Abstract
The current status of the development of composite thermoelectric materials with embedded nanoparticles is reviewed. An introduction is given to the suggested mechanisms of improving thermoelectric properties by inclusions of nanoparticles and to experimental methods used to prepare such composites. The progress made in the development of thermoelectric materials with embedded nanoparticles is then covered, grouping the studies according to the optimal temperature range of operation of the materials investigated. Most studies have been devoted to materials within the medium temperature range, followed by low temperature materials, whereas high temperature materials have not yet received much attention within this area. In the majority of the materials systems studied, reports of improved thermoelectric performance upon introduction of nanoparticles in bulk thermoelectrics are found. However, for continued progress in this area, there is a need for systematic experimental studies that unambiguously correlate the resulting physical effects of the nanoinclusions to the measured materials properties.
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Vineis CJ, Shakouri A, Majumdar A, Kanatzidis MG (2010) Adv Mater 22(36):3970. doi:10.1002/adma.201000839
Dresselhaus MS, Chen G, Tang MY, Yang RG, Lee H, Wang DZ, Ren ZF, Fleurial JP, Gogna P (2007) Adv Mater 19(8):1043
Minnich AJ, Dresselhaus MS, Ren ZF, Chen G (2009) Energy Environ Sci 2(5):466
Medlin DL, Snyder GJ (2009) Curr Opin Colloid Interface Sci 14(4):226. doi:10.1016/j.cocis.2009.05.001
Hicks LD, Dresselhaus MS (1993) Phys Rev B 47(24):16631
Hicks LD, Dresselhaus MS (1993) Phys Rev B 47(19):12727
Venkatasubramanian R, Siivola E, Colpitts T, O’Quinn B (2001) Nature 413(6856):597. doi:10.1038/35098012
Winkler M, Liu X, Konig JD, Buller S, Schurmann U, Kienle L, Bensch W, Bottner H (2012) J Mater Chem 22(22):11323
Rowe DM, Shukla VS, Savvides N (1981) Nature 290(5809):765
Bux SK, Fleurial JP, Kaner RB (2010) Chem Commun 46(44):8311. doi:10.1039/c0cc02627a
Fan SF, Zhao JN, Guo J, Yan QY, Ma J, Hng HH (2010) Appl Phys Lett 96(18):182104. doi:10.1063/1.3427427
Zhao L-D, Zhang B-P, Liu W-S, Li J-F (2009) J Appl Phys 105(2):023704. doi:10.1063/1.3063694
Scoville N, Bajgar C, Rolfe J, Fleurial JP, Vandersande J (1995) Nanostruct Mater 5(2):207
Zebarjadi M, Esfarjani K, Shakouri A, Bahk J-H, Bian Z, Zeng G, Bowers J, Lu H, Zide J, Gossard A (2009) Appl Phys Lett 94(20):202105. doi:10.1063/1.3132057
Zhou J, Li XB, Chen G, Yang RG (2010) Phys Rev B 82(11):115308. doi:10.1103/Physrevb.82.115308
Faleev SV, Leonard F (2008) Phys Rev B 77(21):214304. doi:10.1103/PhysRevB.77.214304
Kim W, Zide J, Gossard A, Klenov D, Stemmer S, Shakouri A, Majumdar A (2006) Phys Rev Lett 96(4):045901. doi:10.1103/PhysRevLett.96.045901
Bhandari CM (1995) Minimizing the thermal conductivity. In: Rowe DM (ed) CRC handbook of thermoelectrics. CRC Press LLC, Boca Raton, p 55
Prasher R (2006) J Heat Transf 128(7):627
Mingo N, Hauser D, Kobayashi NP, Plissonnier M, Shakouri A (2009) Nano Lett 9(2):711. doi:10.1021/nl8031982
Kim W, Majumdar A (2006) J Appl Phys 99(8):084306
Ying CF, Truell R (1956) J Appl Phys 27(9):1086
Kim W, Singer SL, Majumdar A, Zide JMO, Klenov D, Gossard AC, Stemmer S (2008) Nano Lett 8(7):2097. doi:10.1021/nl080189t
Zide JMO, Vashaee D, Bian ZX, Zeng G, Bowers JE, Shakouri A, Gossard AC (2006) Phys Rev B 74 (20):205335. doi:10.1103/PhysRevB.74.205335
Heremans JP, Thrush CM, Morelli DT (2005) J Appl Phys 98(6):063703. doi:10.1063/1.2037209
