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Hydrothermal Synthesis, Crystal Structure, and Catalytic Performance of Four Organic–Inorganic Hybrids Based on Polyoxometalates and O/N-Containing Groups

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Abstract

Four new network organic–inorganic hybrid supramolecular compounds [PW12O40](C2H4N3)3·6H2O (1), [PMo12O40](C2H4N3)3·6H2O (2), [H4SiW12O40]8[C6NO2H4]4[C6NO2H5]16[C5NH6]4·39H2O (3) and [H3VW12O40] (C6H6NO2)2(CHO2)2·4H2O (4) composed by keggin type heteropolyanion and O/N-containing organic groups of 1H-1,2,4-Triazole or 2,3-Pyridinedicarboxylic acid have been successfully synthesized by hydrothermally method, and characterized by infrared spectrum (IR), thermogravimetric–differentialthermal analysis (TG–DTA), cyclic voltammetry (CV) and single crystal X-ray diffraction (XRD). Compounds 1–4 exhibit three dimensional supramolecular network via hydrogen bonds and/or π–π stacking interactions. These compounds exhibit good thermal stability and catalytic ability. They are active for catalytic oxidation of methanol in a continuous-flow fixed-bed micro-reactor, when the initial concentration of methanol is 2.5 g m−3 in air and flow rate is 10 mL min−1, the corresponding elimination rates of methanol are 65% (125 °C), 85% (125 °C), 94% (150 °C), and 80% (125 °C), respectively.

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Acknowledgements

This work was supported by Scientific Research Project of Hunan Province Education Department of China (Project No. 14C0459); Key Laboratory of Theoretical Organic Chemistry and Functional Molecules of Ministry of Education and the Organic Chemistry Key Subject of Hunan Province of China.

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Authors and Affiliations

  1. Key Laboratory of Theoretical Organic Chemistry and Functional Molecule for Ministry of Education, Hunan University of Science and Technology, Xiangtan, 411201, China

    Chunlin Teng, Yuzhe Han, Hanxi Xiao, Xizi Luo, Jiaomei Cui & Qian Deng

  2. School of Chemistry, Sun Yat-sen University, Guangzhou, 510275, China

    Chunlin Teng

  3. School of Chemistry, Southern University of Science and Technology of China, Shenzhen, 518055, China

    Yuzhe Han

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  1. Chunlin Teng
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  2. Yuzhe Han
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Correspondence to Qian Deng.

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Teng, C., Han, Y., Xiao, H. et al. Hydrothermal Synthesis, Crystal Structure, and Catalytic Performance of Four Organic–Inorganic Hybrids Based on Polyoxometalates and O/N-Containing Groups. J Clust Sci 28, 2461–2475 (2017). https://doi.org/10.1007/s10876-017-1234-9

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