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Halogen-Dependent Thermochromic Properties in Three Methyl-Viologen/Haloargentate Charge Transfer (CT) Salts

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Abstract

Three charge transfer (CT) salts, [MV(Ag2X4)]n (MV2+ = N,N′-dimethyl-4,4′-bipyridinium, X = Cl (1), Br (2)) and [MV(Ag2I4)∙H2O]n (3) have been synthesized by using MV2+ as electron acceptor and different haloargentates as electron donor. Notably, the structural and optical characterization for three hybrids reveal halogen-dependent intermolecular CT band (estimated band gaps 3.0, 2.79, and 2.27 eV respectively) and consequent resulted thermochromic behaviors (inactive for 1 and 2 and active for 3).

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References

  1. R. Peng, M. Li, and D. Li (2010). Coord. Chem. Rev. 254, 1.

    Article  CAS  Google Scholar 

  2. C. H. Arnby, S. Jagner, and I. Dance (2004). CrystEngComm 6, 257.

    Article  CAS  Google Scholar 

  3. L. M. Wu, X. T. Wu, and L. Chen (2009). Coord. Chem. Rev. 253, 2787.

    Article  CAS  Google Scholar 

  4. U. Englert (2010). Coord. Chem. Rev. 254, 537.

    Article  CAS  Google Scholar 

  5. R. Meijboom, R. J. Bowen, and S. J. B. Price (2009). Coord. Chem. Rev. 253, 325.

    Article  CAS  Google Scholar 

  6. P. M. Graham and R. D. Pike (2000). Inorg. Chem. 39, 5121.

    Article  CAS  Google Scholar 

  7. W. H. Bi, N. Louvain, N. Mercier, J. Luc, I. Rau, F. Kajzar, and B. Sahraoui (2008). Adv. Mater. 20, 1013.

    Article  CAS  Google Scholar 

  8. W. S. Yang, J. H. Noh, N. J. Jeon, Y. C. Kim, S. Ryu, J. Seo, and S. Seok (2015). Science 348, 1234.

    Article  CAS  Google Scholar 

  9. H. H. Li, Z. R. Chen, L. G. Sun, Z. X. Lian, X. B. Chen, J. B. Li, and J. Q. Li (2010). Cryst. Growth Des. 10, 1068.

    Article  CAS  Google Scholar 

  10. S. Sourisseau, N. Louvain, W. H. Bi, N. Mercier, D. Rondeau, F. Boucher, J. Y. Buzare, and C. Legein (2007). Chem. Mater. 19, 600.

    Article  CAS  Google Scholar 

  11. N. Leblanc, N. Mercier, L. Zorina, S. Simonov, P. Auban-Senzier, and C. Pasquier (2011). J. Am. Chem. Soc. 133, 14924.

    Article  CAS  Google Scholar 

  12. X. W. Lei, C. Y. Yue, L. J. Feng, Y. F. Han, R. R. Meng, J. T. Yang, H. Ding, C. S. Gao, and C. Y. Wang (2016). CrystEngComm 18, 427.

    Article  CAS  Google Scholar 

  13. X. W. Lei, C. Y. Yue, J. Q. Zhao, Y. F. Han, J. T. Yang, R. R. Meng, C. S. Gao, H. Ding, C. Y. Wang, W. D. Chen, and M. C. Hong (2015). Inorg. Chem. 54, 10593.

    Article  CAS  Google Scholar 

  14. W. Lei, C. Y. Yue, J. Q. Zhao, Y. F. Han, Z. R. Ba, C. Wang, X. Y. Liu, Y. P. Gong, and X. Y. Liu (2015). Eur. J. Inorg. Chem. 2015, 4412.

