Skip to main content
Log in

Synthesis, Structures and Fluorescent Properties of Four Coordination Polymers Networks Based on Mixed Ligands

Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

Four new polymers, [Zn(qda)(phen)]n (1), {[Zn3(qda)3(bpy)2]·2DMF}n (2), {[Cd3(qda)3(phen)2]·H2O}n (3) and {[Cd3(qda)3(bpy)2]·H2O}n (4), (H2qda = Hydroquinone-O, O′-diacetic acid, bpy = 2,2′-bipyridine, and phen = 1,10-phenanthroline), have been synthesized and characterized by single crystal X-ray diffraction analysis, powder X-ray diffraction, FTIR and elemental analysis. Compound 1 exhibits one dimensional zigzag chain and compounds 24 show isomorphous two dimension. In addition, photoluminescence for 14 have been investigated in the solid state at room temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

References

  1. J.P. Zhang, Y.B. Zhang, J.B. Lin, X.M. Chen, Chem. Rev. 112, 1001 (2012)

    Article  CAS  Google Scholar 

  2. J.M. Roberts, B.M. Fini, A.A. Sarjeant, O.K. Farha, J.T. Hupp, K.A. Scheidt, J. Am. Chem. Soc. 134, 3334 (2012)

    Article  CAS  Google Scholar 

  3. M.P. Suh, H.J. Park, T.K. Prasad, D.W. Lim, Chem. Rev. 112, 782 (2012)

    Article  CAS  Google Scholar 

  4. J.P. Zou, Q. Peng, Z.H. Wen, G.S. Zeng, Q.J. Xing, G.C. Guo, Cryst. Growth Des. 10, 2613 (2010)

    Article  CAS  Google Scholar 

  5. S.H. Zhang, R.X. Zhao, G. Li, H.Y. Zhang, Q.P. Huang, F.P. Liang, J. Solid State Chem. 220, 206 (2014)

    Article  CAS  Google Scholar 

  6. R.X. Zhao, S.H. Zhang, H.Y. Zhang, G. Li, G.H. Ding, H.P. Li, J. Clust. Sci. (2014). doi:10.1007/s1087601407870

    Google Scholar 

  7. B.H. Ye, M.L. Tong, X.M. Chen, Coord. Chem. Rev. 249, 545 (2005)

    Article  CAS  Google Scholar 

  8. W. Zhang, H.Y. Ye, R.G. Xiong, Coord. Chem. Rev. 253, 2980 (2009)

    Article  CAS  Google Scholar 

  9. C. Wang, W.B. Lin, J. Am. Chem. Soc. 133, 4232 (2011)

    Article  CAS  Google Scholar 

  10. D.X. Xue, A.J. Cairns, Y. Belmabkhout, L. Wojtas, Y. Liu, M.H. Alkordi, M. Eddaoudi, J. Am. Chem. Soc. 135, 7660 (2013)