Vashaee D, Shakouri A (2004) Phys Rev Lett 92(10):106103. doi:10.1103/PhysRevLett.92.106103
Urban JJ, Talapin DV, Shevchenko EV, Kagan CR, Murray CB (2007) Nat Mater 6(2):115. doi:10.1038/nmat1826
Ristein J (2006) Science 313(5790):1057. doi:10.1126/science.1127589
Mahan GD, Sofo JO (1996) Proc Natl Acad Sci 93(15):7436
Mott NF, Jones H (1936) The theory of the properties of metals and alloys. The international series of monographs on physics, 1 edn. Oxford University Press, Oxford
Heremans JP, Jovovic V, Toberer ES, Saramat A, Kurosaki K, Charoenphakdee A, Yamanaka S, Snyder GJ (2008) Science 321(5888):554. doi:10.1126/science.1159725
Poudel B, Hao Q, Ma Y, Lan Y, Minnich A, Yu B, Yan X, Wang D, Muto A, Vashaee D, Chen X, Liu J, Dresselhaus MS, Chen G, Ren Z (2008) Science 320(5876):634. doi:10.1126/science.1156446
Chen C, Liu DW, Zhang BP, Li JF (2011) J Electron Mater 40(5):942. doi:10.1007/s11664-010-1463-2
Zhang T, Zhang Q, Jiang J, Xiong Z, Chen J, Zhang Y, Li W, Xu G (2011) Appl Phys Lett 98(2):022104. doi:10.1063/1.3541654
Ganguly S, Zhou C, Morelli D, Sakamoto J, Uher C, Brock SL (2011) J Solid State Chem 184(12):3195. doi:10.1016/j.jssc.2011.09.031
Sun JH, Qin XY, Xin HX, Li D, Pan L, Song CJ, Zhang J, Sun RR, Wang QQ, Liu YF (2010) J Alloys Compd 500(2):215. doi:10.1016/j.jallcom.2010.04.006
Zhao L-D, Zhang B-P, Li J-F, Zhou M, Liu W-S, Liu J (2008) J Alloys Compd 455(1–2):259. doi:10.1016/j.jallcom.2007.01.015
Chen LD, Kawahara T, Tang XF, Goto T, Hirai T, Dyck JS, Chen W, Uher C (2001) J Appl Phys 90(4):1864. doi:10.1063/1.1388162
Tang X, Zhang Q, Chen L, Goto T, Hirai T (2005) J Appl Phys 97(9):093712. doi:10.1063/1.1888048
Sales BC, Mandrus D, Williams RK (1996) Science 272(5266):1325. doi:10.1126/science.272.5266.1325
Slack GA (1995) New materials and performance limits for thermoelectric cooling. In: Rowe DM (ed) CRC handbook of thermoelectrics. CRC Press LLC, Boca Raton, p 407
Nolas GS, Cohn JL, Slack GA (1998) Phys Rev B 58(1):164
Alboni PN, Ji X, He J, Gothard N, Tritt TM (2008) J Appl Phys 103(11):113707. doi:10.1063/1.2937904
J. L. Mi, Zhao XB, Zhu TJ, Tu JP (2008) Thermoelectric properties of Yb0.15Co4Sb12 based nanocomposites with CoSb3 nano-inclusion. J Phys D 41(20):205403
Xiong Z, Chen X, Zhao X, Bai S, Huang X, Chen L (2009) Solid State Sci 11(9):1612. doi:10.1016/j.solidstatesciences.2009.06.007
Zhao XY, Shi X, Chen LD, Zhang WQ, Bai SQ, Pei YZ, Li XY, Goto T (2006) Appl Phys Lett 89(9):092121. doi:10.1016/1.2345249
Li H, Tang XF, Zhang QJ, Uher C (2009) Appl Phys Lett 94(10):102114. doi:10.1063/1.3099804
Su X, Li H, Wang G, Chi H, Zhou X, Tang X, Zhang Q, Uher C (2011) Chem Mater 23(11):2948
Chen Z, Jeffrey S, Donald M, Xiaoyuan Z, Guoyu W, Ctirad U (2011) J Appl Phys 109(6):063722
Hsu KF, Loo S, Guo F, Chen W, Dyck JS, Uher C, Hogan T, Polychroniadis EK, Kanatzidis MG (2004) Science 303(5659):818. doi:10.1126/science.1092963
Quarez E, Hsu K-F, Pcionek R, Frangis N, Polychroniadis EK, Kanatzidis MG (2005) J Am Chem Soc 127(25):9177
Wang H, Li J-F, Nan C-W, Zhou M, Liu W, Zhang B-P, Kita T (2006) Appl Phys Lett 88(9):092104. doi:10.1063/1.2181197
Zhou M, Li J-F, Kita T (2008) J Am Chem Soc 130(13):4527
Kanatzidis MG (2009) Chem Mater 22(3):648
Sootsman JR, Kong H, Uher C, D’Angelo JJ, Wu C-I, Hogan TP, Caillat T, Kanatzidis MG (2008) Angew Chem Int Ed 47(45):8618
He JQ, Sootsman JR, Girard SN, Zheng JC, Wen JG, Zhu YM, Kanatzidis MG, Dravid VP (2010) J Am Chem Soc 132(25):8669. doi:10.1021/ja1010948
