Journal of Inorganic and Organometallic Polymers and Materials

, 18:472

A Nano-Hybrid of Molybdenum Oxide Intercalated by Dithiocarbamate as an Oxidation Catalyst

  • Maryam Afsharpour
  • Alireza Mahjoub
  • Mostafa M. Amini
Article

DOI: 10.1007/s10904-008-9223-y

Cite this article as:
Afsharpour, M., Mahjoub, A. & Amini, M.M. J Inorg Organomet Polym (2008) 18: 472. doi:10.1007/s10904-008-9223-y

Abstract

A novel nano-layered material based on molybdenum oxide has been synthesized by hydrothermal method using dithiocarbamate. On the basis of the X-ray diffraction, scanning electron microscopy, thermal analysis and infrared spectroscopy results, a possible arrangement of organic ligands in the interlayer space of molybdenum oxide has been proposed. Moreover, the catalytic activity of the synthesized nanohybrid of molybdenum oxide was investigated in oxygen transfer reactions. This reagent can oxidize alkenes, alcohols, sulfides, and amines in the presence of hydrogen peroxide with high yield and selectivity.

Keywords

Oxidation catalystHybrid materialsMolybdenum oxideDithiocarbamate

Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  • Maryam Afsharpour
    • 1
  • Alireza Mahjoub
    • 1
  • Mostafa M. Amini
    • 2
  1. 1.Department of Chemistry, Faculty of ScienceTarbiat Modares UniversityTehranIran
  2. 2.Department of ChemistryShahid Beheshti UniversityTehranIran