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Two New Polymeric Haloplumbates Directed by Diammonium Cations: Structures and Properties

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Abstract

Two new haloplumbate/organic hybrids, [(Et2DABCO)2(Pb3I10)] n (1), [(Me2DABCO)2(Pb4I13)(H3O)(H2O)] n (2) (Et2DABCO = N,N′-diethyl-1,4-diazabicyclo[2.2.2] octane, Me2DABCO = N,N′-dimethyl-1,4-diazabicyclo[2.2.2] octane) have been synthesized. Interestingly, their inorganic polymeric haloplumbates of two hybrids exhibit 1-D and 2-D arrangements under the effect of different substitutents on 1,4-diazabicyclo[2.2.2] octane. And the (Pb4I13) 5n−n layer in 2 is a new type of layered iodoplumbates built from the tetranuclear Pb4I15 building units. C–H···I hydrogen bonds in two compounds can be observed. Their absorption spectra were investigated, and energy band gaps of 2.67/2.60 eV indicate their broad-gap semiconductor natures. The fluorescence of 1 was observed and explained by theoretical calculation.

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References

  1. L. M. Wu, X. T. Wu, and L. Chen (2009). Coord. Chem. Rev. 253, 2787.

    Article  CAS  Google Scholar 

  2. S. A. Adonin, M. N. Sokolov, and V. P. Fedin (2016). Coord. Chem. Rev. 312, 1.

    Article  CAS  Google Scholar 

  3. N. Mercier, N. Louvain, and W. H. Bi (2009). CrystEngComm 11, 720.

    Article  CAS  Google Scholar 

  4. W. H. Bi, N. Louvain, N. Mercier, J. Luc, I. Rau, F. Kajzar, and B. Sahraoui (2008). Adv. Mater. 20, 1013.

    Article  CAS  Google Scholar 

  5. G. E. Wang, G. Xu, B. W. Liu, M. S. Wang, M. S. Yao, and G. C. Guo (2016). Angew. Chem. Int. Ed. 55, 514.

    Article  CAS  Google Scholar 

  6. W. X. Chai, L. M. Wu, J. Q. Li, and L. Chen (2007). Inorg. Chem. 46, 1042.

    Article  CAS  Google Scholar 

  7. G. Xu, G. C. Guo, M. S. Wang, Z. J. Zhang, W. T. Chen, and J. S. Huang (2007). Angew. Chem. Int. Ed. 46, 3249.

    Article  CAS  Google Scholar 

  8. M. S. Wang, G. Xu, Z. J. Zhang, and G. C. Guo (2010). Chem. Commun. 46, 361.

    Article  CAS  Google Scholar 

  9. A. Gagor, M. Weclawik, B. Bondzior, and R. Jakubas (2015). CrystEngComm. 27, 3286.

    Article  Google Scholar 

  10. A. M. Goforth, M. A. Tershansy, M. D. Smith, L. Peterson Jr., J. G. Kelley, W. J. DeBenedetti, and H. C. Zur Loye (2011). J. Am. Chem. Soc. 133, 603.

    Article  CAS  Google Scholar 

  11. L. Etgar, P. Gao, Z. S. Xue, Q. Peng, A. K. Chandiran, B. Liu, M. K. Nazeeruddin, and M. Grätzel (2012). J. Am. Chem. Soc. 134, 17396.

    Article  CAS  Google Scholar 

  12. J. A. Christians, R. C. M. Fung, and P. V. Kamat (2014). J. Am. Chem. Soc. 136, 758.

    Article  CAS  Google Scholar 

  13. A. Lemmerer and D. G. Billing (2010). CrystEngComm 12, 1290.

    Article  CAS  Google Scholar 

  14. A. Thorn, R. D. Willett, and B. Twamley (2005). Cryst. Growth Des. 5, 673.

    Article  CAS  Google Scholar 

  15. A. Thorn, R. D. Willett, and B. Twamley (2006). Cryst. Growth Des. 6, 1134.

    Article  CAS  Google Scholar 

  16. S. Huang and R. G. Xie Preparation manual of organic synthesis reagent (SiChuan University Press, ChengDu, 1988).

    Google Scholar 

  17. J. P. Perew, K. Burke, and M. Ernzerhof (1996). Phy. Rev. Lett. 77, 3865.

    Article  Google Scholar 

  18. M. Segall, M. Probert, C. Pickard, P. Hasnip, S. Clark, K. Refson, and M. (2006). Payne, Materials Studio CASTEP Version 4.1.

