Abstract
We present a simple method for passivation of silicon solar cells at room temperature. Oleylamine has been used as passivation agent on the n-type emitter of silicon solar cell surface. The desired effect is seen in the form of apparent enhancement in efficiency of the solar cell after coating. The efficiency increases by an amount of 14 % as compared to the one without any passivation applied and antireflection coating. The efficiency was found to decrease marginally and stabilized later. Device performance was monitored for 100 h and the efficiency was found higher as compare to bare solar cell without passivation coating.
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M.A. Green, Crystalline and thin-film silicon solar cells: state of the art and future potential. Sol. Energy 74(3), 181–192 (2003)
Survey Report of Selected IEA Countries between 1992 and 2014, In trends 2015 in photovoltaic applications 20th edition 2015, IEA International Energy Agency. p. Report IEA-PVPS T1-27:2015 (2015)
M.A. Green et al., Solar cell efficiency tables (Version 45). Prog. Photovoltaics Res. Appl. 23(1), 1–9 (2015)
S. Zhong et al., High-efficiency nanostructured silicon solar cells on a large scale realized through the suppression of recombination channels. Adv. Mater. 27(3), 555–561 (2015)
W. Soppe, H. Rieffe, A. Weeber, Bulk and surface passivation of silicon solar cells accomplished by silicon nitride deposited on industrial scale by microwave PECVD. Prog. Photovolt. Res. Appl. 13(7), 551–569 (2005)
S. De Wolf et al., Influence of stoichiometry of direct plasma-enhanced chemical vapor deposited SiNx films and silicon substrate surface roughness on surface passivation. J. Appl. Phys. 97(6), 063303 (2005)
P. Panek et al., A comparative study of SiO2 deposited by PECVD and thermal method as passivation for multicrystalline silicon solar cells. Mater. Sci. Eng. B 165(1–2), 64–66 (2009)
C. Rajesh et al., Reduction in surface recombination through hydrogen and 1-heptene passivated silicon nanocrystals film on silicon solar cells. Sol. Energy 86(1), 489–495 (2012)
Y. Morita, H. Tokumoto, Ideal hydrogen termination of Si(001) surface by wet-chemical preparation. Appl. Phys. Lett. 67(18), 2654–2656 (1995)
B. Rijksen et al., Hexadecadienyl monolayers on hydrogen-terminated Si(111): faster monolayer formation and improved surface coverage using the enyne moiety. Langmuir 28(16), 6577–6588 (2012)
N. Clément et al., Role of hydration on the electronic transport through molecular junctions on silicon. J. Phys. Chem. C 116(33), 17753–17763 (2012)
W. Cai et al., Chemical modification and patterning of iodine-terminated silicon surfaces using visible light. J. Phys. Chem. B 106(10), 2656–2664 (2002)
N. Batra et al., A comparative study of silicon surface passivation using ethanolic iodine and bromine solutions. Sol. Energy Mater. Sol. Cells 100, 43–47 (2012)
S. Patil et al., Passivation of n-type emitter and p-type base in solar cells via oxygen terminated silicon nanoparticles. Prog. Photovolt. 21(5), 1146–1152 (2013)
S. Mourdikoudis, L.M. Liz-Marzán, Oleylamine in nanoparticle synthesis. Chem. Mater. 25(9), 1465–1476 (2013)
K. Ali, S.A. Khan, M.Z.M. Jafri, Effect of double layer (SiO2/TiO2) anti-reflective coating on silicon solar cells. Int. J. Electrochem. Sci. 2014(9), 7865–7874 (2014)
R. James, C.P. Durig, G.A. Guirgis, Guirgis, spectra and structure of silicon containing compounds. XXXII. Raman and infrared spectra, conformational stability, vibrational assignment and ab initio calculations of n-propylsilane-d0 and Si-d3. Spectrochim. Acta A 59, 979–1002 (2003)
Acknowledgments
This research is based upon work supported in part by the Solar Energy Research Institute for India and the U.S. (SERIIUS) funded jointly by the U.S. Department of Energy Subcontract DE AC36-08G028308 (Office of Science, Office of Basic Energy Sciences, and Energy Efficiency and Renewable Energy, Solar Energy Technology Program, with support from the Office of International Affairs) and the Government of India Subcontract IUSSTF/JCERDC-SERIIUS/2012 dated 22 Nov. 2012. The author also grateful to MNRE Govt of India for providing part of the funding for this project through Centre of Excellence in Renewable Energy at School of Energy Studies, SP Pune University (GOI-A-171). AMF acknowledges the funding from BCUD (BCUD/372/2014), Savitribai Phule Pune University.
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Shinde, O.S., Funde, A.M., Agarwal, M. et al. Emitter passivation of silicon solar cell via organic coating at room temperature. J Mater Sci: Mater Electron 27, 12459–12463 (2016). https://doi.org/10.1007/s10854-016-5706-8
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DOI: https://doi.org/10.1007/s10854-016-5706-8