Skip to main content
Log in

Ambient volatile organic compounds in the atmosphere of industrial central India

  • Published:
Journal of Atmospheric Chemistry Aims and scope Submit manuscript

Abstract

Volatile organic compounds (VOCs) are an important group of compounds because of their role in atmospheric chemistry and the risk they pose to human health and ecosystem. Therefore, the interest in determining VOCs in the atmosphere has increased over the last few decades to understand their emission, distribution, and sources. Considering the expanding urbanization and increasing use of fuels, very limited data of VOCs in India is available. This paper describes the chemical analysis of 12 light VOCs in 144 ambient air samples collected from three different sites near Raipur, India during a period of April, 2006-March, 2007 in order to understand their temporal and spatial distributions. This data has provided some important insights into the VOC profile, for the first time, of an industrial area in India. The annual average concentrations of all 12 VOCs in our study ranged from 43.2 to 160.4 μg m−3 (mean: 95.6 ± 31.0). The annual average concentration of individual VOCs in Raipur region ranged from 3.4 μg m−3 for xylenes to 18.3 μg m−3 for n-butane. n-Butane, i-butane, and propane were the three most abundant pollutants among all of the VOCs measured. The observed concentrations of these compounds in Raipur region were comparable to other Asian cities with some exceptions. The levels of total VOCs showed seasonal variations with a statistically significant winter maximum and lower values during summer and monsoon ranging from 55.9 ± 9.9 μg/m3 in August to 144.5 ± 15.5 μg/m3 in January. Sources of these VOCs have been described using species ratios and correlation studies.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  • Atkinson, R.: Atmospheric chemistry of VOCs and NOx. Atmos Environ 34, 2063–2101 (2000)

    Article  Google Scholar 

  • Barletta, B., Meinardi, S., Simpson, I.J., Khwaja, H.A., Blake, D.R., Rowland, F.S.: Mixing ratios of volatile organic compounds (VOCs) in the atmosphere of Karachi, Pakistan. Environ 36, 3429–3443 (2002)

  • Blake, D.R., Rowland, F.S.: Urban leakage of liquefied petroleum gas and its impact on Mexico City air quality. Science 269, 953–956 (1995)

    Article  Google Scholar 

  • Borbon, A., Locoge, N., Veillerot, M., Galloo, J.C., Guillermo, R.: Characterisation of NMHCs in a French urban atmosphere: overview of the main sources. Sci Total Environ 292, 177–191 (2002)

    Article  Google Scholar 

  • Brocco, D., Fratarcangeli, R., Lepore, L., Petricca, M., Ventrone, I.: Determination of aromatic hydrocarbons in urban air of Rome. Atmos Environ 31, 557–566 (1997)

    Article  Google Scholar 

  • Camel, V., Caude, M.: Trace enrichment methods for the determination of organic pollutants in ambient air. J Chromatogr A 710, 3–19 (1995)

    Article  Google Scholar 

  • Chameides, W.L., Fehsenfeld, F., Rodgers, M.O., Cardelino, C., Martinez, J., Parrish, D., Lonneman, W., Lawson, R., Rasmussen, R.A., Zimmerman, P., Greenberng, J., Wang, T.: Ozone precursor relationships in the ambient atmosphere. J Geophys Res Atmos 97, 6037–6055 (1992)

    Article  Google Scholar 

  • Chattopadhyay, G., Samanta, G., Chatterjee, P.: Determination of benzene, toluene and xylene in ambient air of Calcutta for three years during winter. Environ Technol 18, 211–218 (1997)

    Article  Google Scholar 

  • Chen, T.Y., Simpson, I.J., Blake, D.R., Rowland, F.S.: Impact of the leakage of liquefied petroleum gas (LPG) on Santiago air quality. Geophys Res Lett 28, 2193–2196 (2001)

    Article  Google Scholar 

  • Cheng, L., Fu, L., Angle, R.P., Sandhu, H.S.: Seasonal variations of volatile organic compounds in Edmonton. Alberta Atmos Environ 31, 239–246 (1997)

    Article  Google Scholar 

  • Chou, C.C.K., Lee, C.T., Chen, W.N., Chang, S.Y., Chen, T.K., Lin, C.Y., Chen, J.P.: Lidar observations of the diurnal variations in the depth of urban mixing layer: a case study on the air quality deterioration in Taipei. Taiwan Sci Total Environ 374, 156–166 (2007)

    Article  Google Scholar 

  • Derwent, R.G., Davies, T.J., Delaney, M., Dollard, G.J., Field, R.A., Dumitrean, P., Pepler, S.A.: Analysis and interpretation of the continuous hourly monitoring data for 26 C2-C8 hydrocarbons at 12 United Kingdom sites during 1996. Atmos Environ 34, 297–312 (2000)

    Article  Google Scholar 

  • Deshmukh, D.K., Deb, M.K., Mkoma, S.L.: Size distribution and seasonal variation of size-segregated particulate matter in the ambient air of Raipur city, India. Air Qual Atmos Health 6, 259–276 (2013)