Androulakis J, Lin C-H, Kong H-J, Uher C, Wu C-I, Hogan T, Cook BA, Caillat T, Paraskevopoulos KM, Kanatzidis MG (2007) J Am Chem Soc 129(31):9780. doi:10.1021/ja071875h
Ikeda T, Haile SM, Ravi VA, Azizgolshani H, Gascoin F, Snyder GJ (2007) Acta Mater 55(4):1227
Johnsen S, He JQ, Androulakis J, Dravid VP, Todorov I, Chung DY, Kanatzidis MG (2011) J Am Chem Soc 133(10):3460. doi:10.1021/ja109138p
Biswas K, He JQ, Zhang QC, Wang GY, Uher C, Dravid VP, Kanatzidis MG (2011) Nat Chem 3(2):160. doi:10.1038/nchem.955
Androulakis J, Todorov I, He JQ, Chung DY, Dravid V, Kanatzidis M (2011) J Am Chem Soc 133(28):10920. doi:10.1021/ja203022c
Zhao LD, Lo SH, He JQ, Li H, Biswas K, Androulakis J, Wu CI, Hogan TP, Chung DY, Dravid VP, Kanatzidis MG (2011) J Am Chem Soc 133(50):20476. doi:10.1021/ja208658w
Biswas K, He J, Blum ID, Wu C-I, Hogan TP, Seidman DN, Dravid VP, Kanatzidis MG (2012) Nature 489(7416):414. doi:10.1038/nature11439
Uher C, Yang J, Hu S, Morelli DT, Meisner GP (1999) Phys Rev B 59(13):8615
Shen Q, Chen L, Goto T, Hirai T, Yang J, Meisner GP, Uher C (2001) Appl Phys Lett 79(25):4165
Yang J, Li H, Wu T, Zhang W, Chen L, Yang J (2008) Adv Funct Mater 18(19):2880
Xie WJ, He J, Zhu S, Su XL, Wang SY, Holgate T, Graff JW, Ponnambalam V, Poon SJ, Tang XF, Zhang QJ, Tritt TM (2010) Acta Mater 58(14):4705. doi:10.1016/j.actamat.2010.05.005
Poon SJ, Wu D, Zhu S, Xie WJ, Tritt TM, Thomas P, Venkatasubramanian R (2011) J Mater Res 26(22):2795. doi:10.1557/jmr.2011.329
Christensen M, Johnsen S, Iversen BB (2010) Dalton Trans 39(4):978. doi:10.1039/b916400f
Saramat A, Svensson G, Palmqvist AEC, Stiewe C, Mueller E, Platzek D, Williams SGK, Rowe DM, Bryan JD, Stucky GD (2006) J Appl Phys 99(2):023708. doi:10.1063/1.2163979
Toberer ES, May AF, Snyder GJ (2010) Chem Mater 22(3):624. doi:10.1021/cm901956r
Rogl P (2005) Formation of clathrates. In: ICT: 2005 24th international conference on thermoelectrics, Clemson, SC
Heijl R, Cederkrantz D, Nygren M, Palmqvist AEC (2012) J Appl Phys 112(4):044313
Zaitsev VK, Fedorov MI, Gurieva EA, Eremin IS, Konstantinov PP, Samunin AY, Vedernikov MV (2006) Phys Rev B 74(4):045207. doi:10.1103/PhysRevB.74.045207
Zhang Q, He J, Zhu TJ, Zhang SN, Zhao XB, Tritt TM (2008) Appl Phys Lett 93(10):102109. doi:10.1063/1.2981516
Cederkrantz D, Farahi N, Borup KA, Iversen BB, Nygren M, Palmqvist AEC (2012) J Appl Phys 111(2):023701. doi:10.1063/1.3675512
Wang XW, Lee H, Lan YC, Zhu GH, Joshi G, Wang DZ, Yang J, Muto AJ, Tang MY, Klatsky J, Song S, Dresselhaus MS, Chen G, Ren ZF (2008) Appl Phys Lett 93(19):193121. doi:10.1063/1.3027060
Joshi G, Lee H, Lan Y, Wang X, Zhu G, Wang D, Gould RW, Cuff DC, Tang MY, Dresselhaus MS, Chen G, Ren Z (2008) Nano Lett 8(12):4670
May AF, Fleurial J-P, Snyder GJ (2008) Phys Rev B 78(12):125205. doi:10.1103/PhysRevB.78.125205
Jeng M-S, Yang R, Song D, Chen G (2008) J Heat Transf 130(4):042410. doi:10.1115/1.2818765
Acknowledgements
The authors gratefully acknowledge the financial support from Mistra, the Swedish Foundation for Strategic Environmental Research, through the E4-Mistra program, and thank its members for fruitful discussions. AECP enjoys support from the Swedish Research Council for a Senior Researcher position.
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Ma, Y., Heijl, R. & Palmqvist, A.E.C. Composite thermoelectric materials with embedded nanoparticles. J Mater Sci 48, 2767–2778 (2013). https://doi.org/10.1007/s10853-012-6976-z
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DOI: https://doi.org/10.1007/s10853-012-6976-z