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Ligand Structure Induced Diversification from Dinuclear to 1D Chain Compounds: Syntheses, Structures and Fluorescence Properties

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Abstract

Using the solvothermal method, we present the comparative preparation of [Zn2(Hfhba)4(phen)2] (1), [Zn2(Hfhba)4(2,2′-bipy)2] (2) and [Zn2(Hfhba)4(4,4′-bipy)2]n (3), where H2fhba is 5-fluoro-2-hydroxy-benzoic acid, phen is 1,10-Phenanthroline, 2,2′-bipy is 2,2′-Bipyridine, 4,4′-bipy is 4,4′-Bipyridine. Complexes 1–3 were characterized by elemental analysis, IR, UV–Vis spectroscopy, and X-ray single-crystal diffraction. Complexes 1 and 2 are two new dinuclear complexes and 3 is a 1-D polymer. Luminescent properties of 1–3 have also been studied.

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Acknowledgments

This work is financially supported by Startup foundation for Dr Xiao of Guilin University of Technology.

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Authors and Affiliations

  1. Guangxi Scientific Experiment Center of Ming, Metallurgy and Environment, The Guangxi Talent Highland for Hazardous Waste Disposal Industrialization, Guilin University of Technology, Guilin, 541004, People’s Republic of China

    Yu Xiao & Pu Huang

  2. College of Chemistry and Bioengineering (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, Guilin, 541004, People’s Republic of China

    Wei Wang

Authors
  1. Yu Xiao
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  2. Pu Huang
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  3. Wei Wang
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Corresponding author

Correspondence to Yu Xiao.

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10876_2014_799_MOESM1_ESM.docx

CCDC 1013842–1013844 contains the supplementary crystallographic data for complex 1–3. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via http://www.ccdc.cam.ac.uk/data_request/cif. Electronic Supplementary Information (ESI) available: [Structure of 2, Packing drawing of 1 and 3.]

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Xiao, Y., Huang, P. & Wang, W. Ligand Structure Induced Diversification from Dinuclear to 1D Chain Compounds: Syntheses, Structures and Fluorescence Properties. J Clust Sci 26, 1091–1102 (2015). https://doi.org/10.1007/s10876-014-0799-9

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  • DOI: https://doi.org/10.1007/s10876-014-0799-9

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