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Ultrasound-Assisted Synthesis of a Novel Nano-Zigzag-Pattern Lead (II) Metal–Organic System: A New Precursor to Produce Nano-Sized PbO

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Abstract

A sonochemical method was used to synthesize a new nano Pb(II) 1D metal–organic zigzag chain [Pb(p-2-einh)NO2]n (1) (p-2-einh = (1-(pyridin-2-yl)ethylidene)isonicotinohydrazide). The compound was characterized by scanning electron microscopy (SEM), transmission electron microscopy, elemental analysis, IR spectroscopy, thermogravimetric analysis, X-ray powder diffraction, and single-crystal X-ray analysis. The X-ray analysis reveals a 1D zigzag-chain metal–organic polymer structure for 1 that is further extended to a 3D supramolecular structure by—interaction and other labile interactions. A coordination number of six was determined for the Pb(II) ions in PbN3O3. Lead oxide nanoparticles were prepared at 180 °C by thermolysis of 1. The average diameter of the nanoparticles was 20 nm. The size and morphology of the PbO samples were observed using SEM, and the structure of the system was optimized by DFT calculations. The calculated structural parameters and FT-IR spectra are consistent with the crystal structure.

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Notes

  1. A description of the basis sets and theory level used in this work can be found in the following: [42].

References

  1. R. Chakrabarty, P.S. Mukherjee, P.J. Stang, Chem. Rev. 111, 6810 (2011)

    Article  CAS  Google Scholar 

  2. A. Erxleben, Coord. Chem. Rev. 246, 203 (2003)

    Article  CAS  Google Scholar 

  3. C.L. Cahill, D.T. de Lill, M. Frisch, CrystEngComm. 9, 15 (2007)

    Article  CAS  Google Scholar 

  4. A. Morsali, L.-G. Zhu, Helv. Chim. Acta 89, 81 (2006)

    Article  CAS  Google Scholar 

  5. S.R. Batten, S.M. Neville, D.R. Turner, Coordination Polymers: Design, Analysis and Application (Royal Society of Chemistry, Cambridge, 2009)

    Google Scholar 

  6. C. Janiak, Dalton Trans. 2003, 2781

  7. K. Akhbari, A. Morsali, Dalton. Trans. 42, 4786 (2013)

    Article  CAS  Google Scholar 

  8. T. Uemura, S. Kitagawa, Chem. Lett. 34,132 (2005)

    Article  CAS  Google Scholar 

  9. N. Soltanzadeh, A. Morsali, Ultrason. Sonochem. 17, 139 (2010)

    Article  CAS  Google Scholar 

  10. H. Sadeghzadeh, A. Morsali, CrystEngComm. 12, 370 (2010)

    Article  CAS  Google Scholar 

  11. W. Lu, S.S.-Y. Chui, K.-M. Ng, C.-M. Che, Angew. Chem.Int. Ed. 47, 4568 (2008)

    Article  CAS  Google Scholar 

  12. L. Shimonni-Livny, J.P. Glusker, C.W. Bock, Inorg. Chem. 37, 1853 (1998)

    Article  Google Scholar 

  13. J. Parr, Polyhedron 16, 551 (1997)

    Article  CAS  Google Scholar 

  14. S. Sobanska, J. P. Wignacourt, P. Conflant, M. Drache, M. Lagrenee, E.M. Holt, New J. Chem. 23, 393 (1999)

    Article  CAS  Google Scholar 

  15. E.J. Baran, C.C. Wagner, M. Rossi, Z.F. Caruso, Anorg. Allg. Chem. 626, 701 (2000)

    Article  CAS  Google Scholar 

  16. B. Mirtamizdoust, Z. Trávníček, Y. Hanifehpour, P. Talemi, H. Hammud, S.W. Joo, Ultrason. Sonochem. 34, 255 (2015)

    Article  Google Scholar 

  17. B. Mirtamizdoust, D. Bieńko, Y. Hanifehpour, E.R.T. Tiekink, V.T. Yilmaz, P. Talemi, S.W. Joo, J. Inorg. Organomet. Polym. 26, 819 (2016)

