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Structure and Photocatalytic Property of a Novel Three-Dimensional Supramolecular Cu(ΙΙ) Coordination Polymer with pcu Topology Based on the Rigid Multifunctional Ligand

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Abstract

A new copper coordination polymer, [Cu2L4(H2O)2]n (1), (HL = 3-(pyridine-2-yl)benzoic acid) has been solvothermally synthesized by using the HL and CuCl2⋅2H2O and characterized by IR spectra, elemental analysis, single-crystal and powder X-ray diffractions, and TGA. Compound 1 contains a well-known paddle-wheel unit [Cu2(COO)4], which is connected to a three-dimensional supramolecular structure with pcu topology through the hydrogen bond interactions. Compound 1 displays considerable thermal stability and exhibits selective absorption in the visible region, which is shown by thermogravimetric analysis and solid-state UV–Vis diffuse-reflectance spectra, respectively. In addition, compound 1 represents an example of visible light driven photocatalyst based on coordination polymer and shows good degradation ability over Rhodamine B (RhB).

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References

  1. F. Kayaci, S. Vempati, C. Ozgit-Akgun, I. Donmez, N. Biyikli, T. Uyar, Nanoscale. 6, 5735 (2014)

    Article  CAS  Google Scholar 

  2. K.R. Reddy, M. Hassan, V.G. Gomes, Appl. Catal. A 489, 1 (2015)

    Article  CAS  Google Scholar 

  3. M. Hassan, E. Haque, K.R. Reddy, A.I. Minett, J. Chen, V.G. Gomes, Nanoscale. 6, 11988 (2014)

    Article  CAS  Google Scholar 

  4. K.R. Reddy, B.S. Cheol, C.H. Yoo, D. Sohn, Y. Lee, J. Colloid. Interface. Sci. 340, 160 (2009)

    Article  CAS  Google Scholar 

  5. M. Hassan, K.R. Reddy, E. Haque, A.I. Minett, V.G. Gomes, J. Colloid. Interface. Sci. 410, 43 (2013)

    Article  CAS  Google Scholar 

  6. K.R. Reddy, B.S. Cheol, K.R. Sun, C.J. Kim, H. Chung, Y. Lee, Synth. Met. 159, 595 (2009)

    Article  CAS  Google Scholar 

  7. K.R. Reddy, K.P. Lee, I.A. Gopalan, A.M. Showkat, Polym. Adv. Technol. 18, 38 (2007)

    Article  CAS  Google Scholar 

  8. S.H. Choi, D.H. Kim, A.V. Raghu, K.R. Reddy, H.I. Lee, K.S. Yoong, H.M. Jeong, B.K. Kim, J. Macromol. Sci. 51, 197 (2012)

    Article  CAS  Google Scholar 

  9. M. Li, D. Li, M. O’Keefe, O.M. Yaghi, Chem. Rev. 114, 1343 (2014)

    Article  CAS  Google Scholar 

  10. H.-C. Zhou, S. Kitagawa, Chem. Soc. Rev. 43, 5415 (2014)

    Article  CAS  Google Scholar 

  11. L.E. Kreno, K. Leong, O.K. Farha, M. Allendorf, R.P.V. Duyne, J.T. Hupp, Chem. Rev. 112, 1105 (2012)

    Article  CAS  Google Scholar 

  12. T. Zhang, W.-B. Lin, Chem. Soc. Rev. 43, 5982 (2014)

    Article  CAS  Google Scholar 

  13. L. Liu, S.-M. Wang, Z.-B. Han, M.-L. Ding, D.-Q. Yaun, H.-L. Jiang, Inorg. Chem. 55, 3558 (2016)

    Article  CAS  Google Scholar 

  14. F. Wang, Z.-S. Liu, H. Yang, Y.-X. Tan, J. Zhang, Angew. Chem. Int. Ed. Engl. 50, 450 (2011)

    Article  CAS  Google Scholar 

  15. L.-L. Wen, J.-B. Zhao, K.-L. Lv, Y.-H. Wu, K.-J. Deng, X.-K. Leng, D.-F. Li, Cryst. Growth Des. 12, 1603 (2012)

    Article  CAS  Google Scholar 

  16. T. Wen, D.-X. Zhang, J. Zhang, Inorg. Chem. 52, 12 (2013)

    Article  CAS  Google Scholar 

  17. P. Manna, J. Debgupta, S. Bose, S.K. Das, Angew. Chem. Int. Ed. Engl. 55, 2425 (2016)

    Article  CAS  Google Scholar 

  18. C. Wang, Z.-G. Xie, K.E. Krafft, W.-B. Lin, J. Am. Chem. Soc. 133, 13445 (2011)

    Article  CAS  Google Scholar 

  19. C. Wang, J.-L. Wang, W.-B. Lin, J. Am. Chem. Soc. 134, 19895 (2012)

    Article  CAS  Google Scholar 

  20. H.-Q. Xu, J.-H. Hu, D.-K. Wang, Z.-H. Li, Q. Zhang, Y. Luo, S.-H. Yu, H.-L. Jiang, J. Am. Chem. Soc. 137, 13440 (2015)