    Article  CAS  Google Scholar 

  15. T. Y. Chen, L. Shi, H. Yang, X. M. Ren, C. Xiao, and W. Q. Jin (2016). Inorg. Chem. 55, 1230.

    Article  CAS  Google Scholar 

  16. Y. Z. Qiao, W. Z. Fu, J. M. Yue, X. C. Liu, Y. Y. Niu, and H. W. Hou (2012). CrystEngComm 14, 3241.

    Article  CAS  Google Scholar 

  17. X. W. Lei, C. Y. Yue, J. Q. Zhao, Y. F. Han, J. T. Yang, R. R. Meng, C. S. Gao, H. Ding, C. Y. Wang, W. D. Chen, and M. C. Hong (2015). Inorg. Chem. 54, 10593.

    Article  CAS  Google Scholar 

  18. H. Chan, Y. Chen, M. Dai, C. N. Liu, H. F. Wang, Z. G. Ren, Z. J. Huang, C. Y. Ni, and J. P. Lang (2012). CrystEngComm 14, 466.

    Article  CAS  Google Scholar 

  19. S. Mishra, E. Jeanneau, G. Ledouxc, and S. Daniele (2009). Dalton Trans. 4954.

  20. S. Mishra, E. Jeanneau, S. Daniele, and G. Ledoux (2008). Dalton Trans. 28, 6296.

    Article  Google Scholar 

  21. S. Mishra, E. Jeanneau, G. Ledoux, and S. Daniele (2014). Inorg. Chem. 53, 11721.

    Article  CAS  Google Scholar 

  22. R. G. Lin, G. Xu, M. S. Wang, G. Lu, P. X. Li, and G. C. Guo (2013). Inorg. Chem. 52, 1199.

    Article  CAS  Google Scholar 

  23. R. G. Lin, G. Xu, G. Lu, M. S. Wang, P. X. Li, and G. C. Guo (2014). Inorg. Chem. 53, 5538.

    Article  CAS  Google Scholar 

  24. M. Li, L. J. Yuan, and Z. Y. Fu (2015). Inorg. Chem. Commun. 57, 58.

    Article  CAS  Google Scholar 

  25. J. B. Wu, C. Y. Tao, Y. Li, Y. Yan, J. Y. Li, and J. H. Yu (2014). Chem. Sci. 5, 4237.

    Article  CAS  Google Scholar 

  26. P. C. Jhang, N. T. Chuang, and S. L. Wang (2010). Angew. Chem. Int. Ed. 49, 4200.

    Article  CAS  Google Scholar 

  27. Y. R. Qiao, P. F. Hao, and Y. L. Fu (2015). Inorg. Chem. 54, 8705.

    Article  CAS  Google Scholar 

  28. G. N. Liu, J. R. Shi, X. J. Han, X. Zhang, K. Li, J. Li, T. Zhang, Q. S. Liu, Z. W. Zhang, and C. C. Li (2015). Dalton Trans. 44, 12561.