    Article  CAS  Google Scholar 

  18. A. Valipour, B. Mirtamizdoust, M. Ghaedi, F. Taghizadeh, P. Talemi, J. Inorg. Organomet. Polym. 26, 197 (2016)

    Article  CAS  Google Scholar 

  19. B. Shaabani, B. Mirtamizdoust, D. Viterbo, G. Croce, H. Hammud, P. Hojati-Lalemi, Z.A. Khandar, Anorg. Allg. Chem. 637, 713 (2011)

    Article  CAS  Google Scholar 

  20. B. Mirtamizdoust, B. Shaabani, S.W. Joo, D. Viterbo, G. Croce, Y. Hanifehpour, J. Inorg. Organomet. Polym. 22, 1397 (2012)

    Article  CAS  Google Scholar 

  21. B. Shaabani, B. Mirtamizdoust, M. Shadman, H.K. Fun, Z. Anorg. Allg. Chem. 635, 2642 (2009)

    CAS  Google Scholar 

  22. B. Mirtamizdoust, B. Shaabani, A. Khandar, H.K. Fun, S. Huang, M. Shadman, P. Hojati-Talemi, Z. Anorg. Allg. Chem. 638, 844 (2012)

    Article  CAS  Google Scholar 

  23. Y. Hanifehpour, B. Mirtamizdoust, S.W. Joo, J. Inorg. Organomet. Polym. 22, 916 (2012)

    Article  CAS  Google Scholar 

  24. Y. Hanifehpour, B. Mirtamizdoust, A.R. Farzam, S.W. Joo, J. Inorg. Organomet. Polym. 22, 957 (2012)

    Article  CAS  Google Scholar 

  25. B. Mirtamizdoust, S. Ali-Asgari, S.W. Joo, E. Maskani, Y. Hanifehpour, T.H. Oh, J. Inorg. Organomet. Polym. 23, 751 (2013)

    Article  CAS  Google Scholar 

  26. Y. Hanifehpour, A. Morsali, B. Mirtamizdoust, S.W. Joo, J. Mol. Struct. 1079, 67 (2015)

    Article  CAS  Google Scholar 

  27. B. Mirtamizdoust, M.S. Shalamzari, S. Behrouzi, M.H. Florencio, H.K. Fun, J. Inorg. Organomet. Polym. 22, 1358 (2012)

    Article  CAS  Google Scholar 

  28. Y. Hanifehpour, B. Mirtamizdoust, A. Morsali, S.W. Joo, Ultrason. Sonochem. 23, 275 (2015)

    Article  CAS  Google Scholar 

  29. Y. Hanifehpour, B. Mirtamizdoust, A. Morsali, S.W. Joo, Ultrason. Sonochem. 31, 201–205 (2016)

    Article  CAS  Google Scholar 

  30. G.H. Shahverdizadeh, F. Hakimi, B. Mirtamizdoust, A. Soudi, P. Hojati-Talemi, J. Inorg. Organomet. Polym. 22, 903 (2012)

