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Two Organic–Inorganic Hybrids Assembled from Transition–Metal Complexes and Keggin-Type Silicotungstates

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Abstract

By introducing rigid aromatic N-ligands to the lacunary silicotungstate system under hydrothermal conditions, two new Keggin-type polyoxotungstate hybrids with copper–organic complexes [Cu(phen)(H2O)2]2[Cu(phen)2]2[α-SiW12O40]2·4H2O (1) and [Cu(4,4′-bpy)]3H[α-SiW12O40]·3 H2O (2) (phen = 1,10-phenanthroline, 4,4′-bpy = 4,4′-bipyridine) have been made and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The common architectural feature of 1 and 2 is that both comprise the plenary Keggin-type [α-SiW12O40]4− polyoxoanions modified by Cu–organic fragments containing various organic ligands. It should be pointed out that {[Cu(phen) (H2O)2][α-SiW12O40]}2+ and {[Cu(phen)2][α-SiW12O40]}2+ building units in 1 are alternately held together into an infinite 1-D chain fashion while the most striking characteristic of 2 is that two types of {–4,4′-bpy–Cu– 4,4′-bpy–Cu–}n 1-D polymeric chains are combined together by hexadentate [α-SiW12O40]4− polyoxoanions as the inorganic bridging ligands, giving birth to the aesthetic 3-D extended architecture. Moreover, electrochemical properties of 1 and 2 have been investigated.

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Acknowledgments

This work was supported by the Natural Science Foundation of China (21101055, 213010 4 9, U130 4208), the Natural Science Foundation of Henan Province (12230 0 41010 6, 10230 0 410 093), the Foundation of State Key Laboratory of Structural Chemistry (20120 013), 2014 Special Foundation for Scientific Research Project of Henan University, 2012 Young Backbone Teachers Foundation from Henan Province and the Students Innovative Pilot Plan of Henan University (2013, 2014).

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  1. Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecule and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, Henan, China

    Jie Luo, Jian-Cai Liu, Bo Shao, Li-Juan Chen & Jun-Wei Zhao

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  1. Jie Luo
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Correspondence to Jun-Wei Zhao.

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Luo, J., Liu, JC., Shao, B. et al. Two Organic–Inorganic Hybrids Assembled from Transition–Metal Complexes and Keggin-Type Silicotungstates. J Clust Sci 26, 2005–2022 (2015). https://doi.org/10.1007/s10876-015-0899-1

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