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Narrow Bandgap Platinum(II)-Containing Polyynes with Diketopyrrolopyrrole and Isoindigo Spacers

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Abstract

Two new solution-processible platinum(II) polyyne polymers P1 and P2 bridged by diketopyrrolopyrrole and isoindigo units have been synthesized via the CuI-catalyzed dehydrohalogenation reaction of the platinum(II) chloride precursors and the corresponding diacetylene ligands. The photophysical and electrochemical properties of P1 and P2 were investigated. These metallo-organic polymers have relatively narrow bandgaps of around 1.58–1.70 eV and broad absorption bands which are favorable for harvesting solar energy.

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Acknowledgments

We thank the National Natural Science Foundation of China (Project Number 51373145), Hong Kong Baptist University (FRG2/12-13/083), Hong Kong Research Grants Council (HKBU203312 and HKUST2/CRF/10) and Areas of Excellence Scheme, University Grants Committee of HKSAR (project No. AoE/P-03/08) for financial support. The work was also supported by Partner State Key Laboratory of Environmental and Biological Analysis (SKLP-14-15-P011) and Strategic Development Fund of HKBU. The project was also supported by Open Research Fund of State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences. Y. H. Lo gratefully acknowledges the financial support from the National Science Council of Taiwan (NSC 102-2113-M-845-001) and the project of the specific research fields in the University of Taipei, Taiwan. H. Li thanks the 111 Project and Beijing Engineering Research Center of Food Environment and Public Health from Minzu University of China (Nos. B08044 and 10301-01404026) for financial support.

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Authors and Affiliations

  1. Institute of Molecular Functional Materials and Department of Chemistry, Partner State Key Laboratory of Environmental and Biological Analysis and Institute of Advanced Materials, Hong Kong Baptist University, Waterloo Road, Kowloon Tong, Hong Kong, People’s Republic of China

    Qian Liu, Cheuk-Lam Ho, Hua Li & Wai-Yeung Wong

  2. Department of Applied Physics and Chemistry, University of Taipei, Taipei, 100, Taiwan

    Yih Hsing Lo

  3. College of Life and Environmental Sciences & Beijing Engineering Research Center of Food Environment and Public Health, Minzu University of China, Beijing, 100081, People’s Republic of China

    Hua Li

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  1. Qian Liu
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  2. Cheuk-Lam Ho
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  4. Hua Li
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Correspondence to Cheuk-Lam Ho, Yih Hsing Lo or Wai-Yeung Wong.

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Dedicated to Prof. Benzhong Tang in honor of his outstanding contributions to the field of Inorganic and Organometallic Polymers.

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Liu, Q., Ho, CL., Lo, Y.H. et al. Narrow Bandgap Platinum(II)-Containing Polyynes with Diketopyrrolopyrrole and Isoindigo Spacers. J Inorg Organomet Polym 25, 159–168 (2015). https://doi.org/10.1007/s10904-014-0120-2

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