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Urothermal Synthesis of a New Cd(II)-Terephthalate: Synthesis, Structure, CO2 Adsorption and Luminescent Properties

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Abstract

A new Cd(II) compound, namely [Cd(pbdc)(e-urea)]n (1 H2pbdc = terephthalic acid, e-urea = ethyleneurea), has been synthesized by urothermal reactions of Cd(NO3)2, and H2pbdc. Single crystal X-ray analysis reveals that it features a three-dimensional framework based on Cd(II)-carboxylate inorganic chains. The coordinated e-urea molecules are filled in the rhombic channels. Thermal analysis reveals that it can be stable up to 350 °C. The CO2 adsorption and luminescent properties of compound 1 were also investigated.

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References

  1. S.T. Zheng, T. Wu, J. Zhang, M. Chow, R.A. Nieto, P.Y. Feng, X.H. Bu, Angew. Chem. Int. Ed. 49, 5362 (2010)

    Article  CAS  Google Scholar 

  2. J.M. Taylor, K.W. Dawson, G.K.H. Shimizu, J. Am. Chem. Soc. 135, 1193 (2013)

    Article  CAS  Google Scholar 

  3. Z. Yin, Q.X. Wang, M.H. Zeng, J. Am. Chem. Soc. 134, 4857 (2012)

    Article  CAS  Google Scholar 

  4. R.X. Yao, X. Xu, X.M. Zhang, Chem. Mater. 24, 303 (2012)

    Article  CAS  Google Scholar 

  5. X. Zhang, Y.Y. Huang, Q.P. Lin, J. Zhang, Y.G. Yao, Dalton Trans. 42, 2294 (2013)

    Article  CAS  Google Scholar 

  6. L. Zhou, C.G. Wang, X.F. Zheng, Z.F. Tian, L.L. Wen, H. Qu, D.F. Li, Dalton Trans. 42, 16375 (2013)

    Article  CAS  Google Scholar 

  7. X.J. Zhou, C. Chen, C.X. Ren, J.K. Sun, J. Zhang, J. Mater. Chem. C 4, 744 (2103)

    Google Scholar 

  8. K.Z. Du, M.L. Feng, J.R. Li, X.Y. Huang, CrystEngComm 15, 5594 (2013)

    Article  CAS  Google Scholar 

  9. D. Sun, C.F. Yang, H.R. Xu, H.X. Zhao, Z.H. Wei, N. Zhang, L.J. Yu, R.B. Huang, L.S. Zheng, ChemComm 46, 8168 (2010)

    CAS  Google Scholar 

  10. P.X. Yin, J. Zhang, Y.Y. Qin, J.K. Cheng, Z.J. Li, Y.G. Yao, CrystEngComm 13, 3536 (2011)

    Article  CAS  Google Scholar 

  11. J. Zhang, J.T. Bu, S.M. Chen, T. Wu, S.T. Zheng, Y.G. Chen, R.A. Nieto, P.Y. Feng, X.H. Bu, Angew. Chem. Int. Ed. 49, 8876 (2010)

    Article  CAS  Google Scholar 

  12. Z.Q. Jiang, G.Y. Jiang, D.C. Hou, F. Wang, Z. Zhao, CrystEngComm 15, 315 (2013)

    Article  CAS  Google Scholar 

  13. G.M. Sheldrick, SADABS (University of Göttingen, Göttingen, 1996)

    Google Scholar 

  14. G.M. Sheldrick, SHELXL-97: Program for Refining Crystal Structure Refinement, University of Göttingen, Germany, 1997

  15. Y.P. He, Y.X. Tan, J. Zhang, Inorg. Chem. 51, 11232 (2012)

    Article  CAS  Google Scholar 

  16. R. Banerjee, A. Phan, B. Wang, C. Knobler, H. Furukawa, M.O. Yaghi, Science 319, 939 (2008)

    Article  CAS  Google Scholar 

  17. X. Zhang, Y.Y. Huang, J.K. Cheng, Y.G. Yao, J. Zhang, F. Wang, CrystEngComm 14, 4843 (2012)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by Grants from the Sci-technical Support Project of Hebei Province (14227115D).

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Authors and Affiliations

  1. College of Sciences, Agricultural University of Hebei, Baoding, 071001, China

    Yanli Dong, Pingping Zhou & Huimin Liu

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  1. Yanli Dong
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  2. Pingping Zhou
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  3. Huimin Liu
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Correspondence to Huimin Liu.

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Dong, Y., Zhou, P. & Liu, H. Urothermal Synthesis of a New Cd(II)-Terephthalate: Synthesis, Structure, CO2 Adsorption and Luminescent Properties. J Inorg Organomet Polym 24, 874–878 (2014). https://doi.org/10.1007/s10904-014-0053-9

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  • DOI: https://doi.org/10.1007/s10904-014-0053-9

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