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New Member of Organic Ligand Functionalized TMSP: Synthesis, Characterized and Properties of Na15[(MnII(COOH))3(AsW9O33)2]·15H2O

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Abstract

Reaction of [Mn12(CH3COO)16(H2O)4O12]·2CH3COOH·4H2O and Na9[AsW9O33]·19.5H2O in aqueous solution leads to the isolation of a new carboxy group decorated TMSP, Na15[(MnII(COOH))3(AsW9O33)2]·15H2O (1). The structure of 1 was characterized by elemental analysis, thermometric analysis and single crystal X-ray diffraction (Crystal data for 1: Trigonal, P-3, a = 12.8804(4) Å, b = 12.8804(4) Å, c = 30.3501(19) Å, V = 4360.6(3) Å3, Z = 2). Structural analysis reveals that 1 represents the first example of carboxy group decorated arsenotungstate. Antitumor study indicates that compound 1 possesses high antitumor activity against Hela cells. In addition, the magnetic properties of 1 were also investigated.

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Acknowledgments

This work was supported by National Natural Science Foundation of China (21201090). Applied Basic Research Programs of Science and Technology Commission Foundation of Yunnan Province (2012FD045), Kunming university students funding innovative projects (No. S1109).

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Authors and Affiliations

  1. Department of Chemical Science and Technology, Kunming University, Kunming, 65200, Yunnan, People’s Republic of China

    Qiong Wu, Fuyan Wang, Qian Cai & Lifen Sun

  2. Medical School, Kunming University, Kunming, 65200, Yunnan, People’s Republic of China

    Hongping Ju, Jian Tao & Jun Li

  3. Stem Cell, Tissue and Organ Engineering Research Center, Kunming General, Hospital of Chinese People’s Liberation Army, Kunming, 650032, People’s Republic of China

    Qiong Wu, Jun Li & Xinghua Pan

  4. Center for Disease Control and Prevention, Chengdu Military Region, Kunming, 650118, People’s Republic of China

    Qiong Wu

  5. Hebei Medical University, Shijiazhuang, 050017, Hebei, People’s Republic of China

    Zihao Chen

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  1. Qiong Wu
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Correspondence to Hongping Ju or Xinghua Pan.

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Wu, Q., Ju, H., Tao, J. et al. New Member of Organic Ligand Functionalized TMSP: Synthesis, Characterized and Properties of Na15[(MnII(COOH))3(AsW9O33)2]·15H2O. J Clust Sci 26, 1811–1820 (2015). https://doi.org/10.1007/s10876-015-0880-z

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  • DOI: https://doi.org/10.1007/s10876-015-0880-z

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