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Synthesis and Crystal Structures of the Nickel(II) and [Tri(n-butyl)]tin(IV) Complexes with the New Sulfonamide Carboxylic Acid, 4-{(2-Nitrophenylsulfonamido)methyl}cyclohexanecarboxylic Acid

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Abstract

The structures of the nickel(II) and [tri(n-butyl)]tin(IV) complexes with the sulfonamide carboxylic acid, 4-{(2-nitrophenylsulfonamido)methyl}cyclohexanecarboxylic acid, [Ni(C14H17N2O6S)2(H2O)4], (1), and [Sn(C4H9)3(C14H17N2O6S)]n, (2) have been determined. Crystals of 1 are triclinic, space group P−1, with unit cell dimensions a = 5.2264(4), b = 6.2415(2), c = 27.1409(16) Å, α = 85.682(4), β = 89.935(4), γ = 82.861(5)o and Z = 1, while compound 2 is monoclinic, space group C2/c, with unit cell dimensions a = 30.425(3), b = 10.1384(5), c = 19.4463(13) Å, β = 92.303(7)o and Z = 8. Compound 1 is a discrete centrosymmetric octahedral NiO6 complex comprising four waters and two O-donors from inversion-related monodentate carboxylate ligands. Compound 2 is coordination polymeric with the five-coordinate SnIV centre having the common trigonal bipyramidal repeat unit with three tri(n-butyl) groups occupying the trigonal plane of the bipyramid and the carboxylate O-donors bridging the apical sites.

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Acknowledgements

We are thankful to Higher Education Commission (HEC) of Pakistan for funding this work under the Project No. 20-2549/NRPU/R&D/HEC/12. GS acknowledges support from the Science and Engineering Faculty, Queensland University of Technology, Brisbane, Australia.

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Authors and Affiliations

  1. Department of Chemistry, University of Gujrat, Gujrat, 50700, Pakistan

    Muhammad Danish, Rabia Ayub Butt, Saba Akbar & Muhammad Ashfaq

  2. Science and Engineering Faculty, Queensland University of Technology, Brisbane, 4001, Australia

    Graham Smith

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  1. Muhammad Danish
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  2. Rabia Ayub Butt
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  3. Saba Akbar
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  4. Muhammad Ashfaq
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Correspondence to Muhammad Danish or Graham Smith.

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Danish, M., Butt, R.A., Akbar, S. et al. Synthesis and Crystal Structures of the Nickel(II) and [Tri(n-butyl)]tin(IV) Complexes with the New Sulfonamide Carboxylic Acid, 4-{(2-Nitrophenylsulfonamido)methyl}cyclohexanecarboxylic Acid. J Chem Crystallogr 46, 421–428 (2016). https://doi.org/10.1007/s10870-016-0671-x

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