Skip to main content
SpringerLink
Log in

One Novel Trinuclear Nickel(II) Cluster Containing a Pyramidal Ni3(μ 3-OH) Core: Crystal Structure and Hirshfeld Surface Analysis

  • Original Paper
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

One new trinuclear nickel(II) cluster with a Ni3(μ 3-OH) core was synthesized by the method of in situ one pot synthesis. The complex [Ni3(μ 3-OH)(cpza)3]Cl2·H2O (1) (where Hcpza is N-(4-cyano-1H-pyrazol-3-yl)acetamide) was characterized by single-crystal X-ray diffraction methods, elemental analyses, IR spectroscopy and Hirshfeld surface analysis. For complex 1, the crystal structure is extended into 3D structure through N–H···O and O–H···Cl hydrogen bonds. According to the 3D Hirshfeld surface and 2D fingerprint plots, the main interactions in the cluster are the H···H, N···H and O···H contacts.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Chart 1

Similar content being viewed by others

References

  1. L. K. Frensch, K. Pröpper, M. John, S. Demeshko, C. Bröuckner, and F. Meyer (2011). Angew. Chem. Int. Ed. 50, 1420.

    Article  CAS  Google Scholar 

  2. A. C. Cunha, V. F. Ferreira, A. K. Jordão, M. C. B. V. de Souza, S. M. S. V. Wardell, J. L. Wardell, P. A. Tan, R. P. A. Bettens, S. K. Seth, and E. R. T. Tiekink (2013). CrystEngCommun. 15, 4917.

    Article  CAS  Google Scholar 

  3. S. K. Seth, V. S. Lee, J. Yana, S. M. Zain, A. C. Cunha, V. F. Ferreira, A. K. Jordão, M. C. B. V. de Souza, S. M. S. V. Wardell, J. L. Wardell, and E. R. T. Tiekink (2015). CrystEngCommun. 17, 2255.

    Article  CAS  Google Scholar 

  4. S. K. Seth and K. Jana (2014). Inorg. Chem. Commun. 43, 60.

    Article  CAS  Google Scholar 

  5. S. K. Seth, N. K. Das, K. Aich, D. Sen, H. K. Fun, and S. Goswami (2013). J. Mol. Struct. 1048, 157.

    Article  CAS  Google Scholar 

  6. K. Umakoshi, Y. Yamauchi, K. Nakamiya, T. Kojima, M. Yamasaki, H. Kawano, and M. Onishi (2003). Inorg. Chem. 42, 3907.

    Article  CAS  Google Scholar 

  7. E. Kavlakoglu, A. Elmali, Y. Elerman, and I. Svoboda (2002). Polyhedron. 21, 1539.

    Article  CAS  Google Scholar 

  8. G. Mezei, M. Rivera-Carrillo, and R. G. Raptis (2004). Inorg. Chim. Acta 357, 3721.

    Article  CAS  Google Scholar 

  9. C. D. Nicola, F. Garau, M. Gazzano, M. F. C. G. da Silva, A. Lanza, M. Monari, F. Nestola, L. Pandolfo, C. Pettinari, and A. J. L. Pombeiro (2012). Cryst. Growth Des. 12, 2890.

    Article  Google Scholar 

  10. C. D. Nicola, F. Garau, M. Gazzano, M. Monari, L. Pandolfo, C. Pettinari, and R. Pettinari (2010). Cryst. Growth Des. 10, 3120.

    Article  Google Scholar 

  11. J. Li, J. H. Zhou, Y. Z. Li, L. H. Weng, X. T. Chen, Z. Yu, and Z. L. Xue (2004). Inorg. Chim. Chem. 7, 538.

    Article  CAS  Google Scholar 

  12. J. H. Zhou, Z. Liu, Y. Z. Li, Y. Song, X. T. Chen, and X. Z. You (2006). J. Coord. Chem. 59, 147.

    Article  CAS  Google Scholar 

  13. M. Lukasiewicz, Z. Ciunik, J. Mazurek, J. Sobczak, A. Staroń, S. Wołowiec, and J. J. Ziołkowski (2001). Eur. J. Inorg. Chem. 1575.

