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Structure Modulation in Four New Coordination Polymers by In Situ Ligands Synthesis of Anthracene Derivatives and Various Auxiliary N-donor Ligands

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Abstract

Four novel coordination polymers, [Zn(HL1)2(phen)2]·2CH3OH·2H2O (1), [ZnCl(HL1)(4,4′-bipy)0.5] n (2), [Cd(HL1)(L2)0.5(2,2′-bipy)2]·3H2O (3), [Zn(L3)0.5(N3)1.5(phen)] n (4) (H2L1 = 9-(1H-tetrazole-5-yl)-10-carboxyl anthracene, H2L2 = 9,10-di-(1H-tetrazole-5-yl) anthracene, HL3 = 9-(1H-tetrazole-5-yl)-10-cyan anthracene, 1,10-phen = 1,10-phenanthroline, 4,4′-bipy = 4,4′-bipyridine, 2,2′-bipy = 2,2′-bipyridine), have been constructed by in situ ligands synthesis system. The formation of tetrazole-based ligands H2L1, H2L2 and H2L3 involves the in situ Sharpless [2 + 3] cycloaddition reaction between 9,10-dicyanoanthracene (DCA) and NaN3 in the presence of Zn2+/Cd2+ ions as Lewis-acid catalysts under hydro/solvothermal conditions. At the same time, there is also another in situ carboxyl ligand synthesis reaction by hydrolysis from nitrile in compounds 1 and 2. The four compounds have been characterized by elemental analysis, IR and single-crystal X-ray diffraction analysis. Compound 1 exhibits a butterfly-shaped mononuclear structure. Compound 2 represents a 2D framework constructed by six-membered {Zn6} rings as secondary building units (SBUs). Compound 3 presents a dinuclear {Cd2} structure with two butterflies “flying side by side” fashion. While compound 4 displays a 1D chain structure based on a dinuclear {Zn2} SBUs. Moreover, the luminescence properties of 1–4 have been also investigated.

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Acknowledgments

This work was financially supported by the NNSF of China (21403102, 51303076 and 51172102), the National Undergraduate Training Programs for Innovation and Entrepreneurship (201510447001 and 201510447026).

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Authors and Affiliations

  1. School of Materials Science and Engineering, and School of Chemistry and Chemical Engineering, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng, 252000, People’s Republic of China

    Hui-Yan Ma, Wen-Qiang Wang, Na Yang, Xi-Xi Li, Yun-Wu Li & Xin Shao

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  1. Hui-Yan Ma
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  2. Wen-Qiang Wang
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  3. Na Yang
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  4. Xi-Xi Li
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Correspondence to Yun-Wu Li or Xin Shao.

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Ma, HY., Wang, WQ., Yang, N. et al. Structure Modulation in Four New Coordination Polymers by In Situ Ligands Synthesis of Anthracene Derivatives and Various Auxiliary N-donor Ligands. J Clust Sci 27, 1293–1306 (2016). https://doi.org/10.1007/s10876-016-1000-4

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