Journal of Chemical Crystallography

, Volume 40, Issue 4, pp 316–322

Supramolecular Organization in Tetra Aqua (μ-8-Hydroxyquinoline-5-sulfonate) Barium (II) and Ag···I Interactions in a Pseudopolymorphic Form of (7-Iodo-8-hydroxyquinoline-5-sulfonate) Silver (I) Monohydrate

  • K. Balasubramani
  • M. Hemamalini
  • S. Francis
  • P. Thomas Muthiah
  • T. Vijay
  • T. N. Guru Row
  • G. Bocelli
  • A. Cantoni
Original Paper

DOI: 10.1007/s10870-009-9653-6

Cite this article as:
Balasubramani, K., Hemamalini, M., Francis, S. et al. J Chem Crystallogr (2010) 40: 316. doi:10.1007/s10870-009-9653-6
  • 100 Views

Abstract

The complexes, Ba (HQS) (H2O)4 (HQS = 8-hydroxyquinoline-5-sulfonic acid) (1) and Ag (HIQS) (H2O) (Ferron = 7-iodo-8-hydroxyquinoline-5-sulfonic acid) (2) have been synthesized and characterized by X-ray diffraction analysis and spectroscopic studies. In compound 1, Ba2+ ion has a nine-coordinate monocapped antiprismatic geometry. In compound 2, Ag+ has distorted tetrahedral coordination and Ag···I interactions generate the supramolecular architectures. The complexes have been characterized by FT-IR and UV–Visible measurements. In both the structures, the inversion-related organic ligands are stacked over one another leading to three-dimensional networks.

Graphical Abstract

https://static-content.springer.com/image/art%3A10.1007%2Fs10870-009-9653-6/MediaObjects/10870_2009_9653_Figa_HTML.gif

Keywords

Metal sulfoxinatesSupramolecular chemistryPseudopolymorphismX-ray diffraction analysisIR spectraElectronic spectra

Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  • K. Balasubramani
    • 1
  • M. Hemamalini
    • 1
  • S. Francis
    • 1
  • P. Thomas Muthiah
    • 1
  • T. Vijay
    • 2
  • T. N. Guru Row
    • 2
  • G. Bocelli
    • 3
  • A. Cantoni
    • 3
  1. 1.School of ChemistryBharathidasan UniversityTiruchirappalliIndia
  2. 2.Solid State & Structural Chemistry UnitIndian Institute of ScienceBangaloreIndia
  3. 3.IMEM-CNRFontanini-ParmaItaly