Abstract
The last decade’s research on the performance of proton-exchange membrane direct ethanol fuel cells (PEM-DEFCs) and anion exchange membrane direct ethanol fuel cells (AEM-DEFCs) is included in the present review. Future research challenges are identified along with potential strategies to overcome them. Pt-containing or Pt-free PEM-DEFCs that use acid proton-exchange membranes (typically Nafion type) exhibit relatively low performance (i.e., the state-of-the-art peak power density is 110 mW cm−2 at 145 °C over 4 mg of total Pt loading), while Pt-containing or Pt-free AEM-DEFCs that use low-cost anion-exchange membrane have recently exhibited better performance values (i.e., the state-of-the-art peak power density is about 185 mW cm−2 at 80 °C over Au-modified Pd catalysts supported on carbon nanotubes. The required faster kinetics of the ethanol oxidation and especially for the oxygen reduction reaction seem to be satisfied from one side by the AEM-DEFCs and from the other by PEM-DEFCs only if working at intermediate temperature values (>150 °C). Moreover, new possibilities of using less expensive metal catalysts (as silver, nickel, and palladium) are opening mainly for AEM-DEFCs and the last years for PEM-DEFCs too. Finally, it is worth to be noticed that the best value ever reported (peak power density is 360 mW cm−2 at 60 °C) has been obtained in a very promising alkaline-acid direct ethanol fuel cell (AA-DEFC).
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References
Costamagna P, Srinivasan S (2001) Quantum jumps in the PEMFC science and technology from the 1960s to the year 2000: part II. Engineering, technology development and application aspects. J Power Sources 102(1–2):253–269
Bianchini C, Shen PK (2009) Palladium-based electro-catalysts for alcohol oxidation in half cells and in direct alcohol fuel cells. Chem Rev 109(9):4183–4206
Rabis A, Rodriguez P, Schmidt TJ (2012) Electrocatalysis for polymer electrolyte fuel cells: recent achievements and future challenges. ACS Catal 2(5):864–890
Brouzgou A, Song S, Tsiakaras P (2012) Low and non-platinum electrocatalysts for PEMFCs: current status, challenges and prospects. J Appl Catal B: Environ 127:371–388
Gottesfeld S (2008) Electrocatalysis of oxygen reduction in polymer electrolyte fuel cells: a brief history and a critical examination of present theory and diagnostics. Fuel cell catal. Wiley, New York, pp 1–30
Carrette L, Friedrich KA, Stimming U (2001) Fuel cells: fundamentals and applications. Fuel Cells 1(1):5–39
McLean GF, Niet T, Prince-Richard S, Djilali N (2002) An assessment of alkaline fuel cell technology. Int J Hydrogen Energy 27(5):507–526
Danks TN, Slade RCT, Varcoe JR (2003) Alkaline anion-exchange radiation-grafted membranes for possible electrochemical application in fuel cells. J Mater Chem 13(4):712–721
Varcoe JR, Slade RCT (2005) Prospects for alkaline anion-exchange membranes in low temperature fuel cells. Fuel Cells 5(2):187–200
Matsuoka K, Iriyama Y, Abe T, Matsuoka M, Ogumi Z (2005) Alkaline direct alcohol fuel cells using an anion exchange membrane. J Power Sources 150:27–31
Varcoe JR, Slade RCT, Lam How Yee E (2006) An alkaline polymer electrochemical interface: a breakthrough in application of alkaline anion-exchange membranes in fuel cells. Chem Commun 13:1428–1429
Zhu LD, Zhao TS, Xu JB, Liang ZX (2009) Preparation and characterization of carbon-supported sub-monolayer palladium decorated gold nanoparticles for the electro-oxidation of ethanol in alkaline media. J Power Sources 187(1):80–84
Yu EH, Scott K (2004) Development of direct methanol alkaline fuel cells using anion exchange membranes. J Power Sources 137(2):248–256
Zeng L, Zhao TS, Li YS (2012) Synthesis and characterization of crosslinked poly (vinylΒ alcohol)/layered double hydroxide composite polymer membranes for alkaline direct ethanol fuel cells. Int J Hydrogen Energy 37(23):18425–18432
