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An Organic–Inorganic Hybrid Polymer Based on Molybdenum(V) Phosphate and Cadmium(II) Complex

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Abstract

An unusual organic–inorganic hybrid polymer, [Cd(pztt)(H2O)2]4[CdMo V12 O24(OH)6 (HPO4)4(H2PO4)2(PO4)2]·10H2O (pztt = 3-(pyrazin-2-yl)-5-(1H-1,2,4-triazol-3-yl)-1,2,4-triazliyi) (1), have been hydrothermally synthesized and structurally characterized by the elemental analysis, TG, IR, UV–Vis, PXRD and the single-crystal X-ray diffraction. In compound 1, the sandwich-type {Cd[Mo6P4O31]2} units are modified with Cd(pztt)(H2O)2 fragments to lead bi-supported dimer clusters, which are further linked by binuclear complex subunits [Cd2(pztt)2(H2O)4] to yield unusual 1-D chains. The 1-D chains are further packed into 2-D and 3-D supramolecular assemblies via strong hydrogen-bonding interactions. In addition, the electrochemical behavior of 1-CPE and the photoluminescence properties of 1 in the solid state at room temperature have been investigated in detail.

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References

  1. P. Gouzerh, A. Proust, Chem. Rev. 98, 77 (1998)

    Article  CAS  Google Scholar 

  2. R.B. Getman, Y.S. Bae, C.E. Wilmer, R.Q. Snurr, Chem. Rev. 112, 703 (2012)

    Article  CAS  Google Scholar 

  3. P. Horcajada, R. Gref, T. Baati, P.K. Allan, G. Maurin, P. Couvreur, G. Férey, R.E. Morris, C. Serre, Chem. Rev. 112, 1232 (2012)

    Article  CAS  Google Scholar 

  4. Y.Z. Li, J. Luo, Y.T. Zhang, J.W. Zhao, L.J. Chen, P.T. Ma, J.Y. Niu, J. Solid State Chem. 205, 82 (2013)

    Article  CAS  Google Scholar 

  5. C. Lydon, C. Busche, H.N. Miras, A. Delf, D.L. Long, L. Yellowlees, L. Cronin, Angew. Chem. Int. Ed. 51, 2115 (2012)

    Article  CAS  Google Scholar 

  6. P. Yin, C.P. Pradeep, B.F. Zhang, F.Y. Li, C. Lydon, M.H. Rosnes, L. Dong, E. Bitterlich, L. Xu, L. Cronin, T.B. Liu, Chem. Eur. J. 18, 8157 (2012)

    Article  CAS  Google Scholar 

  7. L.A. Meyer, R.C. Haushalter, Inorg. Chem. 32, 1579 (1993)

    Article  CAS  Google Scholar 

  8. R.C. Haushalter, F.W. Lai, Inorg. Chem. 28, 2904 (1989)

    Article  CAS  Google Scholar 

  9. A. Muller, S. Dillinger, E. Krickemeyer, H. Bogge, W. Plass, A. Stammler, R.C. Haushalter, Z. Naturforsch, Teil B. 52, 1301 (1997)

    Google Scholar 

  10. D.L. Long, E. Burkholder, L. Cronin, Chem. Soc. Rev. 36, 105 (2007)

    Article  CAS  Google Scholar 

  11. M. Yuan, E.B. Wang, Y. Lu, Y.G. Li, C.W. Hu, N.H. Hu, H.Q. Jia, J. Solid State Chem. 170, 192 (2003)

    Article  CAS  Google Scholar 

  12. M. Yuan, E.B. Wang, Y. Lu, Y.G. Li, C.W. Hu, N.H. Hu, H.Q. Jia, Inorg. Chem. Commun. 5, 505 (2002)

    Article  CAS  Google Scholar 

  13. H.X. Guo, S.X. Liu, J. Mol. Struct. 741, 229 (2005)

    Article  CAS  Google Scholar 

  14. X. He, P. Zhang, T.Y. Song, Z.C. Mu, J.H. Yu, Y. Wang, J.N. Xu, Polymer 23, 2153 (2004)

    CAS  Google Scholar 

  15. X. Zhang, J.Q. Xu, J.H. Yu, J. Lu, Y. Xu, Y. Chen, T.G. Wang, X.Y. Yu, Q.F. Yang, Q. Hou, J. Solid State Chem. 180, 1949 (2007)