    Article  CAS  Google Scholar 

  31. Y. Hanifehpour, V. Safarifard, A. Morsali, B. Mirtamizdoust, S.W. Joo, Ultrason. Sonochem. 23, 282 (2015)

    Article  CAS  Google Scholar 

  32. Y. Hanifehpour, B. Mirtamizdoust, B. Khomami, S.W. Joo, Z. Anorg. Allg. Chem. 641, 2466 (2015)

    Article  CAS  Google Scholar 

  33. Y. Hanifehpour, B. Mirtamizdoust, M. Hatami, B. Khomami, S.W. Joo, J. Mol. Struct. 1091, 43 (2015)

    Article  CAS  Google Scholar 

  34. M.R. Maurya, S. Khurana, W. Zhang, D. Rehder, J. Chem. Soc. Dalton Trans. 3015 (2003)

  35. Mercury 1.4.1, Copyright Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge, CB2 1EZ, UK, 2001–2005

  36. J.M. Harrowfield, H. Miyamae, B.W. Skelton, A.A. Soudi, A.H. White, Aust. J. Chem 49, 1165 (1996)

    Article  Google Scholar 

  37. Bruker AXS Crystal Structure Analysis Package: Bruker (2000). SHELXTL. Version 6.14. Bruker AXS Inc., Madison, Wisconsin, USA. Bruker (2008). SADABS. Version 2008/1. Bruker AXS Inc., Madison, Wisconsin, USA. Bruker (2008). XPREP. Version 2008/2. Bruker AXS Inc., Madison, Wisconsin, USA. Bruker (2009). SAINT. Version 7.68 A. Bruker AXS Inc., Madison, Wisconsin, USA. Bruker (2010). APEX2. Version 2010.3–0. Bruker AXS Inc., Madison, Wisconsin, USA

  38. D.T. Cromer, J.T. Waber, International Tables for X-ray Crystallography, vol. 4 (Kynoch Press, Birmingham, 1974), Table 2.2 A

    Google Scholar 

  39. A.D. Becke, J. Chem. Phys. 98, 5648 (1993)

    Article  CAS  Google Scholar 

  40. A. Lee, W. Yang, R.G. Parr, Phys. Rev. B 37, 785 (1988)

    Article  CAS  Google Scholar 

  41. P.J. Hay, W.R. Wadt, J. Chem. Phys. 82, 270 (1985)

    Article  CAS  Google Scholar 

  42. J.B. Foresman, A.E. Frisch, Exploring Chemistry with Electronic Structure Methods, 2nd ed. (Gaussian Inc., Pittsburgh, 1996)

    Google Scholar 

  43. Gauss View, Version 3.0 Gaussian Inc., Pittsburgh, 2003

  44. A.E. Reed, F. Weinhold, Chem. Rev. 88, 899 (1998)

    Article  Google Scholar 

  45. H.B. Schelegel, Ab Initio Methods in Quantum Chemistry (Wiley, New York, 1987), pp. 249–286

    Google Scholar 

  46. L. Hashemi, A. Morsali, Ultrason. Sonochem 24, 146 (2015)

    Article  CAS  Google Scholar 

  47. K. Akhbari, S. Beheshti, A. Morsali, G. Bruno, H. Amiri Rudbari, Inorg. Chim. Acta 423, 101 (2014)

    Article  CAS  Google Scholar 

  48. L. Hashemi, A. Morsali, Ultrason. Sonochem. 21, 1417 (2014)

    Article  CAS  Google Scholar 

  49. L. Shimoni-Livny, J.P. Glusker, C.W. Brock, Inorg. Chem. 37, 1853 (1998)

    Article  CAS  Google Scholar 

  50. C.A. Hunter, J.K.M. Sanders, J. Am. Chem. Soc. 112, 5525 (1990)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

Support for this investigation from the University of Qom is gratefully acknowledged. This work is funded by Yeungnam University Postdoctoral Fellowship Program.

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    Authors and Affiliations

    1. School of Mechanical Engineering, Yeungnam University, Gyeongsan, 712-749, South Korea

      Younes Hanifehpour & Sang Woo Joo

    2. Mechanical and Electrical Engineering College, Hainan University, Haikou, 570228, Hainan Province, People’s Republic of China

      Teng Zhou

    3. Department of Chemistry, Faculty of Science, University of Qom, PO Box 37185-359, Qom, Iran

      Babak Mirtamizdoust & Hossein Mostaanzadeh

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    1. Younes Hanifehpour
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    5. Sang Woo Joo
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    Correspondence to Younes Hanifehpour or Sang Woo Joo.

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    Teng Zhou has equal contribution as the first author.

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    Hanifehpour, Y., Zhou, T., Mirtamizdoust, B. et al. Ultrasound-Assisted Synthesis of a Novel Nano-Zigzag-Pattern Lead (II) Metal–Organic System: A New Precursor to Produce Nano-Sized PbO. J Inorg Organomet Polym 27, 552–561 (2017). https://doi.org/10.1007/s10904-017-0497-9

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