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Synthesis, Structural Characterization and Thermal Behavior of New Organic–Inorganic Sulfate

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Abstract

The new organic–inorganic compound has been synthesized and characterized by X-ray single crystal, infra-red, Raman spectroscopy and thermal investigations. It crystallizes in the monoclinic space group P21 with following unit cell dimensions: a = 4.5542(2) Å, b = 10.5171(5) Å, c = 13.7373(6) Å, β = 93.936(2)°, Z = 2 and V = 656.42(5) Å3. The crystal structure has been determined and refined to R1 = 0.0395 and wR2 = 0.1143 using 3950 independent reflections. The atomic arrangement is defined by infinite anionic chains running parallel to the [100] direction. These last are interconnected to the organic cation by hydrogen bonds N–H…O to form a one dimensional network.

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Authors and Affiliations

  1. Laboratoire Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, 3018, Sfax, Tunisie

    Sami Soukrata, Mohamed Belhouchet & Tahar Mhiri

  2. Laboratoire des Oxydes et Fluorures, UMR 6010 CNRS, Faculté des Sciences et Techniques, Université du Maine, Avenue O. Messiaen, 72085, Le Mans Cedex 9, France

    Karim Adil

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  1. Sami Soukrata
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  2. Mohamed Belhouchet
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  4. Tahar Mhiri
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Correspondence to Sami Soukrata.

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Soukrata, S., Belhouchet, M., Adil, K. et al. Synthesis, Structural Characterization and Thermal Behavior of New Organic–Inorganic Sulfate. J Clust Sci 26, 1413–1424 (2015). https://doi.org/10.1007/s10876-014-0823-0

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  • DOI: https://doi.org/10.1007/s10876-014-0823-0

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