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Synthesis, Crystal Structures and Magnetic Properties of Three New Polynuclear Cu(II) Complexes Based on the Methoxybenzoate Isomers

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Abstract

In this paper, self-assembly reactions of copper(II) ions, methoxybenzoate isomers and 2,2′-bipyridine yield two copper-oxygen polynuclear complexes: [Cu2(bpy)2(2-C8H7O3)3]·(2-C8H7O3)·14H2O 1, [Cu4(bpy)4(H2O)(OH)4]·4(3-C8H7O3)·17H2O 2, and a simple mononuclear complex [Cu(bpy)(H2O)(4-C8H7O3)2] 3. (bpy = 2,2′-bipyridine, C8H7O3 = methoxybenzoate ion). Single crystal X-ray diffraction analyses reval that compound 1 is a dinuclear copper(II) complex which bridged by three carboxylate groups, and 2 presents a discrete step-like tetra-nuclear copper Cu4O4 core. Compound 3 shows a square pyramidal mononuclear geometry. The magnetic susceptibility of complex 1 measured from 2 to 300 K, revealed an antiferromagnetic interaction between the Cu(II) ions. Furthermore, the results about IR spectra and thermal analyses were discussed.

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Acknowledgments

This project was supported by the Department of Education of Zhejiang Province and K. C. Wong Magna Fund in Ningbo University.

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Authors and Affiliations

  1. Center of Applied Solid State Chemistry Research, Ningbo University, Ningbo, 315211, People’s Republic of China

    Jian-Qing Xu, Yue-Qing Zheng, Hong-Lin Zhu & Wei Xu

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  1. Jian-Qing Xu
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  2. Yue-Qing Zheng
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  3. Hong-Lin Zhu
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Correspondence to Yue-Qing Zheng.

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Xu, JQ., Zheng, YQ., Zhu, HL. et al. Synthesis, Crystal Structures and Magnetic Properties of Three New Polynuclear Cu(II) Complexes Based on the Methoxybenzoate Isomers. J Clust Sci 27, 485–499 (2016). https://doi.org/10.1007/s10876-015-0941-3

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