    Article  CAS  Google Scholar 

  21. C.-C. Wang, J.-R. Li, X.-L. Lv, Y.-Q. Zhang, G.-S. Guo, Energy. Environ. Sci. 7, 2831 (2014)

    CAS  Google Scholar 

  22. B. Xu, Z.-M. Chen, P.-F. Zhi, G.-N. Liu, C.-C. Li, Inorg. Chem. Commun. 52, 9 (2015)

    Article  CAS  Google Scholar 

  23. O.R. Evans, W.-B. Lin, Chem. Mater. 13, 2705 (2001)

    Article  CAS  Google Scholar 

  24. R.-Q. Zhong, R.-Q. Zou, M. Du, L. Jiang, T. Yanada, G. Maruta, S. Takeda, Q. Xu, Cryst. Eng. Comm. 10, 605 (2008)

    Article  CAS  Google Scholar 

  25. J.-H. Luo, Y.-S. Zhao, H.-W. Xu, T.L. Kinnibrugh, D.-L. Yang, T.V. Timofeeva, L.L. Daemen, J.-Z. Zhang, W. Bao, J.D. Thompson, R.P. Currier, Inorg. Chem. 46, 9021 (2007)

    Article  CAS  Google Scholar 

  26. Y-B. Zhang, H-L. Zhou, C-T He, W. Xue, J-P Zhang, X-M. Chen, Chem. J. Chinese University. 32, 497 (2011)

  27. SAINT version 6.02a, Software Reference Manual (Bruker AXS Inc, Madison, WI, 2002)

  28. G.M. Sheldrick, SHELXS-97, Program for the Solution of Crystal Structures (University of Göttingen, Germany, 1997)

    Google Scholar 

  29. G.M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structures (University of Göttingen, Germany, 1997)

    Google Scholar 

  30. C.-H. Zhou, Y.-M. Wang, K. Jin, J.-J. Ma, J.-S. Hu, Inorg. Chem. Commun. 62, 81 (2015)

    Article  CAS  Google Scholar 

  31. M. O’Keefe, M.A. Peskov, S.J. Ramsden, O.M. Yaghi, Acc. Chem. Res. 41, 1782 (2008)

    Article  Google Scholar 

  32. V.A. Blatov, A.P. Shevchenko, TOPOS 4.0 (Samara State University, Russia, 2008)

    Google Scholar 

  33. K. Nakamoto, Infrared and raman spectra of inorganic and coordination compounds, 6th edn. (Wiley, New Jersey, 2009)

    Google Scholar 

  34. W.-L. Liu, J.-H. Yu, J.-X. Jiang, L.-M. Yuan, B. Xu, Q. Liu, B.-T. Qu, G.-Q. Zhang, C.-G. Yan, Cryst. Eng. Comm. 13, 2764 (2011)

    Article  CAS  Google Scholar 

  35. Z.-Q. Shi, N.-N. Ji, G.-F. He, Y.-F. Han, Chin. J. Inorg. Chem. 27, 1507 (2011)

    CAS  Google Scholar 

  36. J.-S. Hu, X.-H. Huang, C.-L. Pan, L. Zhang, Cryst. Growth Des. 15, 2272 (2015)

    Article  CAS  Google Scholar 

  37. T. Leshuk, S. Linley, G. Baxter, F. Gu, A.C.S. Appl, Mater. Interfaces. 4, 6062 (2012)

    Article  CAS  Google Scholar 

  38. M.P. Seabra, E. Rego, A. Ribeiro, J.A. Labrincha, Chem. Eng. J. 171, 175 (2011)

    Article  CAS  Google Scholar 

  39. K.R. Reddy, V.G. Gomes, M. Hassan, Mater. Res. Express. 1, 015012 (2012)

    Article  Google Scholar 

  40. K.R. Reddy, K. Nakata, T. Ochiai, T. Murakami, D.A. Tryk, A. Fujishima, J. Nanosci. Nanotechnol. 10, 7951 (2010)

    Article  CAS  Google Scholar 

  41. K.R. Reddy, K. Nakata, T. Ochiai, T. Murakami, D.A. Tryk, A. Fujishima, J. Nanosci. Nanotechnol. 11, 3692 (2011)

    Article  CAS  Google Scholar 

  42. Z.-L. Liao, G.-D. Li, M.-H. Li, J.-S. Chen, Inorg. Chem. 47, 4844 (2008)

    Article  CAS  Google Scholar 

  43. C.G. Silva, I. Luz, F.X.L. Xamena, A. Corma, H. García, Chem. Eur. J. 16, 11133 (2010)

    Article  CAS  Google Scholar 

  44. Q. Zhang, J.N.M. Shreeve, Angew. Chem. Int. Ed. Engl. 53, 2540 (2014)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the National Nature Science Foundation of China (No. 21101019), the Natural Science Foundation of Anhui Province University (No. gxyqZD2016371) and the Chizhou College (No.2015ZR001).

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Authors and Affiliations

  1. School of Chemistry and Material Engineering, Chizhou College, Chizhou, 247000, People’s Republic of China

    Xiaoshuo Wu Pengfei Wang & Siyuan Xu Pengpeng Lu

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  1. Xiaoshuo Wu Pengfei Wang
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  2. Siyuan Xu Pengpeng Lu
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Corresponding author

Correspondence to Xiaoshuo Wu Pengfei Wang.

Electronic Supplementary Material

Below is the link to the electronic supplementary material.

10904_2016_404_MOESM1_ESM.doc

Supplementary material 1 (DOC 193 kb) CCDC-1476277 contains the supplementary crystallographic data for compound 1. These data also can be obtained free of charge from The Cambridge Crystalographic Data Centra via www.ccdc.ac.uk/data_request/cif. Supplementary data associated with this manuscript can be found in supporting information

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Wang, X.W.P., Lu, S.X.P. Structure and Photocatalytic Property of a Novel Three-Dimensional Supramolecular Cu(ΙΙ) Coordination Polymer with pcu Topology Based on the Rigid Multifunctional Ligand. J Inorg Organomet Polym 26, 1101–1106 (2016). https://doi.org/10.1007/s10904-016-0404-9

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  • DOI: https://doi.org/10.1007/s10904-016-0404-9

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