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Synthesis and Electric Modulus Formalism of Novel Metal-Phthalocyanine Bridged Polymers

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Abstract

Novel nickel and copper phthalocyanine polymers, with uniformly carboxylic end groups and carbonyl groups as bridges linking the phthalocyanine units, were successfully prepared. Structural modelling and atomic absorption spectroscopy confirmed the network polymeric structure and suggested at least nine phthalocyanine units in each polymeric network. The dielectric properties of the prepared polymers were investigated over a wide range of frequencies at room temperature. The electric modulus formalism was used to study the conductivity relaxation in the prepared polymers. The collapsing of the real part of the conductivity function, σ’, at higher frequencies for both materials was observed indicating that the local molecular dynamics is due to the polymer conjugated backbone (functional and/or terminal groups) with no clear effect of the central metal.

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References

  1. H.F. Moser, A.L. Thomas, Phthalocyanine compounds (Reinhold, New York, 1963)

    Google Scholar 

  2. D. Woehrle, V. Schmidt, B. Schumann, A. Yamada, K. Shigehara, Ber. Bunsenges. Phys. Chem. 91, 975–981 (1987)

    Article  CAS  Google Scholar 

  3. C.S. Marvel, J.H. Rassweiler, J. Am. Chem. Soc. 80, 1197 (1958)

    Article  CAS  Google Scholar 

  4. N. Namba (ed.), Phthalocyanine-Chemistry and Functions (IPC, Tokyo, 1997)

  5. M. Ottmar, D. Hohnholz, A. Wedel, M. Hanack, Synth. Met. 105, 145–149 (1999)

    Article  CAS  Google Scholar 

  6. C. Boscornea, St. Tomas, L.G. Hinescu, C. Tarabasaanu-Mihaila, J. Mater. Process. Technol. 119, 344–347 (2001)

    Article  CAS  Google Scholar 

  7. A.W. Snow, J. R. Griffith In Encyclopaedia of Polymer Science and Engineering, Vol. 11, (Wiley and Sons, New York, 1988) pp. 212–225

  8. M.R. Willis, Mol. Cryst. Liq. Cryst. 171, 217–234 (1989)

    Google Scholar 

  9. B. Neil, McKeown, Phthalocyanine Materials: Synthesis, Structure and Function (Cambridge University Press, Cambridge, 1998)

  10. W. Darwish, G. Turky, J. Inorg. Organomet. Polym. 24, 347–354 (2014)

    Article  CAS  Google Scholar 

  11. H.S. Nalwa (ed.), Handbook of Low and High Dielectric Constant Materials and their Application Vol. 1, Chapter 8; Vol. 2, Chapter 9 (Academic Press, San Diego, 1999)