    Article  CAS  Google Scholar 

  29. T. L. Yu, J. J. Shen, Y. L. Wang, and Y. L. Fu (2015). Eur. J. Inorg. Chem. 2015, 1989.

    Article  CAS  Google Scholar 

  30. H. J. Du, W. L. Zhang, C. H. Wang, Y. Y. Niu, and H. W. Hou (2016). Dalton Trans. 45, 2624.

    Article  CAS  Google Scholar 

  31. Z. J. Zhang, G. C. Guo, G. Xu, M. L. Fu, J. P. Zou, and J. S. Huang (2006). Inorg. Chem. 45, 10028.

    Article  CAS  Google Scholar 

  32. M. A. White and M. J. LeBlanc (1999). Chem. Educ. 76, 1201.

    Article  CAS  Google Scholar 

  33. D. C. MacLaren and M. A. White (2003). J. Mater. Chem. 13, 1695.

    Article  CAS  Google Scholar 

  34. D. Haristoy and D. Tsiourvas (2003). Chem. Mater. 15, 2079.

    Article  CAS  Google Scholar 

  35. C. G. Bazuin, D. Guillon, A. Skoulios, and R. J. Zana (1986). Phys. (Paris) 47, 927.

    Article  CAS  Google Scholar 

  36. K. Binnemans (2005). Chem. Rev. 105, 4148.

    Article  CAS  Google Scholar 

  37. J. S. Moore and S. I. Stupp (1986). Macromolecules 19, 1815.

    Article  CAS  Google Scholar 

  38. E. M. Kosower (1958). J. Am. Chem. Soc. 80, 3253.

    Article  CAS  Google Scholar 

  39. J. T. Sampanthar, K. G. Neoh, S. W. Ng, E. T. Kang, and K. L. Tan (2000). Adv. Mater. 12, 1536.

    Article  CAS  Google Scholar 

  40. D. Cummins, G. Boschloo, M. Ryan, D. Corr, S. N. Rao, and D. J. Fitzmaurice (2000). Phys. Chem. B. 104, 11449.

    Article  CAS  Google Scholar 

  41. T. L. Yu, L. An, L. Zhang, J. J. Shen, Y. B. Fu, and Y. L. Fu (2014). Cryst. Growth Des. 14, 3875.

    Article  CAS  Google Scholar 

  42. J. J. Shen, C. F. Zhang, T. L. Yu, L. An, and Y. L. Fu (2014). Cryst. Growth Des. 14, 6337.

    Article  CAS  Google Scholar 

  43. C. F. Zhang, J. J. Shen, Q. Guan, T. L. Yu, and Y. L. Fu (2015). Solid State Sci. 46, 14.

    Article  Google Scholar 

  44. M. A. Tershansy, A. M. Goforth, J. R. Gardinier, M. D. Smith, L. Peterson Jr., and H. C. Zur Loye (2007). Solid State Sci. 9, 410.

    Article  CAS  Google Scholar 

  45. A. M. Goforth, M. A. Tershansy, M. D. Smith, L. Peterson Jr., J. G. Kelley, W. J. I. DeBenedetti, and H. C. Zur Loye (2011). J. Am. Chem. Soc. 133, 603.

    Article  CAS  Google Scholar 

  46. A. Lemmerer and D. G. Billing (2012). Dalton Trans. 41, 1146.

    Article  CAS  Google Scholar 

  47. D. G. Billing and A. Lemmerer (2008). New J. Chem. 32, 1736.

    Article  CAS  Google Scholar 

  48. M. C. Burns, M. A. Tershansy, J. M. Ellsworth, Z. Khaliq, L. Peterson Jr., M. D. Smith, and H. C. Zur Loye, (2006). Inorg. Chem. 45, 10437.

    Article  CAS  Google Scholar 

  49. H. X. Guo, Y. Zhang, X. Z. Li, and W. Weng (2010). Inorg. Chem. Commun. 13, 425.

    Article  CAS  Google Scholar 

  50. R. Kannappan, C. Bucher, E. S. Aman, J. C. Moutet, A. Milet, M. Oltean, E. Metay, S. P. Rostaing, M. Lemairec, and C. Chaix (2010). New J. Chem. 34, 1373.

    Article  CAS  Google Scholar 

  51. N. Mercier (2013). Eur. J. Inorg. Chem. 2013, 19.

    Article  Google Scholar 

  52. P. X. Li, M. S. Wang, L. Z. Cai, G. E. Wang, and G. C. Guo (2015). J. Mater. Chem. C 3, 253.

    Article  CAS  Google Scholar 

  53. M. Suzuki, M. Kimura, K. Hanabusa, and H. Shirai (1997). Chem. Commun. 21, 2061.

    Article  Google Scholar 

  54. P. AbetaIyere (1996). Synth. React. Inorg. Met. Org. Chem. 26, (7), 1231.

    Article  Google Scholar 

  55. T. Kinuta, T. Sato, N. Tajima, R. Kuroda, Y. Matsubara, and Y. Imai (2010). J. Mol. Struct. 982, 45.

    Article  CAS  Google Scholar 

  56. H. H. Li, P. Wang, X. H. Chao, C. C. Lin, A. W. Gong, and Z. R. Chen (2015). J. Clust. Sci. 26, 851.

    Article  CAS  Google Scholar 

  57. Y. X. Zhao and K. Zhu (2014). J. Am. Chem. Soc. 136, 12241.

    Article  CAS  Google Scholar 

  58. N. Leblanc, M. Allain, N. Mercier, and L. Sanguinet (2011). Cryst. Growth Des. 11, 2064.

    Article  CAS  Google Scholar 

  59. X. W. Lei, C. Y. Yue, L. J. Feng, Y. F. Han, R. R. Meng, J. T. Yang, H. Ding, C. S. Gao, and C. Y. Wang (2016). CrystEngComm 18, 427.