  14. P. M. Slangen, P. J. van Koningsbruggen, J. G. Haasnoot, J. Jansen, S. Gorter, J. Reedijk, H. Kooijman, W. J. J. Smeets, and A. L. Spek (1993). Inorg. Chim. Acta 212, 289.

    Article  CAS  Google Scholar 

  15. P. M. Slangen, P. J. van Koningsbruggen, K. Goubitz, J. G. Haasnoot, and J. Reedijk (1994). Inorg. Chem. 33, 1121.

    Article  CAS  Google Scholar 

  16. O. Roubeau, J. M. A. Gómez, E. Balskus, J. J. A. Kolnaar, and J. Reedijk (2001). New J. Chem. 25, 144.

    Article  CAS  Google Scholar 

  17. H. H. Murray, R. G. Raptis, and J. P. Fackler (1988). Inorg. Chem. 27, 26.

    Article  CAS  Google Scholar 

  18. R. G. Raptis and J. P. Fackler (1988). Inorg. Chem. 27, (41), 79.

    Google Scholar 

  19. M. K. Ehlert, S. J. Rettig, A. Storr, R. C. Thompson, and J. Trotter (1990). Can. J. Chem. 68, 1444.

    Article  CAS  Google Scholar 

  20. B. Bovio, F. Botani, and G. Banditelli (1984). Inorg. Chim. Acta 87, 25.

    Article  CAS  Google Scholar 

  21. G. Yang and R. G. Raptis (2003). Inorg. Chem. 42, 261.

    Article  CAS  Google Scholar 

  22. H. V. R. Dias, H. V. K. Diyabalanage, M. A. Raqshdeh-Omary, M. A. Franzman, and M. A. Omary (2003). J. Am. Chem. Soc. 125, 12072.

    Article  CAS  Google Scholar 

  23. P. A. Angaridis, P. Baran, R. Boca, F. Cervantes-Lee, W. Haase, G. Mezei, R. G. Raptis, and R. Werner (2002). Inorg. Chem. 41, 2219.

    Article  CAS  Google Scholar 

  24. R. Boca, L. Dlhan, G. Mezei, T. Ortiz-Pérez, R. G. Raptis, and J. Telser (2003). Inorg. Chem. 42, 5801.

    Article  CAS  Google Scholar 

  25. G. Mezei and R. G. Raptis (2004). Inorg. Chim. Acta 357, 3279.

    Article  CAS  Google Scholar 

  26. X. Liu, M. P. de Miranda, E. J. L. McInnes, C. A. Kilner, and M. A. Halcrow (2004). J. Chem. Soc., Dalton Trans. 59.

  27. G. Mezei, R. G. Raptis, and J. Telser (2006). Inorg. Chem. 45, 8841.

    Article  CAS  Google Scholar 

  28. T. Afrati, C. Dendrinou-Samara, C. Raptopoulou, A. Terzis, V. Tangoulis, and D. P. Kessissoglou (2007). Dalton Trans. 5156.

  29. T. Afrati, C. Dendrinou-Samara, C. Raptopoulou, A. Terzis, V. Tangoulis, A. Tsipis, and D. P. Kessissoglou (2008). Inorg. Chem. 47, 7545.

    Article  CAS  Google Scholar 

  30. T. Afrati, A. A. Pantazaki, C. Dendrinou-Samara, C. Raptopoulou, A. Terzis, and D. P. Kessissoglou (2010). Dalton Trans. 39, 765.

    Article  CAS  Google Scholar 

  31. S. Ferrer, J. G. Haasnoot, J. Reedijk, E. Müller, M. Biagini-Cingi, M. Lanfranchi, A. M. Manotti-Lanfredi, and J. Ribas (2000). Inorg. Chem. 39, 1859.

