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Three Novel Cd(II) and Zn(II) Coordination Polymers with O-, N-donor Ligands: Syntheses, Structures, and Photoluminescence Properties

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Abstract

Three new multi-dimensional coordination polymers, namely, [Cd(SIP)(HBPP)(BPP)0.5(H2O)·H2O]n (1), [Zn(L)(BIB)0.5]n (2), and {[Cd2(L)2(BIB)2](H2O)7}n (3) (H3SIP = 5-sulfo-1,3-benzenedicarboxylate, BPP = 1,3-bis(4-pyridyl)propane, H2L = 4-oxyacetate-benzoic acid, and BIB = 1,4-bis(imidazol-1-yl)-butane), were hydrothermally synthesized by self-assembly of the flexible N-donor ligand and the polycarboxylate ligands. Single crystal X-ray analyses reveal that complexes 13 possess different structural features. The Cd(II) atom in complex 1 is seven-coordinated by two bidentate chelating carboxylate groups and two nitrogen atoms as well as one water molecule. The adjacent Cd(II) atoms are bridged by two carboxylate groups to form 1D chains running along different directions, which are connected by BPP ligands to generate 2D network. The resulting 2D networks are further linked by hydrogen-bond interactions, affording a 3D supramolecular architecture. In complex 2, the [Zn2(COO)4] units are bridged by L2− ligands to generate 1D double chain structure and then linked by BIB ligands to give 2D grid framework. In complex 3, the [Cd(L2)]n and [Cd(BIB)]n helixes are alternately arranged, leading to the formation of a 2D bilayer structure.

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References

  1. J.R. Li, J.L. Sculley, H.C. Zhou, Chem. Rev. 112, 869 (2012)

    Article  CAS  Google Scholar 

  2. J. An, S.J. Geib, N.L. Rosi, J. Am. Chem. Soc. 131, 8376 (2009)

    Article  CAS  Google Scholar 

  3. X.Z. Song, S.Y. Song, C. Qin, S.Q. Su, S.N. Zhao, M. Zhu, Z.M. Hao, H.J. Zhang, Cryst. Growth Des. 12, 253 (2012)

    Article  CAS  Google Scholar 

  4. D.S. Li, J. Zhao, Y.P. Wu, B. Liu, L. Bai, K. Zou, M. Du, Inorg. Chem. 52, 8091 (2013)

    Article  CAS  Google Scholar 

  5. W.H. Zhang, Y.Y. Wang, E.K. Lermontova, G.P. Yang, B. Liu, J.C. Jin, Z. Dong, Q.Z. Shi, Cryst. Growth Des. 10, 76 (2010)

    Article  CAS  Google Scholar 

  6. Z.B. Han, X.N. Cheng, X.M. Chen, Cryst. Growth Des. 5, 695 (2005)

    Article  CAS  Google Scholar 

  7. L.F. Ma, L.Y. Wang, J.L. Hu, Y.Y. Wang, G.P. Yang, Cryst. Growth Des. 9, 5334 (2009)

    Article  CAS  Google Scholar 

  8. D.S. Li, Y.P. Wu, J. Zhao, J. Zhang, J.Y. Lu, Coord. Chem. Rev. 261, 1 (2014)

    Article  CAS  Google Scholar 

  9. S.S. Chen, J. Fan, T.-A. Okamura, M.S. Chen, Z. Su, W.Y. Sun, N. Ueyama, Cryst. Growth Des. 10, 812 (2010)

    Article  CAS  Google Scholar 

  10. Y.L. Wang, D.Q. Yuan, W.H. Bi, X. Li, X.J. Li, F. Li, R. Cao, Cryst. Growth Des. 5, 1849 (2005)

    Article  CAS  Google Scholar 

  11. Y.H. Zhou, J. Inorg. Organomet. Polym. 23, 458 (2013)

    Article  CAS  Google Scholar 

  12. Y.H. Zhou, J. Inorg. Organomet. Polym. 23, 1189 (2013)

    Article  CAS  Google Scholar 

  13. D.S. Li, P. Zhang, J. Zhao, Z.F. Fang, M. Du, K. Zou, Y.Q. Mu, Cryst. Growth Des. 12, 1697 (2012)

    Article  CAS  Google Scholar 

  14. P.W. Liu, C.P. Li, Y. Bi, J. Chen, J. Coord. Chem. 66, 2012 (2013)

    Article  CAS  Google Scholar 

  15. X.L. Wang, Y. Qu, G.C. Liu, J. Luan, H.Y. Lin, Inorg. Chim. Acta 399, 105 (2013)

    Article  CAS  Google Scholar 

  16. E.C. Yang, Z.Y. Liu, C.H. Zhang, Y.L. Yang, X. Zhao, Dalton Trans. 42, 1581 (2013)

    Article  CAS  Google Scholar 

  17. R. Abhinandan, K.J. Swapan, B. Madhusudan, H. Debdoot, S.C. Durga, Z. Ennio, D. Sudipta, J. Solid State Chem. 197, 46 (2013)