    Article  CAS  Google Scholar 

  16. W.J. Chang, Y.C. Jiang, S.L. Wang, K.H. Lii, Inorg. Chem. 45, 6586 (2006)

    Article  CAS  Google Scholar 

  17. Q.B. Bo, Z.X. Sun, G.X. Sun, Z.W. Zhang, C.L. Chen, Y.X. Li, J. Coord. Chem. 60, 275 (2007)

    Article  CAS  Google Scholar 

  18. A. Leclaire, M.M. Borel, A. Guesdon, R.E. Marsh, J. Solid State. Chem. 159, 7 (2001)

    Article  CAS  Google Scholar 

  19. Y. Ma, Y.G. Li, E.B. Wang, Y. Lu, C. Qin, X.X. Xu, J. Clust. Sci. 17, 167 (2006)

    Article  CAS  Google Scholar 

  20. H.X. Guo, S.X. Liu, J. Mol. Struct. 751, 156 (2005)

    Article  CAS  Google Scholar 

  21. Y. Ma, Y.G. Li, E.B. Wang, Y. Lu, X.L. Wang, D.R. Xiao, X.X. Xu, Inorg. Chim. Acta 360, 421 (2007)

    Article  CAS  Google Scholar 

  22. X.L. Wang, J.J. Cao, G.C. Liu, H.Y. Lin, A.X. Tian, Inorg. Chim. Acta 402, 6 (2013)

    Article  CAS  Google Scholar 

  23. X. Zhang, Z.H. Yi, L.Y. Zhao, Q. Chen, X.L. Wang, J.Q. Xu, W.J. Xia, C. Yang, Cryst. Eng. Comm. 12, 595 (2010)

    Article  CAS  Google Scholar 

  24. Q.Y. Chen, Y. Li, F.K. Zheng, W.Q. Zou, M.F. Wu, G.C. Guo, A.Q. Wu, J.S. Huang, Inorg. Chem. Commun. 11, 969 (2008)

    Article  CAS  Google Scholar 

  25. C. Yang, M.S. Wang, Z.N. Xu, F. Chen, G.N. Liu, G. Xu, G.C. Guo, J.S. Huang, Inorg. Chem. Commun. 13, 326 (2010)

    Article  CAS  Google Scholar 

  26. G.M. Sheldrick, SHELXL 97, Program for Crystal Structure Refinement (University of Gőttingen, Germany, 1997)

    Google Scholar 

  27. G.M. Sheldrick, SHELXL 97, Program for Crystal Structure Solution (University of Gőttingen, Germany, 1997)

    Google Scholar 

  28. I.D. Brown, D. Altermatt, Acta Crystallogr. Sect. B. 41, 244 (1985)

    Article  Google Scholar 

  29. W. Liu, H.H. Thorp, Inorg. Chem. 32, 4102 (1993)

    Article  CAS  Google Scholar 

  30. M.T. Pope, Heteropoly and Isopoly Oxometalates (Springer, Berlin, 1983)

    Book  Google Scholar 

  31. Y. Li, X.H. Zhong, F.K. Zheng, M.F. Wu, Z.F. Liu, G.C. Guo, Inorg. Chem. Commun. 14, 407 (2011)

    Article  CAS  Google Scholar 

  32. Q. Ye, Y.M. Song, G.X. Wang, K. Chen, D.W. Fu, P.W.H. Chan, J.S. Zhu, S.P.D. Huang, R.G. Xiong, J. Am. Chem. Soc. 128, 6554 (2006)

    Article  CAS  Google Scholar 

  33. K. Unoura, N. Tanaka, Inorg. Chem. 22, 2963 (1983)

    Article  CAS  Google Scholar 

  34. H. Fu, W.L. Chen, E.B. Wang, J. Liu, S. Chang, Inorg. Chem. Acta 362, 1412 (2009)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported the National Natural Science Foundation of China (Grants Nos. 21271056 and 21371042), the Natural Science Foundation of Heilongjiang Province [grant number B201306] the Science and Technology Project of Education Office of Heilongjiang Province (No. 12531182).

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Authors and Affiliations

  1. Key Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, School of Chemistry and Chemical Engineering, Harbin Normal University, Harbin, 150025, People’s Republic of China

    Yuee Iiu, Kai Yu, Hui Xu, Jinghan Wang, Zhanhua Su, Baibin Zhou & Qun Wang

  2. Key Laboratory of Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, Harbin Normal University, Harbin, 150025, People’s Republic of China

    Yuee Iiu, Kai Yu, Hui Xu, Jinghan Wang, Zhanhua Su, Baibin Zhou & Qun Wang

Authors
  1. Yuee Iiu
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  2. Kai Yu
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  3. Hui Xu
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  4. Jinghan Wang
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  5. Zhanhua Su
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Correspondence to Zhanhua Su or Qun Wang.

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Iiu, Y., Yu, K., Xu, H. et al. An Organic–Inorganic Hybrid Polymer Based on Molybdenum(V) Phosphate and Cadmium(II) Complex. J Inorg Organomet Polym 24, 759–765 (2014). https://doi.org/10.1007/s10904-014-0029-9

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  • DOI: https://doi.org/10.1007/s10904-014-0029-9

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