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Structure of multilayer ZrO2/SrTiO3

  • E-MRS MACAN
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Abstract

Multilayered oxide heteroepitaxial systems, including that of a 1-nm-thick Y2O3-stabilised ZrO2 (YSZ) sandwiched between layers of SrTiO3 (STO) [1], have been a subject of much interest lately due to their significantly enhanced ionic conductivities as compared to the bulk materials. We aim to provide the foundation for understanding this increase in conductivity by considering the atomic configurations at the interfaces of such systems, specifically a ZrO2/STO multilayer system. Possible stable lattice structures of pure ZrO2 in the system are explored using a genetic algorithm in which the interatomic interactions are modelled by simple pair potentials. The energies of several of the more stable of these structures are then evaluated more accurately within density functional theory (DFT). We find that the fluorite ZrO2 phase is unstable as a coherently strained epitaxial layer in the multilayer system. Instead, anatase-, columbite-, rutile-, and pyrite-like ZrO2 epitaxies are found to be more stable, with the anatase-like epitaxy being the most stable structure over a wide range of chemical potential of the components. We also find a high energy metastable structure resembling the tetragonal fluorite structure which is predicted by DFT to be stabilised by SrO-terminated STO but not by TiO2-terminated STO.

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Acknowledgements

We would like to thank David W. McComb for useful discussions. The calculations were performed on the Imperial College High Performance Computing Service facilities as well as HECToR, the UK’s national high-performance computing service, which is provided by UoE HPCx Ltd. at the University of Edinburgh, Cray Inc. and NAG Ltd., and funded by the Office of Science and Technology through EPSRC’s High End Computing Programme. This study is funded by the Agency for Science, Technology and Research (A*STAR), Singapore.

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  1. Department of Materials, Imperial College London, Exhibition Road, London, SW7 2AZ, UK

    Wei Li Cheah & Michael W. Finnis

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  1. Wei Li Cheah
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  2. Michael W. Finnis
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Correspondence to Wei Li Cheah.

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Cheah, W.L., Finnis, M.W. Structure of multilayer ZrO2/SrTiO3 . J Mater Sci 47, 1631–1640 (2012). https://doi.org/10.1007/s10853-011-5985-7

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