Abstract
Electrodeposition and dissolution of zinc in sulfuric acid were studied as the negative electrode reactions in acidic zinc-based redox flow batteries. The zinc deposition and dissolution is a quasi-reversible reaction with a zinc ion diffusion coefficient of 4.6 × 10−6 cm2 s−1 obtained. The increase of acid concentration facilitates an improvement in the kinetics of zinc electrodeposition–dissolution process. But too high acid concentration would result in a significant decrease in charge efficiency. The performance of the zinc electrode in a three-electrode system with magnetic stirring was also studied as a function of Zn(II) ion concentration, sulfuric acid concentration, current density, and the addition of additives in 1 M H2SO4 medium. The optimum electrolyte composition is suggested at high zinc(II) concentration (1.25 M) and moderate sulfuric acid concentration (1.0–1.5 M) at a current density range of 20–30 mA cm−2. Whether in acid-free solution or in sulfuric acid solution with or without additives, no dendrite formation is observed after zinc electrodeposition for 1 h at 20 mA cm−2. The energy efficiency is improved from 77 % in the absence of additives in 1 M H2SO4 medium to over 80 % upon the addition of indium oxide or SLS–Sb(III) combined additive as hydrogen suppressants.
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This work was financed by the National Basic Research Program (973 Program) of China (2010CB227204).
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Pan, J., Wen, Y., Cheng, J. et al. Zinc deposition and dissolution in sulfuric acid onto a graphite–resin composite electrode as the negative electrode reactions in acidic zinc-based redox flow batteries. J Appl Electrochem 43, 541–551 (2013). https://doi.org/10.1007/s10800-013-0538-1
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DOI: https://doi.org/10.1007/s10800-013-0538-1