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Synthesis and Molecular Structure of Redox Active Platinum–Bis(Telluroferrocenyl) Complex and its Chelated Rhenium-Chloro(Tricarbonyl) Derivative

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Abstract

A new chelating metalloligand (dppe)Pt(TeFc)2 (Fc = ferrocenyl) (1) was synthesized and used to prepare a mixed-metal tellurate-brigded complex (dppe)Pt(μ-TeFc)2Re(CO)3Cl (2). Both compounds were structurally and electrochemically investigated. Details of their molecular structure and CVA are discussed.

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Acknowledgments

We gratefully acknowledge the financial support from the Russian Foundation for Basic Research (Grant 13-03-92691, 12-03-00860, 13-03-12415) and RF President Fellowship (MK 5635.2013.03).

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Authors and Affiliations

  1. N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, GSP-1, Leninsky Prospect, 31, 119991, Moscow, Russia

    Alexander A. Pasynskii, Yury V. Torubaev, Alina Pavlova & Ivan V. Skabitsky

  2. Higher Chemical College of Russian Academy of Sciences, Miusskaya Sq. 9, 125047, Moscow, Russia

    Gleb Denisov

  3. A.N.Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, GSP-1, Leninsky Prospect, 31, 119991, Moscow, Russia

    Vitaly A. Grinberg

Authors
  1. Alexander A. Pasynskii
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  2. Yury V. Torubaev
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  3. Alina Pavlova
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  4. Ivan V. Skabitsky
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  5. Gleb Denisov
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  6. Vitaly A. Grinberg
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Corresponding author

Correspondence to Yury V. Torubaev.

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Appendix A

Appendix A

Atomic coordinates and other structural parameters of 1–2 have been deposited with the Cambridge Crystallographic Data Center (nos. CCDC 997651 (1), CCDC 997652 (2).

Supplementary data associated with this article can be found, in the online version, at https://www.ccdc.cam.ac.uk/services/structure_deposit/.

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Pasynskii, A.A., Torubaev, Y.V., Pavlova, A. et al. Synthesis and Molecular Structure of Redox Active Platinum–Bis(Telluroferrocenyl) Complex and its Chelated Rhenium-Chloro(Tricarbonyl) Derivative. J Clust Sci 26, 247–255 (2015). https://doi.org/10.1007/s10876-014-0767-4

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  • DOI: https://doi.org/10.1007/s10876-014-0767-4

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