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Synthesis and Characterization of a 3-D Framework Constructed from [V12B18O54(OH)6(H2O)]10− Clusters and K+ Cations

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Abstract

An organic–inorganic hybrid polyoxovanadoborate K6(CH3NH3)4[V12B18O54(OH)6-(H2O)]·2en·12H2O (1, en = ethylenediamine) has been synthesized under hydrothermal conditions and characterized by IR spectroscopy, element analyses, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) and single-crystal X-ray diffraction. Single-crystal structure analysis reveals that 1 consists of a cage-like polyoxovanadium borate [V12B18O54(OH)6(H2O)]10− cluster that is constructed from a puckered {B18O36(OH)6} ring sandwiched by two triangle {V6O18} units, in which a water molecule is confined in the middle of the cage-like cluster. Interestingly, 1 represents the rare example of extended 3-D framework constructed from [V12B18O54(OH)6-(H2O)]10− clusters through K+ cations.

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Acknowledgments

This work was supported by the NNSF of China (Nos. 91122028, 21221001, 50872133 and 21101055), the NNSF for Distinguished Young Scholars of China (No. 20725101), and the 973 Program (Nos. 2014CB932101 and 2011CB932504).

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Authors and Affiliations

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, Fujian, China

    Guo-Yu Yang

  2. MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, Beijing, 100081, China

    Qin Meng, Huan He, Bai-Feng Yang & Guo-Yu Yang

  3. Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, Henan, China

    Jun-Wei Zhao

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  1. Qin Meng
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  2. Huan He
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Correspondence to Jun-Wei Zhao or Guo-Yu Yang.

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Meng, Q., He, H., Yang, BF. et al. Synthesis and Characterization of a 3-D Framework Constructed from [V12B18O54(OH)6(H2O)]10− Clusters and K+ Cations. J Clust Sci 25, 1273–1282 (2014). https://doi.org/10.1007/s10876-014-0705-5

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  • DOI: https://doi.org/10.1007/s10876-014-0705-5

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