 (2017). https://doi.org/10.1007/s10904-017-0528-6

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