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One-Step Preparation of 1-D Copper(I) Polymer of Pyridyl-Ester with Fluorescence Properties

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Abstract

The reported metal complexes of ethyl isonicotinate (L) and its derivative ligands are usually synthetized by two-step method with difficult synthetic routes, but this work first provides one-step solvothermal method for preparation of 1-D copper(I) coordination polymer of ethyl isonicotinate [CuI(L)]n (1), where 1-D stair-step chain [Cu2I2]n is decorated by L ligand. 1 exhibits a fluorescence emission at room temperature, and its theoretical band structure has also been studied.

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Acknowledgment

This work was supported by the NNSF of china (No. 21163022), the NSF of Chongqing municipality (No. cstc2014jcyjA50002), and the Key Project of Chinese Ministry of Education (No. 212132) and Program for Excellent Talents in Chongqing Higher Education Institutions. The authors are also grateful to the innovative training program of university student (201410637004), graduate innovative research projects of Chongqing municipality (CYS14137) and Chongqing normal university for financial support (14CSLJ02,13XLZ07).

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Authors and Affiliations

  1. College of Chemistry, Chongqing Normal University, Chongqing, 401331, People’s Republic of China

    Qiuling Tang, Jian Zhou, Shumei Cao, Xing Liu, Rongqing Zhao & Xiaofeng Tan

  2. Chongqing Key Laboratory of Photo-Electric Functional Materials, Chongqing, 401331, People’s Republic of China

    Jian Zhou

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  1. Qiuling Tang
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  2. Jian Zhou
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  3. Shumei Cao
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  4. Xing Liu
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  5. Rongqing Zhao
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  6. Xiaofeng Tan
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Correspondence to Jian Zhou.

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Tang, Q., Zhou, J., Cao, S. et al. One-Step Preparation of 1-D Copper(I) Polymer of Pyridyl-Ester with Fluorescence Properties. J Clust Sci 26, 1735–1742 (2015). https://doi.org/10.1007/s10876-015-0871-0

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  • DOI: https://doi.org/10.1007/s10876-015-0871-0

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