Journal of Inorganic and Organometallic Polymers and Materials

, Volume 23, Issue 2, pp 418–423

A Photoluminescent Polymeric 2D Silver(I) Complex Exhibits a Fishbone-like 1D Silver Cluster and New Coordination Mode of the Pyridine-2,3-Dicarboxylate

Authors

    • Department of Chemistry, Faculty of Arts and SciencesDumlupınar University
  • Gönül Pamuk
    • Department of Chemistry, Faculty of Arts and SciencesDumlupınar University
  • Nazlı Uzun
    • Department of Chemistry, Faculty of Arts and SciencesDumlupınar University
  • Okan Zafer Yeşilel
    • Department of Chemistry, Faculty of Arts and SciencesEskişehir Osmangazi University
  • Fatih Semerci
    • Department of Chemistry, Faculty of Arts and SciencesKırklareli University
  • Handan Günay
    • Department of Chemistry, Faculty of Arts and SciencesDumlupınar University
  • Orhan Büyükgüngör
    • Department of Physics, Faculty of Arts and SciencesOndokuz Mayıs University
Article

DOI: 10.1007/s10904-012-9798-1

Cite this article as:
Çolak, A.T., Pamuk, G., Uzun, N. et al. J Inorg Organomet Polym (2013) 23: 418. doi:10.1007/s10904-012-9798-1

Abstract

In this study, a novel organic–inorganic hybrid compound with AgNO3 and 2,3-pyridinedicarboxylic acid (H2pydc), [Ag26-pydc)]n (1) has been synthesized. The molecular structure of complex has been determined by the single crystal X-ray diffraction. The complex has been observed to crystallize in the monoclinic space group P21/c. The asymmetric unit of compound consists of two crystallographically different Ag(I) centers and one pydc ligand. The Ag1 and Ag2 adopt tetrahedral and T-shaped geometries, respectively. At the same time, the silver(I) compound consists of a fish bone similar to the 1D silver cluster. Furthermore, novel coordination mode shown by H2pydc indicates that the crystal exhibits photoluminescence in the solid state at room temperature.

Keywords

Pyridine-2,3-dicarboxylate complex Silver(I) complex Silver cluster Photoluminescent silver complex

Supplementary material

10904_2012_9798_MOESM1_ESM.doc (92 kb)
Supplementary material 1 (DOC 91 kb)

Copyright information

© Springer Science+Business Media New York 2012