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Two Borate Supramolecular Frameworks Based on B4O5(OH)4 Cluster Units

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Abstract

Two new tetraborates, namely [Li(H2O)4]2[Cu(H2O)6][Cu(H2O)5]2[B4O5(OH)4]4·4H2O (1) and [Cu(en)2(H2O)2][Cu(en)2(B(OH)3)2][B4O5(OH)4]2·H2O (2) have been made under solvothermal conditions and characterized by FT-IR spectroscopy, powder X-ray diffraction, single crystal X-ray diffraction and thermogravimetric analysis, respectively. 1: triclinic, Pī, a = 7.0400(2) Å, b = 7.8779(3) Å, c = 25.8958(11) Å, α = 90.827(3)º, β = 95.985(3)º, γ = 105.816(3)º, Z = 1. 2: monoclinic, P2/c, a = 12.5723(6) Å, b = 9.1508(5) Å, c = 15.9800(6) Å, β = 94.742(4)º, Z = 2. In structure 1, the B4O5(OH)4 clusters join together via H-bonding interactions to produce 3-D supramolecular framework with three types of channels located by the Cu(H2O)6, Cu(H2O)5 and Li(H2O)4 polyhedra, respectively. While in 2, the B4O5(OH)4 clusters link each other to form 2-D layers and then further pillared by Cu(en)2(B(OH)3)2 complexes via H-bonding interactions, resulting in 3-D supramolecular framework with hexagonal and rectangle channels, in which the rectangle channels are filled by Cu(H2O)2(en)2 complexes.

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Acknowledgments

This work was supported by the NSFC (nos. 91122028, 50872133 and 21201017), the NSFC of Distinguished Young Scholars (No. 20725101), and the 973 Program (Nos. 2014CB932101).

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Authors and Affiliations

  1. MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, Beijing, 100081, China

    Guang Huang, Rui Pan, Huan He, Bai-Feng Yang & Guo-Yu Yang

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  1. Guang Huang
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  2. Rui Pan
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  3. Huan He
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Correspondence to Guo-Yu Yang.

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Huang, G., Pan, R., He, H. et al. Two Borate Supramolecular Frameworks Based on B4O5(OH)4 Cluster Units. J Clust Sci 26, 1993–2003 (2015). https://doi.org/10.1007/s10876-015-0894-6

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