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Hydroxo-Lanthanide Cluster Organic Framework Built by Hexanuclear Cluster Units

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Abstract

A novel hydroxo-lanthanide cluster organic framework, Sm3L8(μ 3-OH)(H2O)·H2O (1), derived from the 4-pyridin-4-ylbenzoic acid (HL) has been hydrothermally made and structurally characterized by single crystal X-ray diffraction. Structure analysis shows the hexanuclear Sm6 cluster unit is composed of inorganic tetranuclear hydroxo [Sm4(OH)2]10+ (Sm4) cluster and dimeric [Sm2(COO)4]2+ (Sm2) core. The Sm6 cluster units are connected by L ligands to form a 2D Ln-based cluster organic framework. From the topological point of view, the layer architecture can be described as 4-connected sql net. Furthermore, the elemental analysis, PXRD, IR and TGA are also studied.

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Acknowledgments

This work was supported by the NSFC (nos. 91122028, 21221001, and 50872133), the 973 Program (nos. 2014CB932101 and 2011CB932504), the NSFC for Distinguished Young Scholars (no. 20725101).

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Authors and Affiliations

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China

    Wei-Hui Fang & Guo-Yu Yang

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  1. Wei-Hui Fang
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  2. Guo-Yu Yang
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Correspondence to Guo-Yu Yang.

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Fang, WH., Yang, GY. Hydroxo-Lanthanide Cluster Organic Framework Built by Hexanuclear Cluster Units. J Clust Sci 25, 1401–1411 (2014). https://doi.org/10.1007/s10876-014-0717-1

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