  12. M. Guo, X. Yan, Y. Kwon, T. Hayakawa, M. Kakimoto, T. Goodson, J. Am. Chem. Soc. 128, 14820–14821 (2006)

    Article  CAS  Google Scholar 

  13. D. Woehrle, E. Preussner, Makromol. Chem. 186, 2189–2207 (1985). references cited therein

  14. D. Woehrle, U. Marose, R. Knoop, Makromol. Chem. 186, 2209–2228 (1985)

    Article  CAS  Google Scholar 

  15. D. Woehrle, G. Meyer, Makromol. Chem. 181, 2127–2135 (1980)

    Article  CAS  Google Scholar 

  16. D. Woehrle, B. Schulte, Makromol. Chem. 186, 2229–2245 (1985)

    Article  CAS  Google Scholar 

  17. H. Yanagi, M. Wada, Y. Ueda, M. Ashida, D. Woehrle, Macromol. Chem. Phys. (Makromol. Chem.) 193, 1903–1911 (1992)

    Article  CAS  Google Scholar 

  18. J.H. Tian, I.J. Wang, Dyes Pigm. 29, 169–179 (1995)

    Article  CAS  Google Scholar 

  19. J.H. Tian, I.J. Wang, Dyes Pigm. 29, 181–190 (1995)

    Article  CAS  Google Scholar 

  20. W.C. Drinkard, J.C. Bailar Jr, J. Am. Chem. Soc. 81, 4795–4797 (1959)

    Article  CAS  Google Scholar 

  21. N. Masilela, T. Nyokong, Dyes Pigm. 84, 242–248 (2010)

    Article  CAS  Google Scholar 

  22. V. Iliev, A. Mihaylova, J. Photochem. Photobiol. A 149, 23–30 (2002)

    Article  CAS  Google Scholar 

  23. B.N. Achar, K.S. Lokesh, J. Organomet. Chem. 689, 2601–2605 (2004)

    Article  CAS  Google Scholar 

  24. D. Woehrle, U. Huendorf, Makromol. Chem. 186, 2177–2178 (1985)

    Article  CAS  Google Scholar 

  25. L.K. Lee, N.H. sabelli, P.R. Le Breton, J. Phys. Chem. 86, 3926–3931 (1982)

    Article  CAS  Google Scholar 

  26. E.S. Dodsworth, A.B.P. Lever, P. Seymour, C.C. Leznoff, J. Phys. Chem. 89, 5698–5705 (1985)

    Article  CAS  Google Scholar 

  27. N. Kobayashi, A.B.P. Lever, J. Am. Chem. Soc. 109, 7433–7441 (1987)

    Article  CAS  Google Scholar 

  28. M.N. Yarasir, M. Kandaz, A. Koca, B. Salih, Polyhedron 26, 1139 (2007)

    Article  CAS  Google Scholar 

  29. M. Gouterman, D. Dolphin, The Porphyrins, vol. 1 (Springer, London, 1990), p. 123

  30. D.R. Boston, J.C. Bailar Jr, Inorg. Chem. 11, 1578–1583 (1972)

    Article  CAS  Google Scholar 

  31. M. Mudarra, J. Belana, J.C. Ca˜nadas, J.A. Diego, J. Sellar`es, R. D´ıaz-Calleja, M.J. Sanchis, J. Appl. Phys. 88, 4807–4812 (2000)

    Article  CAS  Google Scholar 

  32. Lu Hongbo, Xingyuan Zhang, Hui Zhang, J. Appl. Phys. 100, 054104–054107 (2006)

    Article  Google Scholar 

  33. S. Lanfredi, P.S. Saia, R. Lebullenger, A.C. Hernandes, Solid State Ionics 146, 329–339 (2002)

    Article  CAS  Google Scholar 

  34. A. Rivera, J. Santamarıa, C. Le, Appl. Phys. Lett. 78, 610–612 (2001)

    Article  CAS  Google Scholar 

  35. J. Liu, C. Duan, W. Yin, W.N. Mei, R.W. Smith, J.R. Hardy, J. Chem. Phys. 119, 2812–2819 (2003)

    Article  CAS  Google Scholar 

  36. G.C. Psarras, E. Manolakaki, G.M. Tsangaris, Composites Part A 34, 1187–1198 (2003)

    Article  Google Scholar 

Download references

Acknowledgments

We are grateful for the financial support of (National Research Centre, Dokki, Giza, Egypt) within the In-house research project number 914-01-02.

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Authors and Affiliations

  1. Department of Polymers and Pigments, National Research Centre, Elbohooth Street, Dokki, Giza, 12622, Egypt

    Wael M. Darwish & Mahmoud A. Abd El-Ghaffar

  2. Department of Microwave Physics and Dielectrics, National Research Centre, Elbohooth Street, Dokki, Giza, 12622, Egypt

    Gamal M. Turky

Authors
  1. Wael M. Darwish
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  2. Mahmoud A. Abd El-Ghaffar
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  3. Gamal M. Turky
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Corresponding author

Correspondence to Wael M. Darwish.

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Darwish, W.M., Abd El-Ghaffar, M.A. & Turky, G.M. Synthesis and Electric Modulus Formalism of Novel Metal-Phthalocyanine Bridged Polymers. J Inorg Organomet Polym 24, 858–864 (2014). https://doi.org/10.1007/s10904-014-0055-7

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