    Article  Google Scholar 

  • Ding, W. H., & Wang, J. L.: Spatial concentration profiles of C 2-C 6 hydrocarbons in the atmosphere of Taipei metropolitan area. Chemosphere 37(6), 1187–1195 (1998)

  • Dutta, C., Som, D., Chatterjee, A., Mukherjee, A.K., Jana, T.K., Sen, S.: Mixing ratios of carbonyls and BTEX in ambient air of Kolkata, India and their associated health risk. Environ Monit Assess 148, 97–107 (2009)

    Article  Google Scholar 

  • Filella, I., Penuelas, J.: Daily, weekly and seasonal relationships among VOCs, NOx and O3 in a semi-urban area near Barcelona. J Atmos Chem 54, 189–201 (2006)

    Article  Google Scholar 

  • Finlayson-Pitts, B.J., Pitts, J.N.: Tropospheric air pollution: ozone, airborne toxics, polycyclic aromatic hydrocarbons, and particles. Science 276, 1045–1051 (1997)

    Article  Google Scholar 

  • Gee, I.L., Sollars, C.J.: Ambient air levels of volatile organic compounds in Latin American and Asian cities. Chemosphere 36, 2497–2506 (1998)

    Article  Google Scholar 

  • Genc, D.D., Yesilyurt, C., Tuncel, G.: Air pollution forecasting in Ankara, Turkey using air pollution index and its relation to assimilative capacity of the atmosphere. Environ Monit Assess 166, 11–27 (2010)

    Article  Google Scholar 

  • Giri, B., Patel, K.S., Jaiswal, N.K., Sharma, S., Ambade, B., Wang, W., Simonich, S.L.M., Simoneit, B.R.T.: Composition and sources of organic tracers in aerosol particles of industrial central India. Atmos Res 120, 312–324 (2013)

    Article  Google Scholar 

  • Guo, H., So, K. L., Simpson, I. J., Barletta, B., Meinardi, S., & Blake, D. R.: C 1–C 8 volatile organic compounds in the atmosphere of Hong Kong: Overview of atmospheric processing and source apportionment. Atmospheric Environment 41, 1456–1472 (2007)

  • Hartmann, R., Voght, U., Baumbach, G., Seyfioglu, R., Muezzinoglu, A.: Results of emission and ambient air measurements of VOC in Izmir. Environ Res Forum 7, 107–112 (1997)

    Google Scholar 

  • Hewitt CNE (1998) Reactive hydrocarbons in the atmosphere: Academic press

  • Hoque, R.R., Khillare, P.S., Agarwal, T., Shridhar, V., Balachandran, S.: Spatial and temporal variation of BTEX in the urban atmosphere of Delhi. India Sci Total Environ 392, 30–40 (2008)

    Article  Google Scholar 

  • Khoder, M.I.: Ambient levels of volatile organic compounds in the atmosphere of Greater Cairo. Atmos Environ 41, 554–566 (2007)

    Article  Google Scholar 

  • Lee, S.C., Chiu, M.Y., Ho, K.F., Zou, S.C., Wang, X.: Volatile organic compounds (VOCs) in urban atmosphere of Hong Kong. Chemosphere 48(2), 375–382 (2002)

    Article  Google Scholar 

  • Mayrsohn, H., Crabtree, J.H.: Source reconciliation of atmospheric hydrocarbons. Atmos Environ 10, 137–143 (1976)

    Article  Google Scholar 

  • McCarthy, M.C., O’Brien, T.E., Charrier, J.G., Hafner, H.: Characterization of the chronic risk and hazard of hazardous air pollutants in the united states using ambient monitoring data. Environ Health Perspect 117, 790–796 (2009)

    Article  Google Scholar 

  • Mohan Rao, A.M., Pandit, G.G., Sain, P., Sharma, S., Krishnamoorthy, T.M., Nambi, K.S.V.: Non-methane hydrocarbons in industrial locations of Bombay. Atmos Environ 31, 1077–1085 (1997)

    Article  Google Scholar 

  • Monod, A., Sive, B.C., Avino, P., Chen, T., Blake, D.R., Sherwood Rowland, F.: Monoaromatic compounds in ambient air of various cities: a focus on correlations between the xylenes and ethylbenzene. Atmos Environ 35, 135–149 (2001)

    Article  Google Scholar 

  • Morikawa, T., Wakamatsu, S., Tanaka, M., Uno, I., Kamiura, T., Maeda, T.: C2-C5 hydrocarbon concentrations in Central Osaka. Atmos Environ 32, 2007–2016 (1998)

    Article  Google Scholar 

  • Na, K., Kim, Y.P.: Seasonal characteristics of ambient volatile organic compounds in Seoul. Korea Atmos Environ 35, 2603–2614 (2001)

    Article  Google Scholar 

  • Na, K., Kim, Y.P., Moon, K.C.: Diurnal characteristics of volatile organic compounds in the Seoul atmosphere. Atmos Environ 37, 733–742 (2003)

    Article  Google Scholar 

  • Na, K., Kim, Y.P., Moon, I., Moon, K.C.: Chemical composition of major VOC emission sources in the Seoul atmosphere. Chemosphere 55, 585–594 (2004)