    Article  Google Scholar 

  18. Z.Y. Liu, B. Ding, E.C. Yang, X. Zhao, J. Dalton Trans. 41, 9611 (2012)

    Article  CAS  Google Scholar 

  19. C.P. Li, Q. Yu, J. Chen, M. Du, Cryst. Growth Des. 10, 2650 (2010)

    Article  CAS  Google Scholar 

  20. C.P. Li, J. Chen, Q. Yu, M. Du, Cryst. Growth Des. 10, 1623 (2010)

    Article  CAS  Google Scholar 

  21. X.Y. Cao, Z.J. Li, J. Zhang, Y.Y. Qin, J.K. Cheng, Y.G. Yao, Cryst EngComm 10, 1345 (2008)

    Article  CAS  Google Scholar 

  22. X.Y. Cao, J. Zhang, Z.J. Li, J.K. Cheng, Y.G. Yao, CrystEngComm 9, 806 (2007)

    Article  CAS  Google Scholar 

  23. X.Y. Cao, J. Zhang, J.K. Cheng, Y. Kang, Y.G. Yao, CrystEngComm 6, 315 (2004)

    Article  CAS  Google Scholar 

  24. M. Bao, B.D. Liu, Z.G. Ning, J. Northeast Norm. Univ. 50 (1994)

  25. J. Yang, J.F. Ma, Y.Y. Liu, J.C. Ma, H.Q. Jia, N.H. Hu, Eur. J. Inorg. Chem. 2006, 1208 (2006)

    Article  Google Scholar 

  26. G.M. Sheldrick, Acta Cryst. A64, 112 (2008)

    Article  Google Scholar 

  27. P. Lin, W. Clegg, R.W. Harrington, R.A. Henderson, A.J. Fletcher, J. Bell, K.M. Thomas, Inorg. Chem. 45, 4284 (2006)

    Article  CAS  Google Scholar 

  28. J. Zhang, Y.B. Chen, S.M. Chen, Z.J. Li, J.K. Cheng, Y.G. Yao, Inorg. Chem. 45, 3161 (2006)

    Article  CAS  Google Scholar 

  29. Y. Xu, F. Luo, Y.X. Che, J.M. Zheng, Inorg. Chem. Commun. 13, 1489–1492 (2010)

    Article  CAS  Google Scholar 

  30. M.Y. Wu, F.L. Jiang, W. Wei, Q. Gao, Y.G. Huang, L. Chen, M.C. Hong, Cryst. Growth Des. 9, 2559 (2009)

    Article  CAS  Google Scholar 

  31. M.C. Das, H. Xu, S.C. Xiang, Z.J. Zhang, H.D. Arman, G.D. Qian, B.L. Chen, Chem. Eur. J. 17, 7817 (2011)

    Article  CAS  Google Scholar 

  32. Q.Y. Liu, L. Xu, Inorg. Chem. Commun. 8, 401 (2005)

    Article  CAS  Google Scholar 

  33. C.J. Wang, K.F. Yue, Z.X. Tu, L.L. Xu, Y.L. Liu, Y.Y. Wang, Cryst. Growth Des. 11, 2897 (2011)

    Article  CAS  Google Scholar 

  34. J. Tao, J.X. Shi, M.L. Tong, X.X. Zhang, X.M. Chen, Inorg. Chem. 40, 6328 (2001)

    Article  CAS  Google Scholar 

  35. V.W.W. Yam, K.K.W. Lo, Chem. Soc. Rev. 28, 323 (1999)

    Article  CAS  Google Scholar 

  36. W. Chen, J.Y. Wang, C. Chen, Q. Yue, H.M. Yuan, J.S. Chen, S.N. Wang, Inorg. Chem. 42, 944 (2003)

    Article  CAS  Google Scholar 

  37. S.L. Zheng, J.H. Yang, X.L. Yu, X.M. Chen, W.T. Wong, Inorg. Chem. 43, 830 (2004)

    Article  CAS  Google Scholar 

  38. S. Basak, S. Sen, C. Marschner, J. Baumgartner, S.R. Batten, D.R. Turner, S. Mitra, Polyhedron 27, 1193 (2008)

    Article  CAS  Google Scholar 

  39. H. Hadadzadeh, S.R. Hosseinian, S.J.A. Fatemi, Polyhedron 28, 2776 (2009)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the Natural Science Foundation of Anhui Provincial Education Department (KJ2014A228).

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Correspondence to Yong-Hong Zhou.

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Zhou, YH. Three Novel Cd(II) and Zn(II) Coordination Polymers with O-, N-donor Ligands: Syntheses, Structures, and Photoluminescence Properties. J Inorg Organomet Polym 25, 535–543 (2015). https://doi.org/10.1007/s10904-014-0113-1

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  • DOI: https://doi.org/10.1007/s10904-014-0113-1

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