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A New (4,8)-Connected scu-Type Heterometallic-Organic Framework: Synthesis, Structure and Luminescent Property

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Abstract

Presented here is a new heterometallic coordination polymer, namely [ZnCa(btec)(H2O)2]n (1 H4btec = 1,2,4,5-benzenetetracarboxylic acid), which was successfully synthesized via the hydrothermal reactions of H4btec, Zn(NO3)2 and CaCl2. Single crystal X-ray structural analysis reveals that compound 1 features a 3D inorganic–organic hybrid framework, which can be simplified into a (4,8)-connected scu topological network by viewing Zn(II) ions, Ca(II) ions, btec4− ligands as 4-, 4-, and 8-connected nodes, respectively. Moreover, the luminescent properties of compound 1 and the desolvated samples were also investigated at room temperature.

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Acknowledgments

This work was supported by grants from the Sci-technical Support Project of Hebei Province (14227115D).

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Authors and Affiliations

  1. College of Sciences, Agricultural University of Hebei, Baoding, 071001, China

    Yanli Dong, Xiaohui Li & Huimin Liu

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  1. Yanli Dong
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  2. Xiaohui Li
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  3. Huimin Liu
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Correspondence to Huimin Liu.

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Dong, Y., Li, X. & Liu, H. A New (4,8)-Connected scu-Type Heterometallic-Organic Framework: Synthesis, Structure and Luminescent Property. J Inorg Organomet Polym 25, 645–649 (2015). https://doi.org/10.1007/s10904-014-0130-0

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  • DOI: https://doi.org/10.1007/s10904-014-0130-0

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