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Application of Partial Least Square (PLS) Analysis on Fluorescence Data of 8-Anilinonaphthalene-1-Sulfonic Acid, a Polarity Dye, for Monitoring Water Adulteration in Ethanol Fuel

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Abstract

Fluorescence characteristic of 8-anilinonaphthalene-1-sulfonic acid (ANS) in ethanol-water mixture in combination with partial least square (PLS) analysis was used to propose a simple and sensitive analytical procedure for monitoring the adulteration of ethanol by water. The proposed analytical procedure was found to be capable of detecting even small adulteration level of ethanol by water. The robustness of the procedure is evident from the statistical parameters such as square of correlation coefficient (R2), root mean square of calibration (RMSEC) and root mean square of prediction (RMSEP) that were found to be well with in the acceptable limits.

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Acknowledgments

Authors thank Council of Scientific and Industrial Research (CSIR), New Delhi, India for providing the financial support to carryout the work.

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Authors and Affiliations

  1. Department of Chemistry, Indian Institute of Technology-Madras, Chennai, 600036, India

    Keshav Kumar & Ashok Kumar Mishra

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  1. Keshav Kumar
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  2. Ashok Kumar Mishra
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Correspondence to Keshav Kumar.

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Kumar, K., Mishra, A.K. Application of Partial Least Square (PLS) Analysis on Fluorescence Data of 8-Anilinonaphthalene-1-Sulfonic Acid, a Polarity Dye, for Monitoring Water Adulteration in Ethanol Fuel. J Fluoresc 25, 1055–1061 (2015). https://doi.org/10.1007/s10895-015-1592-3

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  • DOI: https://doi.org/10.1007/s10895-015-1592-3

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