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Elaboration, Structural, Vibrational, DSC Investigations and Hirshfeld Surface Analysis of New Organic–Inorganic Hybrid Compound: [H2mela]Cu2Br6

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Abstract

The present paper accounts for the synthesis, crystal structure, differential scanning calorimetry and vibrational spectroscopy of a new compound (1,3,5-triazinidium-2,4,6-triamine) hexabromidodicuprate (II) grown at room temperature by slow evaporation of aqueous solution. From X-ray diffraction data collected at room temperature, it is concluded that it crystallizes in the monoclinic system (P21/c space group). The anion and the cation are linked by N–H···Br hydrogen bonds. Furthermore, the room temperature IR and Raman spectra of the title compound were recorded and analyzed. The differential scanning calorimetric has also been investigated. Hirshfeld surfaces were used to confirm the existence of inter-molecular interactions in the compound.

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Acknowledgments

The authors thank the members of units of common services, at the University of Sfax for their assistance in the measurements for X-ray diffraction. The authors are also thankful to Prof Hamadi KHEMAKHEM, for his co-operating in the Raman spectroscopy measurement.

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Authors and Affiliations

  1. Laboratoire des Sciences des Matériaux et d’Environnement, Faculté des Sciences de Sfax, BP 1171, 3000, Sfax, Tunisia

    Radhia Mesbeh, Besma Hamdi & Ridha Zouari

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  1. Radhia Mesbeh
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  2. Besma Hamdi
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  3. Ridha Zouari
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Correspondence to Radhia Mesbeh.

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Mesbeh, R., Hamdi, B. & Zouari, R. Elaboration, Structural, Vibrational, DSC Investigations and Hirshfeld Surface Analysis of New Organic–Inorganic Hybrid Compound: [H2mela]Cu2Br6 . J Clust Sci 27, 1751–1762 (2016). https://doi.org/10.1007/s10876-016-1041-8

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  • DOI: https://doi.org/10.1007/s10876-016-1041-8

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