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Methyl orange removal from wastewater using [Zn2(oba)2(4-bpdh)]·3DMF metal–organic frameworks nanostructures

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Abstract

A porous coordination polymer, [Zn2(oba)2(4-bpdh)]·3DMF (TMU-5) upon silk yarn, has been synthesized under ultrasound irradiation. We here present a textile for the adsorptive removal methyl orange from wastewater using three-dimensional porous Zn(II)-based metal–organic framework (TMU-5) and silk fibers. The effect of sequential dipping steps in growth of TMU-5 upon fiber has been studied. These systems depicted a decrease in the size accompanying a decrease in the sequential dipping steps. The samples were characterized with powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy spectra and scanning electron microscopy. XRD analyses indicated that the prepared TMU-5 on silk fibers were crystalline.

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Acknowledgments

Support of this investigation by Iran National Science Foundation: INSF and Razi University of Kermanshah are gratefully acknowledged.

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Authors and Affiliations

  1. Faculty of Chemistry, Razi University, Kermanshah, 67194, Islamic Republic of Iran

    Amir Reza Abbasi & Mohammadreza Yousefshahi

  2. Department of Chemistry, Faculty of Science, Khorramabad Branch, Islamic Azad University, Khorramabad, Iran

    Azadeh Azadbakht

  3. Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14155-4838, Tehran, Iran

    Ali Morsali & Mohammad Yaser Masoomi

Authors
  1. Amir Reza Abbasi
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  2. Mohammadreza Yousefshahi
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  3. Azadeh Azadbakht
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  4. Ali Morsali
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  5. Mohammad Yaser Masoomi
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Correspondence to Amir Reza Abbasi or Ali Morsali.

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Abbasi, A.R., Yousefshahi, M., Azadbakht, A. et al. Methyl orange removal from wastewater using [Zn2(oba)2(4-bpdh)]·3DMF metal–organic frameworks nanostructures. J Inorg Organomet Polym 25, 1582–1589 (2015). https://doi.org/10.1007/s10904-015-0262-x

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