    Article  CAS  Google Scholar 

  11. F.N. Dai, H.Y. He, D.L. Gao, F. Ye, X.L. Qiu, D.F. Sun, CrystEngComm 11, 2516 (2009)

    Article  CAS  Google Scholar 

  12. B.Y. Li, G.H. Li, D. Liu, Y. Peng, X.J. Zhou, J. Hua, Z. Shi, S.H. Feng, CrystEngComm 13, 1291 (2011)

    Article  CAS  Google Scholar 

  13. Q.L. Zhu, T.L. Sheng, R.B. Fu, S.M. Hu, C.J. Shen, X. Ma, X.T. Wu, CrystEngComm 13, 2096 (2011)

    Article  CAS  Google Scholar 

  14. R. Łyszczek, L. Mazur, Inorg. Chem. Commun. 15, 121 (2012)

    Article  Google Scholar 

  15. B.Y. Zhu, J. Inorg. Organomet. Polym. 22, 1069 (2012)

    Article  CAS  Google Scholar 

  16. B.Y. Zhu, X.L. Zhang, F. Guo, X.H. Liu, Inorg. Chim. Acta 391, 58 (2012)

    Article  CAS  Google Scholar 

  17. J.H. Cui, Q.X. Yang, Y.Z. Li, Z.J. Guo, H.G. Zheng, Cryst. Growth Des. 13, 1694 (2013)

    Article  CAS  Google Scholar 

  18. J.J. Zhang, L. Wojtas, R.W. Larsen, M. Eddaoudi, M. Zaworotko, J. Am. Chem. Soc. 131, 17040 (2009)

    Article  CAS  Google Scholar 

  19. M. Sadakiyo, H. Okawa, A. Shigematsu, M. Ohba, T. Yamada, H. Kitagawa, J. Am. Chem. Soc. 134, 5472 (2012)

    Article  CAS  Google Scholar 

  20. Q.S. Zheng, F.L. Yang, M.L. Deng, Y. Ling, X.F. Liu, Z.X. Chen, Y.H. Wang, L.H. Weng, Y.M. Zhou, Inorg. Chem. 52, 10368 (2013)

    Article  CAS  Google Scholar 

  21. J.W. Liu, L.H. Huo, S. Gao, S.W. Ng, Acta Crystallogr., Sect. E 60, m439 (2004)

    Article  CAS  Google Scholar 

  22. Bruker, SMART and SAINT, Bruker AXS Inc., Madison, Wisconsin, USA (2007).

  23. Bruker, SADABS, Bruker AXS Inc., Madison, Wisconsin, USA (2001).

  24. A. Altomare, M.C. Burla, M. Camalli, G.L. Cascarano, C. Giacovazzo, A. Guagliardi, A.G.G. Moliterni, G. Polidori, R. Spagna, J. Appl. Cryst. 32, 115 (1999)

    Article  CAS  Google Scholar 

  25. G.M. Sheldrick, Acta Cryst. A64, 112 (2008)

    Article  Google Scholar 

  26. L.J. Farrugia, J. Appl. Cryst. 32, 837 (1999)

    Article  CAS  Google Scholar 

  27. C. Li, D.S. Li, J. Zhao, Y.Q. Mou, K. Zou, S.Z. Xiao, M. Du, CrystEngComm 13, 6601 (2011)

    Article  CAS  Google Scholar 

  28. Y. Xiao, P. Huang, W. Wang, J. Clust. Sci. (2014). doi:10.1007/s10876-014-0799-9

    Google Scholar 

  29. R.Q. Zou, H. Sakurai, S. Han, R.Q. Zhong, Q. Xu, J. Am. Chem. Soc. 129, 8402 (2007)

    Article  CAS  Google Scholar 

  30. E.Y. Lee, S.Y. Jang, M.P. Suh, J. Am. Chem. Soc. 127, 6374 (2005)

    Article  CAS  Google Scholar 

  31. M.D. Allendorf, C.A. Bauer, R.K. Bhakta, R.J.T. Houk, Chem. Soc. Rev. 38, 1330 (2009)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors gratefully acknowledge the financial support from the Project of Shandong Province Higher Educational Science and Technology Program (Grant No. J11LB56) and the National Natural Science Foundation of China (Grant No. 21371028).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Baoyong Zhu.

Electronic supplementary material

Below is the link to the electronic supplementary material.

10904_2014_110_MOESM1_ESM.tif

Fig. S1 The simulated and experimental PXRD patterns for compound 1(A), compound 2(B), compound 3(C) and compound 4(D). Supplementary material 1 (TIFF 136 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhao, R., Zhu, B. Synthesis, Structures and Fluorescent Properties of Four Coordination Polymers Networks Based on Mixed Ligands. J Inorg Organomet Polym 25, 529–534 (2015). https://doi.org/10.1007/s10904-014-0110-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-014-0110-4

Keywords

Navigation