    Article  CAS  Google Scholar 

  32. C. Chen, H. Y. Qiu, and W. Z. Chen (2011). Inorg. Chem. 50, 8671.

    Article  CAS  Google Scholar 

  33. G. M. Sheldrick (2008). Acta Cryst. A64, 112.

    Article  Google Scholar 

  34. Bruker FRAMBO and SAINT (Bruker AXS Inc., Madison, 2004).

    Google Scholar 

  35. S. K. Seth, I. Saha, C. Estarellas, A. Frontera, T. Kar, and S. Mukhopadhyay (2011). Cryst. Growth Des. 11, 3250.

    Article  CAS  Google Scholar 

  36. S. K. Seth, D. Sarkar, A. D. Jana, and T. Kar (2011). Cryst. Growth Des. 11, 4837.

    Article  CAS  Google Scholar 

  37. S. K. Seth (2013). CrystEngCommun. 15, 1772.

    Article  CAS  Google Scholar 

  38. P. Manna, S. K. Seth, M. Mitra, A. Das, N. J. Singh, S. R. Choudhury, T. Kar, and S. Mukhopadhyay (2013). CrystEngCommun. 15, 7879.

    Article  CAS  Google Scholar 

  39. S. K. Seth (2014). J. Mol. Struct. 1070, 65.

    Article  CAS  Google Scholar 

  40. F. L. Hirshfeld (1977). Theor. Chim. Acta 44, 129.

    Article  CAS  Google Scholar 

  41. S. K. Seth, D. Sarkar, and T. Kar (2011). CrystEngCommun. 13, 4528.

    Article  CAS  Google Scholar 

  42. S. K. Seth, D. Sarkar, A. Roy, and T. Kar (2011). CrystEngCommun. 13, 6728.

    Article  CAS  Google Scholar 

  43. P. Manna, S. K. Seth, A. Das, J. Hemming, R. Prendergast, M. Helliwell, S. R. Choudhury, A. Frontera, and S. Mukhopadhyay (2012). Inorg. Chem. 51, 3557.

    Article  CAS  Google Scholar 

  44. S. K. Seth (2014). J. Mol. Struct. 1064, 70.

    Article  CAS  Google Scholar 

  45. L. Ballell, R. A. Field, K. Duncan, and R. J. Young (2005). Antimicrob. Agents Chemother. 49, 2153.

    Article  CAS  Google Scholar 

  46. L. Yang, Q. P. Huang, C. L. Zhang, R. X. Zhao, and S. H. Zhang (2014). Supramol. Chem. 26, 81.

    Article  CAS  Google Scholar 

  47. C. L. Zhang, X. F. Jiang, L. Yang, S. H. Zhang, and S. M. Shi (2014). J. Clust. Sci. 25, 459.

    Article  Google Scholar 

  48. S. H. Zhang, R. X. Zhao, H. P. Li, C. M. Ge, G. Li, Q. P. Huang, and H. H. Zou (2014). J. Solid State Chem. 216, 30.

    Article  CAS  Google Scholar 

  49. B. Biswas, U. Pieper, T. Weyhermouller, and P. Chaudhuri (2009). Inorg. Chem. 48, 6781.

    Article  CAS  Google Scholar 

  50. J. Esteban, M. Font-Bardia, and A. Escuer (2013). Eur. J. Inorg. Chem. 5274.

Download references

Acknowledgments

We gratefully acknowledge the financial support of the National Natural Science Foundation of China (20801012) and the financial support from Jiangsu Ainaji Neoenergy Science & Technology Co., Ltd (8507040091).

Author information

Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Southeast University, Nanjing, 211189, People’s Republic of China

    Chao Feng, Li-Na Sun, Huan-Huan Huang & Hong Zhao

  2. Key Laboratory of Organosilicon Chemistry and Material Technology of the Ministry of Education, Hangzhou Normal University, Hangzhou, 311121, People’s Republic of China

    Zhi-Rong Qu

Authors
  1. Chao Feng
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Li-Na Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Huan-Huan Huang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zhi-Rong Qu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Hong Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Zhi-Rong Qu or Hong Zhao.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Feng, C., Sun, LN., Huang, HH. et al. One Novel Trinuclear Nickel(II) Cluster Containing a Pyramidal Ni3(μ 3-OH) Core: Crystal Structure and Hirshfeld Surface Analysis. J Clust Sci 27, 63–72 (2016). https://doi.org/10.1007/s10876-015-0904-8

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10876-015-0904-8

Keywords

Search

Navigation