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Two 3D Supramolecular Cadmium(II) Coordination Polymers Derived from Semi-rigid Bis(2-methylbenzimidazole) and Different Dicarboxylate Ligands

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Abstract

Two cadmium(II) coordination polymers, [Cd(L)(nda)(H2O)·0.75H2O] n (1) and [Cd(L)(tbta)(H2O)] n (2) (L = 1,3-bis-(2-methylbenzimidazol-1-ylmethyl)benzene, H2nda = 2,6-naphthalenedicarboxylic acid, H2tbta = tetrabromoterephthalic acid), were synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction and powder X-ray diffraction analysis. Both complexes exhibit 2D (6,3) honeycomb-like structures. Complex 1 is further extended into a twofold interpenetrating 3D 4,4-connected mog supramolecular architecture with point symbol of {4.64.8}2{42.62.82} via classical O–H···O hydrogen bonding interactions, while 2 displays a 3D supramolecular framework through π–π stacking interactions. The fluorescence properties and thermal stability of the two complexes were investigated.

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Acknowledgments

The project was supported by the National Natural Science Foundation of China (51474086) and the Hercules Foundation (project AUGE/11/029“3D-SPACE: 3D Structural Platform Aiming for Chemical Excellence”) for funding.

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Authors and Affiliations

  1. College of Chemical Engineering, Hebei United University, 46 West Xinhua Road, Tangshan, 063009, Hebei, People’s Republic of China

    Rui Yang & Guang Hua Cui

  2. TangShan Gas Group Limited Company, 22 North Huayan Road, Tangshan, 063009, Hebei, People’s Republic of China

    Wen Chen Xiao

  3. Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281 S3, 9000, Ghent, Belgium

    Kristof Van Hecke

Authors
  1. Rui Yang
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  2. Wen Chen Xiao
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  3. Kristof Van Hecke
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  4. Guang Hua Cui
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Correspondence to Guang Hua Cui.

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Yang, R., Xiao, W.C., Van Hecke, K. et al. Two 3D Supramolecular Cadmium(II) Coordination Polymers Derived from Semi-rigid Bis(2-methylbenzimidazole) and Different Dicarboxylate Ligands. J Inorg Organomet Polym 25, 772–779 (2015). https://doi.org/10.1007/s10904-014-0157-2

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  • DOI: https://doi.org/10.1007/s10904-014-0157-2

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