Abstract
Superparamagnetic Fe3O4 nanoparticles decorated multiwalled carbon nanotubes were synthesized by cyclic microwave method and the effect of different reaction parameters on the products were also investigated. The as synthesized products were characterized by XRD, TEM, SEM, EDS, FT-IR, VSM, and Uv–Vis spectroscopy. It was observed that precursors’ concentration ratio had great effect on the particle size and decorating quality. Also the effect of the other parameters including irradiation power and time on product size and uniformity of the product were also investigated. The best products with desired particle size distribution obtained when irradiation power and reaction time were 900 W and 6 min, respectively. Aspirin and acetaminophen were applied as a model drug and the drug release behavior of the composite was investigated. It was observed that the drug discharge was highly dependent to the pH and can be tuned by applying magnetic field.
Similar content being viewed by others
References
S. Iijima (1991). Nature. 354, 56.
W. A. Heer, A. Chatelain, and D. A. Ugarte (1995). Science. 270, 1179.
B. R. Goldsmith (2007). Science. 318, 1886.
J. Jang, J. Bae, and S. H. Yoon (2003). J. Mater. Chem. 13, 676.
J. Liu, M. Shao, X. Chen, W. Yu, X. Liu, and Y. Qian (2003). J. Am. Chem. Soc. 125, 8088.
M. C. Schnitzler, M. M. Oliveira, D. Ugarte, and A. J. G. Zarbin (2003). Chem. Phys. Lett. 381, 541.
G. Korneva, H. Ye, Y. Gogotsi, D. Halverson, G. Friedman, J. C. Bradley, and K. G. Kornev (2005). Nano Lett. 5, 879.
Z. Wang, Z. Zhao, and J. Qiu (2006). Carbon. 44, 1845.
R. Lv, F. Kang, W. Wang, J. Wei, J. Gu, K. Wang, and D. Wu (2007). Carbon. 45, 1433.
K. Jiang, A. Eitan, L. S. Schadler, P. M. Ajayan, and R. W. Siegel (2003). Nano Lett. 3, 275.
J. Li, S. Tang, L. Lu, and H. Zeng (2007). J. Am. Chem. Soc. 129, 9401.
W. Chen, X. Pan, M. G. Willinger, D. S. Su, and X. Bao (2006). J. Am. Chem. Soc. 128, 3136.
Y. Q. Liu and L. Gao (2005). Carbon. 43, 47.
G. Korneva, H. H. Ye, Y. Gogotsi, D. Halverson, G. Friedman, J. C. Bradley, and K. G. Kornev (2005). Nano Lett. 5, 879.
F. Stoffelbach, A. Aqil, C. Jérôme, R. Jérôme, and C. Detrembleur (2005). Chem. Commun. 36, 4532.
K. Tanaka, N. Kitamura, and Y. Chujo (2008). Nucleic Acids Symp. Ser. (Oxf). 52, 693.
C. Alexiou, W. Arnold, R. J. Klein, F. G. Parak, P. Hulin, C. Bergemann, W. Erhardt, S. Wagenpfeil, and A. S. Lubbe (2000). Cancer Res. 60, 6641.
T. K. Jain, J. Richey, M. Strand, D. L. Leslie-Pelecky, C. A. Flask, and V. Labhasetwar (2008). Biomaterials. 29, 4012.
Y. Liu, D. C. Wu, W. D. Zhang, X. Jiang, C. B. He, T. S. Chung, S. H. Goh, and K. W. Leong (2005). Angew. Chem. Int. Ed. 44, 4782.
A. A. Bhirde, V. Patel, J. Gavard, G. F. Zhang, A. A. Sousa, A. Masedunskas, R. D. Leapman, R. Weigert, J. Silvio Gutkind, and J. F. Rusling (2009). Acs Nano. 3, 307.
W. Wu, R. T. Li, X. C. Bian, Z. S. Zhu, D. Ding, X. L. Li, Z. Jia, X. Jiang, and Y. Hu (2009). ACS Nano. 3, 2740.
G. Pastorin, W. Wu, S. Wieckowski, J. P. Briand, K. Kostarelos, and M. Prato (2006). Chem. Commun. 11, 1182.
C. L. Lay, H. Q. Liu, H. R. Tan, and Y. Liu (2010). Nanotechnology. 21, 065101.
X. K. Zhang, L. J. Meng, Q. G. Lu, Z. F. Fei, and P. J. Dyson (2009). Biomaterials. 30, 6041.
R. B. Li, R. Wu, L. Zhao, M. H. Wu, L. Yang, H. And, and F. Zou (2010). ACS Nano. 4, 1399.
L. Jiang and L. Gao (2003). Chem. Mater. 15, 2848.
J. Wan, W. Cai, J. Feng, X. Meng, and E. Liu (2007). J. Mater. Chem. 17, 1188.
W. W. Chen, R. V. Nguyen, and C. J. Li (2009). Tetrahedron Lett. 50, 2895.
J. Liu, A. G. Rinzler, H. Dai, J. H. Hafner, R. K. Bradley, P. J. Boul, A. Lu, T. Iverson, K. Shelimov, C. B. Huffman, F. Rodriguez-Macias, Y.-S. Shon, T. R. Lee, D. T. Colbert, and R. E. Smalley (1998). Science. 280, 1253.
A. V. Ellis and B. Ingham (2006). J. Magn. Magn. Mater. 302, 378.
H. Emadi and A. Nemati Kharat (2013). Mater. Res. Bull. 48, 3994.
R. D. Waldron (1955). Phys. Rev. 99, 1727.
D. Michael, P. Mingos, and D. R. Baghurt (1991). Chem. Soc. Rev. 20, 1.
Y. Shan, K. Chen, X. Yu, and L. Gao (2010). Appl. Surf. Sci. 257, 362.
A. Mahmud, X. Bing Xiong, and A. Lavasanifar (2008). Eur. J. Pharm. Biopharm. 69, 923.
Acknowledgments
The authors are grateful to the University of Tehran for their effort to provide financial support to undertake this work.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Bouriabadi, H., Emadi, H. & Kharat, A.N. Superparamagnetic Fe3O4 Nanoparticles Decorated Multiwalled Carbon Nanotubes: Preparation via Cyclic Microwave Approach and Their Drug Release Behavior. J Clust Sci 27, 1017–1030 (2016). https://doi.org/10.1007/s10876-015-0906-6
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10876-015-0906-6