  19. G. M. Sheldrick SHELXL-97, Program for X-ray Crystal Structure Refinement (University of Göttingen, Göttingen, 1997).

    Google Scholar 

  20. A. B. Corradi, A. M. Ferrari, G. C. Pellacani, A. Saccani, F. Sandrolini, and P. Sgarabotto (1999). Inorg. Chem. 38, 716.

    Article  CAS  Google Scholar 

  21. G. E. Wang, M. S. Wang, X. M. Jiang, Z. F. Liu, R. G. Lin, L. Z. Cai, G. C. Guo, and J. S. Huang (2011). Inorg. Chem. Commun. 14, 1957.

    Article  CAS  Google Scholar 

  22. N. Mercier (2005). CrystEngCommun. 7, 429.

    Article  CAS  Google Scholar 

  23. H. Krautscheid, F. Vielsack, and N. Klaassen (1998). Z. Anorg. Allg. Chem. 624, 807.

    Article  CAS  Google Scholar 

  24. H. Krautscheid and F. Vielsack (1997). Z. Anorg. Allg. Chem. 623, 259.

    Article  CAS  Google Scholar 

  25. H. H. Li, Z. R. Chen, L. Q. Guo, K. N. Ding, J. Q. Li, C. C. Huang, and Z. L. Cai (2007). Aust. J. Chem. 60, 595.

    Article  CAS  Google Scholar 

  26. D. J. Brown (1974). Solid State Chem. 11, 214.

    Article  CAS  Google Scholar 

  27. Q. Hou, F. Q. Bai, M. J. Jia, J. Jin, J. H. Yu, and J. Q. Xu (2012). CrystEngComm 14, 4000.

    Article  CAS  Google Scholar 

  28. W. W. Wendlandt and H. G. Hecht Reflectance Spectroscopy (Interscience Publishers, New York, 1996).

    Google Scholar 

  29. G. Kotiim Reflectance Spectroscopy (Springer, New York, 1969).

    Google Scholar 

  30. M. C. Burns, M. A. Tershansy, J. M. Ellsworth, Z. Khalig, L. P. Jr, M. D. Smith, and H.-C. Zur Loye (2006). Inorg. Chem. 45, 10437.

    Article  CAS  Google Scholar 

  31. X. H. Zhu, N. Mercier, P. Frere, P. Blanchard, J. Roncali, M. Allain, C. Pasquier, and A. Riou (2003). Inorg. Chem. 42, 5330.

    Article  CAS  Google Scholar 

  32. Z. J. Zhang, S. C. Xiang, G. C. Guo, G. Xu, M. S. Wang, J. P. Zou, S. P. Guo, and J. S. Huang (2008). Angew. Chem. Int. Ed. 47, 4149.

    Article  CAS  Google Scholar 

  33. G. E. Wang, X. Gang, M. S. Wang, L. Z. Cai, W. H. Li, and G. C. Guo (2015). Chem. Sci. 6, 7222.

    Article  CAS  Google Scholar 

  34. J. Yang and M. Dolg (2006). J. Phys. Chem. B. 110, 19254.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Research Center for Science Technology and Society, Fuzhou University of International Studies and Trade, Fuzhou, 350202, Fujian, China

    Zhong-Yuan Chen, Shan Lin, Yan-Li Huang & Bao-Guo Chen

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  1. Zhong-Yuan Chen
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  2. Shan Lin
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  3. Yan-Li Huang
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  4. Bao-Guo Chen
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Correspondence to Bao-Guo Chen.

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Chen, ZY., Lin, S., Huang, YL. et al. Two New Polymeric Haloplumbates Directed by Diammonium Cations: Structures and Properties. J Clust Sci 28, 1551–1564 (2017). https://doi.org/10.1007/s10876-017-1163-7

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