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Two Energetic Cobalt(II) Coordination Polymers Derived from Isomeric Ligands

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Abstract

Isomer is sometimes fundamental to the formation of the resulting compounds. The design and preparation of coordination compounds based on isomers is of tremendous paramount since they have a lot in common but simultaneously some difference, which can lead to variation of both the topologies and properties. Solvothermal reactions of Hn-pytza (n = 3, 4) with Co(ClO4)2·6H2O, afforded two interesting coordination polymers, one dimensional [Co(3-pytza)2(H2O)2]n·2nH2O (1) and three dimensional [Co(4-pytza)2]n (2), where Hn-pytza = 5-(n-pyridyl)tetrazole-2-acetic acid (n = 3, 4). The thermal decomposition behavior of the two compounds were characterized by the differential scanning calorimetry (DSC) and thermogravimetric-differential thermogravimetric (TG-DTG), showing [Co(4-pytza)2]n is superior to [Co(3-pytza)2(H2O)2]n·2nH2O in terms of energetic performance. Furthermore, the entropy of activation (∆S), enthalpy of activation (∆H), and free energy of activation (∆G) were calculated, as well.

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Acknowledgments

The authors acknowledge financial support from the Natural Science Foundation of Jiangsu Province (Grant No. BK2012210), the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (Grant No. 10KJB430001) and the Opening Fund of Jiangsu Key Laboratory of Advanced Functional Materials (Grant No. 12KFJJ010).

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Authors and Affiliations

  1. Jiangsu Laboratory of Advanced Functional Material, Department of Chemistry and Material Engineering, Changshu Institute of Technology, Changshu, 215500, Jiangsu, People’s Republic of China

    Da Liang Zhu, Qiu Yan Yue, Jue Wang, Meng Yue Guo, Li Li Miao, Li Jun Qiu, Qiao Yun Li & Gao Wen Yang

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  1. Da Liang Zhu
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  2. Qiu Yan Yue
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  3. Jue Wang
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Correspondence to Qiao Yun Li or Gao Wen Yang.

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Zhu, D.L., Yue, Q.Y., Wang, J. et al. Two Energetic Cobalt(II) Coordination Polymers Derived from Isomeric Ligands. J Inorg Organomet Polym 26, 616–622 (2016). https://doi.org/10.1007/s10904-016-0343-5

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  • DOI: https://doi.org/10.1007/s10904-016-0343-5

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