Abstract
Wetting behavior and interface interaction between Y2O3 and Cu–alloys were investigated at 1,423 K. Pure copper does not wet yttria substrate but the wettability is significantly improved by additions of Al and Ti. Different interface structures were observed in the Y2O3/(Cu–Al) and Y2O3/(Cu–Ti) systems. Relatively deep crater was detected at the interface in the first system, while Cu alloying by Ti led to formation of a flat interface with a thin reaction layer. The results of the wetting experiments and the interface features were well accounted of by thermodynamic analysis of the Y2O3/(Cu–Me) systems.
Similar content being viewed by others
References
Eustathopoulos N, Nicholas MG, Drevet B (1999) Wettability at high temperatures. Pergamon, pp 198–255
Nadich JUV, Zhuravljov VS, Frumina NI (1990) J Mat Sci 25:1895
Yeheskel O, Tevet O (1999) J Am Ceram Soc 82(1):136
Froumin N, Frage N, Polak M, Dariel MP (1997) Scripta Mater 37:1263
Zhang MX, Chang YA (1994) J Phase Equilibria 15(5):470
Kulikov IS (1975) Rasislenie metallov. ed. Metallurgiya, Moscow, pp 34
Fabrichnaya O, Seifert HJ, Weiland R, Ludwig T, Aldinger F, Navrotsky A (2001) Z Metallkd 92:9
Rao YK (1985) Stoichiometry and thermodynamics of metallurgical processes, 1st edn. Cambrige University Press
Smithells CJ (1962) Metals reference book vol 1, 3rd edn. Butterworths, London
Lide DR (ed) (1998) CRC handbook of chemistry and physics, 79th edn. CRC Press, Boca Raton, Florida, USA
Barzilai S, Aizenshtein M, Froumin N, Frage N J Mater Sci Eng (accepted)
Itagaki K, Qi G, Mey S, Spencer PJ (1990) Calphad 14(4):377
Ran Q, Lukas HL, Effenberg G, Petzow G (1989) J Less-Common Metals 146:213
Ansara I, Dinsdale AT, Rand MH (1998) Cost 507 – thermochemical database for light metal alloys, vol 2. European Communities, Belgium
Hilert M (1998) Phase equilibria, phase diagram and phase transformation – their thermodynamic basis, 1st edn. Cambridge University Press
Wagner C (1952) Thermodynamics of alloys. Addison-Wesley, Reading Mass
Itagaki K, Qi G, Mey S, Spencer PJ (1990) Calphad 14(4):377
SGTE, SSOL4 solution database version 4.74B 200
Acknowledgment
This work was supported by the Israeli Council of High Education, grant 138/05.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Barzilai, S., Aizenshtein, M., Froumin, N. et al. Y2O3/(Cu–Me) systems (Me=Al, Ti): interface reactions and wetting. J Mater Sci 41, 5108–5112 (2006). https://doi.org/10.1007/s10853-006-0435-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-006-0435-7