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Supramolecular Organization in Tetra Aqua (μ-8-Hydroxyquinoline-5-sulfonate) Barium (II) and Ag···I Interactions in a Pseudopolymorphic Form of (7-Iodo-8-hydroxyquinoline-5-sulfonate) Silver (I) Monohydrate

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Abstract

The complexes, Ba (HQS) (H2O)4 (HQS = 8-hydroxyquinoline-5-sulfonic acid) (1) and Ag (HIQS) (H2O) (Ferron = 7-iodo-8-hydroxyquinoline-5-sulfonic acid) (2) have been synthesized and characterized by X-ray diffraction analysis and spectroscopic studies. In compound 1, Ba2+ ion has a nine-coordinate monocapped antiprismatic geometry. In compound 2, Ag+ has distorted tetrahedral coordination and Ag···I interactions generate the supramolecular architectures. The complexes have been characterized by FT-IR and UV–Visible measurements. In both the structures, the inversion-related organic ligands are stacked over one another leading to three-dimensional networks.

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Scheme 1
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Acknowledgment

S. F. thanks the Council of Scientific and Industrial Research, New Delhi, India for the award of Senior Research Fellowship [Ref. No. 9/475(123) 2004- EMRI]. M. H. thanks the Council of Scientific and Industrial Research, New Delhi, India for the award of Senior Research Fellowship [Ref. No. 9/475(123) 2004- EMRI].

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Authors and Affiliations

  1. School of Chemistry, Bharathidasan University, Tiruchirappalli, 620 024, India

    K. Balasubramani, M. Hemamalini, S. Francis & P. Thomas Muthiah

  2. Solid State & Structural Chemistry Unit, Indian Institute of Science, Bangalore, India

    T. Vijay & T. N. Guru Row

  3. IMEM-CNR, Parco Area Delle Scienze 37a, 43010, Fontanini-Parma, Italy

    G. Bocelli & A. Cantoni

Authors
  1. K. Balasubramani
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  2. M. Hemamalini
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  3. S. Francis
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  4. P. Thomas Muthiah
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  5. T. Vijay
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  6. T. N. Guru Row
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  7. G. Bocelli
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  8. A. Cantoni
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Correspondence to P. Thomas Muthiah.

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Balasubramani, K., Hemamalini, M., Francis, S. et al. Supramolecular Organization in Tetra Aqua (μ-8-Hydroxyquinoline-5-sulfonate) Barium (II) and Ag···I Interactions in a Pseudopolymorphic Form of (7-Iodo-8-hydroxyquinoline-5-sulfonate) Silver (I) Monohydrate. J Chem Crystallogr 40, 316–322 (2010). https://doi.org/10.1007/s10870-009-9653-6

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  • DOI: https://doi.org/10.1007/s10870-009-9653-6

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