Skip to main content
SpringerLink
Log in

Synthesis of Polyaniline and Transition Metal Nanoparticles Hybrids

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

Synthesis of polyaniline (PANI)/metal nanoparticles hybrids (M NPs, M = Pd, Au, and Pt) through the template approach and their characterization were investigated. The IR study suggests that the partial oxidation of PANI main chain in the complexation of the metal salts. Subsequent reduction of the metal salts to form the M NPs induced the partial reduction of PANI main chain. Hypochromic phenomenon for π–π* and charge transfer (CT) bands were observed in UV–Vis–NIR absorption spectra for PANI/M NPs. SEM–EDX analysis revealed the uniform dispersion of M NPs. The M NPs (average diameter 2–3 nm) were clearly observed in PANI/Pd, Au, and Pt NPs. They were proton-doped, and their conductivity was investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. R. Gangopadhyay, A. De, Chem. Mater. 12, 608 (2000)

    Article  CAS  Google Scholar 

  2. K. Mallick, M. Witcomb, M. Scurrell, Platin. Met. Rev. 51, 3 (2007)

    Article  CAS  Google Scholar 

  3. K. Mallick, M. Witcomb, M.S. Scurrell, Gold Bull. 39, 166 (2006)

    Article  CAS  Google Scholar 

  4. M. Wessling, Polymers 2, 786 (2010)

    Article  CAS  Google Scholar 

  5. D. Li, J. Huang, R.B. Kaner, Acc. Chem. Res. 42, 135 (2009)

    Article  CAS  Google Scholar 

  6. C. Oueiny, S. Berlioz, F.-X. Perrin, Prog. Polym. Sci. 39, 707 (2014)

    Article  CAS  Google Scholar 

  7. A. Drelinkiewicz, M. Hasik, M. Kloc, J. Catal. 186, 123 (1999)

    Article  CAS  Google Scholar 

  8. J. Wang, K.G. Neoh, E.T. Kang, J. Colloid Interface Sci. 239, 78 (2001)

    Article  CAS  Google Scholar 

  9. A. Houdayer, R. Schneider, D. Billaud, J. Ghanbaja, J. Lambert, Appl. Organomet. Chem. 19, 1239 (2005)

    Article  CAS  Google Scholar 

  10. B.J. Gallon, R.W. Kojima, R.B. Kaner, P.L. Diaconescu, Angew. Chem. Int. Ed. 46, 7251 (2007)

    Article  CAS  Google Scholar 

  11. S. Ivanov, U. Lange, V. Tsakova, V.M. Mirsky, Sens. Actuators, B 150, 271 (2010)

    Article  CAS  Google Scholar 

  12. S. Komathi, S. Palaniappan, P. Manisankar, A.I. Gopalan, K.-P. Lee, Macromol. Chem. Phys. 211, 1330 (2010)

    Article  CAS  Google Scholar 

  13. R. Kosydar, M. Goral, A. Drelinkiewicz, J. Stejskal, Chem. Pap. 67, 1087 (2013)

    Article  CAS  Google Scholar 

  14. J. Han, J. Dai, C. Zhou, R. Guo, Polym. Chem. 4, 313 (2013)

    Article  CAS  Google Scholar 

  15. T.K. Sarma, D. Chowdhury, A. Paul, A. Chattopadhyay, Chem. Commun. 10, 1048 (2002)

    Article  Google Scholar 

  16. T.K. Sarma, A. Chattopadhyay, J. Phys. Chem. A 108, 7837 (2004)

    Article  CAS  Google Scholar 

  17. R.J. Tseng, J. Huang, J. Ouyang, R.B. Kaner, Y. Yang, Nano Lett. 5, 1077 (2005)

    Article  CAS  Google Scholar 

  18. W. Li, Q.X. Jia, H.-L. Wang, Polymer 47, 23 (2006)

    Article  CAS  Google Scholar 

  19. G. Tanami, V. Gutkin, D. Mandler, Langmuir 26, 4239 (2010)

    Article  CAS  Google Scholar 

  20. E.A. Sanches, J.C. Soares, R.M. Iost, V.S. Marangoni, G. Trovati, T. Batista, A.C. Mafud, V. Zucolotto, Y.P. Mascarenhas, J. Nanomater. 1 (2011)

    Article  Google Scholar 

  21. Y.-F. Huang, Y.I. Park, C.Y. Kuo, P. Xu, D.J. Williams, J. Wang, C.-W. Lin, H.-L. Wang, J. Phys. Chem. C 116, 11272 (2012)

    Article  CAS  Google Scholar 

  22. J.M. Kinyanjui, R. Harris-Burr, J.G. Wagner, N.R. Wijeratne, D.W. Hatchett, Macromolecules 37, 8745 (2004)

    Article  CAS  Google Scholar 

  23. A. Nyczyk, A. Sniechota, A. Adamczyk, A. Bernasik, W. Turek, Magdalena Hasik. Eur. Polym. J. 44, 1594 (2008)

    Article  CAS  Google Scholar 

  24. A. Drelinkiewicz, A. Zięba, J.W. Sobczak, M. Bonarowska, Z. Karpiński, A. Waksmundzka-Góra, J. Stejskal, React. Funct. Polym. 69, 630 (2009)