    Article  CAS  Google Scholar 

  60. G. Kotiim Reflectance Spectroscopy (Springer, New York, 1969).

    Google Scholar 

  61. O. Schevciw and W. B. White (1983). Mater. Res. Bull. 18, 1059.

    Article  CAS  Google Scholar 

  62. A. J. Macfarlane and R. J. P. Williams (1969). J. Chem. Soc. A. 1517.

  63. G. M. Sheldrick SHELXS-97, A Program for X-ray Crystal Structure Solution, and SHELXL-97. A Program for X-ray Structure Refinement (Göttingen University, Germany, 1997).

    Google Scholar 

  64. H. H. Li, S. Y. Chen, H. J. Dong, Y. L. Wu, and Z. R. Chen (2011). J. Chem. Crystallogr. 41, 858.

    Article  CAS  Google Scholar 

  65. X. L. Sun, Q. Y. Zhu, W. Q. Mu, L. W. Qian, L. Yu, J. Wu, G. Q. Bian, and J. Dai (2014). Dalton Trans. 43, 12582.

    Article  CAS  Google Scholar 

  66. J. H. Russell and S. C. Wallwork (1972). Acta Cryst. B28, 1527.

    Article  Google Scholar 

  67. CrysAlisPro, version 1.171.37.33, release 27-03-2014 CrysAlis171 .NET (Agilent Technologies).

  68. B. Han, J. J. Lu, and J. K. Kochi (2008). Cryst. Growth Des. 8, 1327.

    Article  CAS  Google Scholar 

  69. C. K. Prout and J. D. Wright (1968). Angew. Chem. Int. Ed. 7, 659.

    Article  CAS  Google Scholar 

  70. G. N. Liu, L. L. Liu, Y. N. Chu, Y. Q. Sun, Z. W. Zhang, and C. C. Li (2015). Eur. J. Inorg. Chem. 2015, 478.

    Article  CAS  Google Scholar 

  71. T. L. Yu, J. J. Shen, Y. B. Fu, and Y. L. Fu (2014). CrystEngComm 16, 5280.

    Article  CAS  Google Scholar 

  72. J. K. Sun, P. Wang, Q. X. Yao, Y. J. Chen, Z. H. Li, Y. F. Zhang, L. M. Wu, and J. Zhang (2012). J. Mater. Chem. 22, 12212.

    Article  CAS  Google Scholar 

  73. L. N. Xiao, Y. Y. Hu, L. M. Wang, Y. Wang, J. N. Xu, H. Ding, X. B. Cui, and J. Q. Xu (2012). CrystEngComm 14, 8589.

    Article  CAS  Google Scholar 

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Acknowledgments

We thank the National Natural Science Foundation of China (No. 21171110) and the Research Fund for the Doctoral Program of Higher Education of China (No. 20131404110001).

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Authors and Affiliations

  1. School of Chemistry and Material Science, Shanxi Normal University, Linfen, 041004, People’s Republic of China

    Yachen Zhu, Tanlai Yu, Pengfei Hao, Junju Shen & Yunlong Fu

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  1. Yachen Zhu
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Correspondence to Yunlong Fu.

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Zhu, Y., Yu, T., Hao, P. et al. Halogen-Dependent Thermochromic Properties in Three Methyl-Viologen/Haloargentate Charge Transfer (CT) Salts. J Clust Sci 27, 1283–1291 (2016). https://doi.org/10.1007/s10876-016-0999-6

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