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Ligand-Assisted Conformation of Three Interesting Ni–M (M = Ag, Cu) Heterobimetallic Coordination Polymers: Syntheses, Structures, Thermal and Luminescence Properties

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Abstract

Three new heterobimetallic coordination polymers (CPs), {[Ni(4-pytpy)2][Ag(CH3CN)(NO3)](NO3)2(H2O)2}n 1 (4-pytpy = 4′-(4-pyridyl)- 2,2′:6′,2′′-terpyridine), {[Ni(4-pytpy)2][Ag2(4,4′-bipy)](NO3)4(DMSO)4}n 2 (4,4′-bipy = 4,4′-bipyridine), and {[Ni(4-pytpy)2][Cu3(SCN)5](CH3CN)(DMF)(H2O)0.5}n 3, were synthesized from metalloligand [Ni(4-pytpy)2]2+ with transition metals and different bridging ligands. All three compounds were characterized by elemental analysis, Fourier-transform infrared spectroscopy, thermal analysis and single-crystal X-ray diffraction analysis. Both CPs 1 and 2 display one-dimensional (1D) chain structures, which are further extended to 3D supramolecular structures through hydrogen bonds. CP-3 features a 2D network, which is constructed from 1D double chain cluster structure {[Cu3(SCN)5]2−}n linked by metalloligands [Ni(4-pytpy)2]2+ and exhibits an unusual (3,3,4)-connected 3-nodal topology. Thermal analysis indicates that the dehydrated structures of 1 and 3 can be stable up to 310 °C. The solid-state luminescence properties of compounds 1–3 were also investigated.

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Acknowledgments

Financial support from the National Natural Science Foundation of China (Grants 50925207, 51172100, and 51432006), the Ministry of Science and Technology of China for the International Science Linkages Program (Grant 2011DFG52970), the Ministry of Education of China for the Changjiang Innovation Research Team (Grant IRT13R24), the Ministry of Education and the State Administration of Foreign Experts Affairs for the 111 Project (Grant B13025), and 100 Talents Program of CAS are gratefully acknowledged.

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Authors and Affiliations

  1. Institute of Molecular Engineering and Advanced Materials, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094, People’s Republic of China

    Wenjiang Huang, Hongyang Wei & Chi Zhang

  2. China-Australia Joint Research Center for Functional Molecular Materials Scientific Research Academic, Jiangsu University, Zhenjiang, 212013, People’s Republic of China

    Jun Qian

  3. China-Australia Joint Research Center for Functional Molecular Materials School of Chemical and Material Engineering, Jiangnan University, Wuxi, 214122, People’s Republic of China

    Chi Zhang

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  1. Wenjiang Huang
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Correspondence to Jun Qian or Chi Zhang.

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Huang, W., Wei, H., Qian, J. et al. Ligand-Assisted Conformation of Three Interesting Ni–M (M = Ag, Cu) Heterobimetallic Coordination Polymers: Syntheses, Structures, Thermal and Luminescence Properties. J Clust Sci 27, 1655–1669 (2016). https://doi.org/10.1007/s10876-016-1021-z

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