    Article  Google Scholar 

  • Ng, N.L., Kroll, J.H., Chan, A.W.H., Chhabra, P.S., Flagan, R.C., Seinfeld, J.H.: Secondary organic aerosol formation from m-xylene, toluene, and benzene. Atmos Chem Phys 7, 3909–3922 (2007)

    Article  Google Scholar 

  • Padhy, P., Varshney, C.: Total non methane volatile organic compounds in the atmosphere of Delhi. Atmos Environ 34, 577–584 (2000)

    Article  Google Scholar 

  • Parra, M.A., Elustondo, D., Bermejo, R., Santamaria, J.M.: Ambient air levels of volatile organic compounds (VOC) and nitrogen dioxide (NO2) in a medium size city in Northern Spain. Sci Total Environ 407, 999–1009 (2009)

    Google Scholar 

  • Perry, R., Gee, I.L.: Vehicle emissions and effects on air quality: indoors and outdoors. Indoor Built Environ 3, 224–236 (1994)

    Article  Google Scholar 

  • Perry, R., Gee, I.L.: Vehicle emissions in relation to fuel composition. Sci Total Environ 169, 149–156 (1995)

    Article  Google Scholar 

  • Ras, M.R., Borrull, F., Marcé, R.M.: Sampling and preconcentration techniques for determination of volatile organic compounds in air samples. TrAC Trends Anal Chem 28, 347–361 (2009)

    Article  Google Scholar 

  • Rodolfo Sosa, E., Humberto Bravo, A., Violeta Mugica, A., Pablo Sanchez, A., Emma Bueno, L., Krupa, S.: Levels and source apportionment of volatile organic compounds in southwestern area of Mexico City. Environ Pollut 157, 1038–1044 (2009)

    Article  Google Scholar 

  • Russo, R.S., Zhou, Y., White, M.L., Mao, H., Talbot, R., Sive, B.C.: Multi-year (2004–2008) record of nonmethane hydrocarbons and halocarbons in New England: seasonal variations and regional sources. Atmos Chem Phys 10, 4909–4929 (2010)

    Article  Google Scholar 

  • Sahu, L.K., Lal, S.: Distributions of C2–C5 NMHCs and related trace gases at a tropical urban site in India. Atmos Environ 40, 880–891 (2006)

    Article  Google Scholar 

  • Scheff, P.A., Wadden, R.A.: Receptor modeling of volatile organic compounds. 1. Emission inventory and validation. Environ Sci Tech 27, 617–625 (1993)

    Article  Google Scholar 

  • Sharma, S.: Diurnal study of VOCs in Raipur, Chhattisgarh. Res J Eng Technol 5, 7–8 (2014)

    Google Scholar 

  • Sharma, U.K., Kajii, Y., Akimoto, H.: Characterization of NMHCs in downtown urban center Kathmandu and rural site in Nagarkot in Nepal. Atmos Environ 34, 3297–3307 (2000)

    Article  Google Scholar 

  • Shirai, T., Yokouchi, Y., Blake, D.R., Kita, K., Izumi, K., Koike, M., Kondo, Y.: Seasonal variations of atmospheric C2–C7 nonmethane hydrocarbons in Tokyo. J Geophys Res Atmos 112, 1984–2012 (2007)

    Article  Google Scholar 

  • Singh, H.B.Z., Zimmerman, P.R.: Atmospheric distribution and sources of non-methane hydrocarbons. Wiley, New York (1992)

    Google Scholar 

  • Singh, H.B., Salas, L.J., Cantrell, B.K., Redmond, R.M.: Distribution of aromatic hydrocarbons in the ambient air. Atmos Environ 19, 1911–1919 (1985)

    Article  Google Scholar 

  • Srivastava, A.: Variability in VOC concentrations in an urban area of Delhi. Environ Monit Assess 107, 363–373 (2005)

    Article  Google Scholar 

  • Srivastava, A., Joseph, A.E., Devotta, S.: Volatile organic compounds in ambient air of Mumbai-India. Atmos Environ 40, 892–903 (2006)

    Article  Google Scholar 

  • USEPA 2004 Air quality criteria for particulate matter (2004)

  • WHO (2000) Air Quality Guidelines for Europe. Copenhagen: WHO Regional Publication, European Series. World Health Organization. Regional Office for Europe

  • Yamamoto, N., Okayasu, H., Murayama, S., Mori, S., Hunahashi, K., Suzuki, K.: Measurement of volatile organic compounds in the urban atmosphere of Yokohama, Japan, by an automated gas chromatographic system. Atmos Environ 34(26), 4441–4446 (2000)

    Article  Google Scholar 

  • Yurdakul, S., Civan, M., Tuncel, G.: Volatile organic compounds in suburban Ankara atmosphere, Turkey: sources and variability. Atmos Res 120, 298–311 (2013)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Saroj Sharma.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sharma, S., Giri, B. & Patel, K.S. Ambient volatile organic compounds in the atmosphere of industrial central India. J Atmos Chem 73, 381–395 (2016). https://doi.org/10.1007/s10874-016-9329-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10874-016-9329-5

Keywords

Navigation