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Synthesis, Crystal Structure and Characterization of 3d–4d–4f Heterometallic Clusters Based on Super Tetrahedron Anions

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Abstract

Five heterometallic complexes were prepared in aqueous solution at 3–5 °C and characterized by elemental analyses, inductively coupled plasma analysis, IR spectra, UV–Vis spectra, powder X-ray diffraction and X-ray single-crystal diffraction. Complex 1–5 all contain 4d–4f super tetrahedron cluster anions, which are constructed by LnIII ions (Ln = NdIII, PrIII), [MoO4]2− and [Mo7O24]6− anions. Differences among 1–5 lie on the assembly of super tetrahedron anions by excess LnIII and TMII (TM = CoII, NiII, CuII or ZnII), which generates bigger cluster anions (complex 1–4) or anions with 1D infinite structure (complex 5). The assemble styles for synthons mentioned above show with capped style, head-to-head linking style or side-by-side linking style.

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Acknowledgments

Thr Authors thank the financial support from the National Natural Science Foundation of China (21001026 and 61008040), the State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences (20110006).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350116, People’s Republic of China

    Shu-Ting Wu, Shu-Mei Lu, Hong-Liang Tang, Bin-Bin Deng, Xi-He Huang & Chang-Cang Huang

  2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, Fujian, People’s Republic of China

    Shu-Ting Wu

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  1. Shu-Ting Wu
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Correspondence to Shu-Ting Wu.

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Wu, ST., Lu, SM., Tang, HL. et al. Synthesis, Crystal Structure and Characterization of 3d–4d–4f Heterometallic Clusters Based on Super Tetrahedron Anions. J Clust Sci 25, 1413–1424 (2014). https://doi.org/10.1007/s10876-014-0718-0

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