    Article  CAS  Google Scholar 

  25. A. Nyczyk, M. Hasik, W. Turek, A. Sniechota, Synth. Met. 159, 561 (2009)

    Article  CAS  Google Scholar 

  26. D. Zhai, B. Liu, Y. Shi, L. Pan, Y. Wang, W. Li, R. Zhang, G. Yu, ACS Nano 7, 3540 (2013)

    Article  CAS  Google Scholar 

  27. M. Higuchi, D. Imoda, T. Hirao, Macromolecules 29, 8277 (1996)

    Article  CAS  Google Scholar 

  28. T. Hirao, S. Yamaguchi, S. Fukuhara, Tetrahedron Lett. 40, 3009 (1999)

    Article  CAS  Google Scholar 

  29. T. Hirao, S. Yamaguchi, S. Fukuhara, Synth. Met. 106, 67 (1999)

    Article  CAS  Google Scholar 

  30. T. Hirao, S. Fukuhara, Y. Otomaru, T. Moriuchi, Synth. Met. 123, 373 (2001)

    Article  CAS  Google Scholar 

  31. X. Shen, T. Moriuchi, T. Hirao, Tetrahedron Lett. 45, 4733 (2004)

    Article  CAS  Google Scholar 

  32. T. Hirao, M. Higuchi, B. Hatano, I. Ikeda, Tetrahedron Lett. 36, 5925 (1995)

    Article  CAS  Google Scholar 

  33. D. Saio, T. Amaya, T. Hirao, Adv. Synth. Catal. 352, 2177 (2010)

    Article  CAS  Google Scholar 

  34. T. Amaya, T. Hirao, Synlett 435 (2011)

    Google Scholar 

  35. T. Amaya, T. Ito, Y. Inada, D. Saio, T. Hirao, Tetrahedron Lett. 53, 6144 (2012)

    Article  CAS  Google Scholar 

  36. T. Amaya, T. Ito, T. Hirao, Heterocycles 86, 927 (2012)

    Article  CAS  Google Scholar 

  37. T. Amaya, T. Ito, T. Hirao, Tetrahedron Lett. 54, 2409 (2013)

    Article  CAS  Google Scholar 

  38. T. Amaya, D. Saio, T. Hirao, Macromol. Symp. 270, 88 (2008)

    Article  CAS  Google Scholar 

  39. T. Amaya, D. Saio, T. Hirao, Tetrahedron Lett. 48, 2729 (2007)

    Article  CAS  Google Scholar 

  40. D. Saio, T. Amaya, T. Hirao, J. Inorg. Organomet. Polym. 19, 79 (2009)

    Article  CAS  Google Scholar 

  41. T. Isaji, T. Amaya, Y. Inada, M. Abe, T. Hirao, Bull. Chem. Soc. Jpn. 87, 1130 (2014)

    Article  CAS  Google Scholar 

  42. K. Liu, C.-L. Ho, S. Aouba, Y.-Q. Zhao, Z.-H. Lu, S. Petrov, N. Coombs, P. Dube, H.E. Ruda, W.-Y. Wong, I. Manners, Angew. Chem. Int. Ed. 47, 1255 (2008)

    Article  CAS  Google Scholar 

  43. E.T. Kang, K.G. Neoh, K.L. Tan, Prog. Polym. Sci. 23, 277 (1998)

    Article  CAS  Google Scholar 

  44. G.E. Asturias, A.G. MacDiarmid, R.P. Mccall, A.J. Epstein, Synth. Met. 29, E157 (1989)

    Article  CAS  Google Scholar 

  45. L.L. Premvardhan, S. Wachsmann-Hogiu, L.A. Peteanu, D.J. Yaron, P.-C. Wang, W. Wang, A.G. MacDiarmid, J. Chem. Phys. 115, 4359 (2001)

    Article  CAS  Google Scholar 

  46. O.P. Dimitriev, O.M. Getsko, Synth. Met. 104, 27 (1999)

    Article  CAS  Google Scholar 

  47. Y. Xia, J.M. Wiesinger, A.G. MacDiarmid, Chem. Mater. 7, 443 (1995)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka, 565-0871, Japan

    Toru Amaya, Tadayuki Isaji & Toshikazu Hirao

  2. Nissan Chemical Industries Ltd, 11-1, Kitasode, Sodegaura, Chiba, 299-0266, Japan

    Tadayuki Isaji & Masashi Abe

Authors
  1. Toru Amaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Tadayuki Isaji
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Masashi Abe
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Toshikazu Hirao
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Toshikazu Hirao.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Amaya, T., Isaji, T., Abe, M. et al. Synthesis of Polyaniline and Transition Metal Nanoparticles Hybrids. J Inorg Organomet Polym 25, 145–152 (2015). https://doi.org/10.1007/s10904-014-0123-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-014-0123-z

Keywords

Search

Navigation