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Exploration of Supramolecular Architecture in Complexes with 1-Substituted-1H-[1,2,3]-triazole-4-carboxylic Acid: Structural Elucidation and Hirshfeld Surface Analysis

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Abstract

Two new complexes [Cu(HL)2(H2O)2] (1) and [AgHL] n (2) (where H2L is 5-methyl-1-(1H-pyrazol-3-yl)-1H-1,2,3-triazole-4-carboxylic acid) have been synthesized at room temperature and structurally characterized by elemental analysis, IR spectroscopy, and single crystal X-ray diffraction. Intermolecular, compounds 1 displays a 2D network containing 10-number and 4-number rings forming by intermolecular hydrogen bond O–H···O. Complex 2 is a Ag(I) polymer and exists C–H···Ag interactions forming the 2D layers into supermolecule. Intermolecular interactions in molecular crystal of 2 was explored by hirshfeld surface analysis, and the 2D fingerprint plots reveal that the main intermolecular contact is N···H/H···N contact with proportion of 22.9 %.

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References

  1. G.R. Desiraju, Crystal engineering: the design of organic solids (Elsevier, Amsterdam, 1989)

    Google Scholar 

  2. G.R. Desiraju, Angew. Chem. Int. Ed. Engl. 34, 2311 (1995)

    Article  CAS  Google Scholar 

  3. K. Ariga, Y. Yamauchi, G. Rydzek, Q.M. Ji, Y. Yonamine, K.C.W. Wu, J.P. Hill, Chem. Lett. 43, 36 (2014)

    Article  CAS  Google Scholar 

  4. U.N. Maiti, W.J. Lee, J.M. Lee, Y. Oh, J.Y. Kim, J.E. Kim, J. Shim, T.H. Han, S.O. Kim, Adv. Mater. 26, 40 (2014)

    Article  CAS  Google Scholar 

  5. S.L. Gai, C.X. Li, P.P. Yang, J. Lin, Chem. Rev. 114, 2343 (2014)

    Article  CAS  Google Scholar 

  6. S.K. Seth, N.K. Das, K. Aich, D. Sen, H.K. Fun, S. Goswami, J. Mol. Struct. 1048, 157 (2013)

    Article  CAS  Google Scholar 

  7. Y. Su, S.Q. Zang, Y.Z. Li, H.Z. Zhu, Q.J. Meng, Cryst. Growth Des. 7, 1277 (2007)

    Article  CAS  Google Scholar 

  8. A.M. Baruah, A. Karmakar, J.B. Baruah, Inorg. Chim. Acta 361, 2777 (2008)

    Article  CAS  Google Scholar 

  9. S.H. Zhang, R.X. Zhao, G. Li, H.Y. Zhang, C.L. Zhang, G. Muller, RSC Adv. 4, 54837 (2014)

    Article  CAS  Google Scholar 

  10. R.X. Zhao, H. Hai, G. Li, H.Y. Zhang, Q.P. Huang, S.H. Zhang, H.P. Li, J. Cluster Sci. 25, 1541 (2014)

    Article  CAS  Google Scholar 

  11. F.L. Hirshfeld, Theor. Chim. Acta. 44, 129 (1977)

    Article  CAS  Google Scholar 

  12. Z.J. Li, W.H. Ojala, D.J.W. Grant, J. Pharm. Sci. 90, 1523 (2001)

    Article  CAS  Google Scholar 

  13. M.A. Spackman, J.J. McKinnon, CrystEngComm 4, 378 (2002)

    Article  CAS  Google Scholar 

  14. J.J. McKinnon, D. Jayatilaka, M.A. Spackman, Chem. Commun. 37, 3814 (2007)

    Article  Google Scholar 

  15. M.A. Spackman, J.J. McKinnon, D. Jayatilaka, CrystEngComm 10, 377 (2008)

    CAS  Google Scholar 

  16. S.K. Wolff, D.J. Grimwood, J.J. McKinnon, D. Jayatilaka, M.A. Spackman, CrystalExplorer 2.1 (University of Western Australia, Perth, Australia, 2007)

    Google Scholar 

  17. S.K. Seth, I. Saha, C. Estarellas, A. Frontera, T. Kar, S. Mukhopadhyay, Cryst. Growth Des. 11, 3250 (2011)

    Article  CAS  Google Scholar 

  18. S.K. Seth, D. Sarkar, A.D. Jana, T. Kar, Cryst. Growth Des. 11, 4837 (2011)

    Article  CAS  Google Scholar 

  19. S.K. Seth, D. Sarkar, A. Roy, T. Kar, CrystEngComm 13, 6728 (2011)

    Article  CAS  Google Scholar 

  20. A.L. Rohl, M. Moret, W. Kaminsky, K. Claborn, J.J. Mckinnon, B. Kahr, Cryst. Growth Des. 8, 4517 (2008)

    Article  CAS  Google Scholar 

  21. A. Parkin, G. Barr, W. Dong, C.J. Gilmore, D. Jayatilaka, J.J. Mckinnon, M.A. Spackman, C.C. Wilson, CrystEngComm 9, 648 (2007)

    Article  CAS  Google Scholar 

  22. X.G. Bai, C. Feng, Acta Cryst. E70, o755 (2014)

    Google Scholar 

  23. G.M. Sheldrick, Acta Cryst. A64, 112 (2008)

    Article  Google Scholar 

  24. L. Yang, Q.P. Huang, C.L. Zhang, R.X. Zhao, S.H. Zhang, Supramol. Chem. 26, 81 (2014)

    Article  CAS  Google Scholar 

  25. X.Y. Qin, H.N. Yao, W. Ou, S.H. Zhang, Synth. React. Inorg. Met. Org. Chem. 44, 242 (2014)

    Article  Google Scholar 

  26. W. Wang, H. Hai, S.H. Zhang, L. Yang, C.L. Zhang, J. Cluster Sci. 25, 357 (2014)

    Article  CAS  Google Scholar 

  27. C.L. Zhang, X.F. Jiang, L. Yang, S.H. Zhang, S.M. Shi, J. Cluster Sci. 25, 459 (2014)

    Article  Google Scholar 

  28. H. Zhao, Z.J. Chu, G.Y. Gao, H.H. Huang, Z.R. Qu, Polyhedron 83, 143 (2014)

    Article  CAS  Google Scholar 

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Acknowledgments

We gratefully acknowledge the financial support of the National Natural Science Foundation of China (20801012) and the financial support from Jiangsu Ainaji Neoenergy Science & Technology Co., Ltd (8507040091).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Southeast University, Nanjing, 211189, People’s Republic of China

    Chao Feng, Gui-Yuan Gao, Li-Na Sun & Hong Zhao

  2. Key Laboratory of Organosilicon Chemistry and Material Technology of the Ministry of Education, Hangzhou Normal University, Hangzhou, 311121, People’s Republic of China

    Zhi-Rong Qu

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  1. Chao Feng
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  2. Gui-Yuan Gao
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  4. Li-Na Sun
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Correspondence to Hong Zhao.

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Feng, C., Gao, GY., Qu, ZR. et al. Exploration of Supramolecular Architecture in Complexes with 1-Substituted-1H-[1,2,3]-triazole-4-carboxylic Acid: Structural Elucidation and Hirshfeld Surface Analysis. J Inorg Organomet Polym 25, 1233–1238 (2015). https://doi.org/10.1007/s10904-015-0232-3

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  • DOI: https://doi.org/10.1007/s10904-015-0232-3

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