Skip to main content

Advertisement

Log in

Photoconductivity of polymer films of vanadium composites with copper and cobalt

  • Published:
Journal of Applied Spectroscopy Aims and scope

This is a study of the photoconductive properties of polymer composite films based on non-photoconducting polyvinylbutyral doped with different metallic complexes V/M (M = Cu, Co). The activation energy of the photocurrent is found to rise with an increasing external electric field. The possible influence of an external electric field on recombination and the separation of nonequilibrium charge pairs is considered as a possible explanation for the temperature dependence of the photoconductivity. A phenomenological model for the effect of an electric field on these processes is proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. Ohkoshi, H. Tokoro, T. Hozumi, Y. Zhang, K. Hashimoto, C. Mathoniere, I. Bord, G. Rombaut, M. Verelst, C. C. Moulin, and F. Villain, J. Am. Chem. Soc., 128, No. 1, 270–277 (2006).

    Article  Google Scholar 

  2. N. A. Davidenko, V. N. Nikitina, S. V. Dehtyarenko, O. V. Nesterova, and V. N. Kokozay, Phys. Solid State, 51, No. 2, 421–426 (2009).

    Article  ADS  Google Scholar 

  3. O. V. Vreshch, N. A. Davidenko, S. V. Dekhtyarenko, A. A. Ishchenko, V. N. Kokozei, A. V. Kozinets, V. A. Skryshevskii, and O. V. Tret’yak, KhVÉ, 43, 177–181 (2009).

    Google Scholar 

  4. L. Li, S.-Y. Niu, J. Jin, Q. Meng, Y.-X. Chi, Y.-H. Xing, and G.-N. Zhang, J. Solid State Chem., 184, 1279–1285 (2011).

    Article  ADS  Google Scholar 

  5. D. Gambino, Coord. Chem. Rev., 255, 2193–2230 (2011).

    Article  Google Scholar 

  6. J. A. L. Da Silva, J. J. R. Frausto da Silva, and A. J. L. Pombeiro, Coord. Chem. Rev., 255, 2232–2248 (2011).

    Article  Google Scholar 

  7. V. N. Kokozay, S. R. Petrusenko, O. A. Vinogradova, O. Yu. Vassilyeva, and O. V. Pryma, Method of Direct Synthesis of Heteronuclear Complexes, Ukraine Patent No. 36649 (2001).

  8. N.A. Davidenko, V. N. Nikitina, D. V. Shevchenko, V. N. Kokozei, S. L. Studzinskii, and S. V. Dekhtyarenko, Fiz. Tverd. Tela, 49, No. 12, 2151–2156 (2007).

    Google Scholar 

  9. M. Lampert and P. Mark, Current Injection in Solids, Academic Press, New York, London (1970).

    Google Scholar 

  10. T. Blythe and D. Bloor, Electrical Properties of Polymers, Cambridge University Press (2005).

  11. A. G. Zhdan, A. D. Ozheredov, M. I. Elinson, and M. A. Messerer, Pis’ma ZhETF, 8, 402–407 (1968).

    ADS  Google Scholar 

  12. A. M. Kreshchuk, S. V. Novikov, and I. V. Savel’ev, Fiz. Tekh. Poluprovodnikov, 30, No. 5, 934–941 (1996).

    Google Scholar 

  13. E. D. Denisov, Kinetics of Homogeneous Chemical Reactions [in Russian], Vysshaya Shkola, Moscow (1988).

    Google Scholar 

  14. I. A. Leenson and G. B. Sergeev, Usp. Khimii, 53, No. 5, 721–752 (1984).

    Google Scholar 

  15. I. A. Semiokhin, B. V. Strakhov, and A. I. Osipov, Chemical Reaction Kinetics [in Russian], Izd. Mosk. Univ., Moscow (1995).

  16. V. N. Chebotin, Physical Chemistry of Solids [in Russian], Khimiya, Moscow (1982).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. A. Davidenko.

Additional information

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 80, No. 2, pp. 252–256, March–April, 2013.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Davidenko, N.A., Kokozay, V.N., Pavliuk, M.V. et al. Photoconductivity of polymer films of vanadium composites with copper and cobalt. J Appl Spectrosc 80, 244–248 (2013). https://doi.org/10.1007/s10812-013-9753-0

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10812-013-9753-0

Keywords

Navigation