Matsui K, Tobita E, Sugimoto K, Kondo K, Seita T, Akimoto A (1986) Novel anion exchange membranes having fluorocarbon backbone: preparation and stability. J Appl Polym Sci 32(3):4137–4143
Iwamoto T, Uetake M, Umeda A (1994) Degradation of strong base anion exchange resin. In: Hofman (ed) 68th Autumn annual meeting of the chemical society. Nagoya, Japan
Kruusenberg I, Matisen L, Shah Q, Kannan AM, Tammeveski K (2012) Non-platinum cathode catalysts for alkaline membrane fuel cells. Int J Hydrogen Energy 37(5):4406–4412
Shen SY, Zhao TS, Wu QX (2012) Product analysis of the ethanol oxidation reaction on palladium-based catalysts in an anion-exchange membrane fuel cell environment. Int J Hydrogen Energy 37(1):575–582
Mamlouk M, Scott K, Horsfall JA, Williams C (2011) The effect of electrode parameters on the performance of anion exchange polymer membrane fuel cells. Int J Hydrogen Energy 36(12):7191–7198
Mamlouk M, Horsfall JA, Williams C, Scott K (2012) Radiation grafted membranes for superior anion exchange polymer membrane fuel cells performance. Int J Hydrogen Energy 37(16):11912–11920
Zhao Y, Yu H, Yang D, Li J, Shao Z, Yi B (2013) High-performance alkaline fuel cells using crosslinked composite anion exchange membrane. J Power Sources 221:247–251
Lin B, Qiu L, Lu J, Yan F (2010) Cross-linked alkaline ionic liquid-based polymer electrolytes for alkaline fuel cell applications. Chem Mater 22(24):6718–6725
Bidault F, Brett DJL, Middleton PH, Brandon NP (2009) Review of gas diffusion cathodes for alkaline fuel cells. J Power Sources 187(1):39–48
Scott K, Taama WM, Argyropoulos P, Sundmacher K (1999) The impact of mass transport and methanol crossover on the direct methanol fuel cell. J Power Sources 83(1–2):204–216
Wasmus S, Küver A (1999) Methanol oxidation and direct methanol fuel cells: a selective review. J Electroanal Chem 461(1–2):14–31
Nam-Trung Nguyen, Siew Hwa C (2006) Micromachined polymer electrolyte membrane and direct methanol fuel cells: a review. J Micromech Microeng 16(4):R1
Schultz T, Krewer U, Vidaković T, Pfafferodt M, Christov M, Sundmacher K (2007) Systematic analysis of the direct methanol fuel cell. J Appl Electrochem 37(1):111–119
Zhou W, Zhou Z, Song S, Li W, Sun G, Tsiakaras P, Xin Q (2003) Pt based anode catalysts for direct ethanol fuel cells. Appl Catal B 46(2):273–285
Zhou WJ, Zhou B, Li WZ, Zhou ZH, Song SQ, Sun GQ, Xin Q, Douvartzides S, Goula M, Tsiakaras P (2004) Performance comparison of low-temperature direct alcohol fuel cells with different anode catalysts. J Power Sources 126(1–2):16–22
Song S, Zhou W, Liang Z, Cai R, Sun G, Xin Q, Stergiopoulos V, Tsiakaras P (2005) The effect of methanol and ethanol cross-over on the performance of PtRu/C-based anode DAFCs. Appl Catal B 55(1):65–72
Antolini E, Colmati F, Gonzalez ER (2007) Effect of Ru addition on the structural characteristics and the electrochemical activity for ethanol oxidation of carbon supported Pt–Sn alloy catalysts. Electrochem Commun 9(3):398–404
Andreadis GM, Podias AKM, Tsiakaras PE (2008) The effect of the parasitic current on the direct ethanol PEM fuel cell operation. J Power Sources 181(2):214–227
Andreadis GM, Podias AKM, Tsiakaras PE (2009) A model-based parametric analysis of a direct ethanol polymer electrolyte membrane fuel cell performance. J Power Sources 194(1):397–407
Li YS, Zhao TS, Liang ZX (2009) Performance of alkaline electrolyte-membrane-based direct ethanol fuel cells. J Power Sources 187(2):387–392
Maab H, Nunes SP (2010) Modified SPEEK membranes for direct ethanol fuel cell. J Power Sources 195(13):4036–4042
Jablonski A, Kulesza PJ, Lewera A (2011) Oxygen permeation through Nafion 117 membrane and its impact on efficiency of polymer membrane ethanol fuel cell. J Power Sources 196(10):4714–4718
Song S, He C, Liu J, Wang Y, Brouzgou A, Tsiakaras P (2012) Two-step sequence for synthesis of efficient PtSn@Rh/C catalyst for oxidizing ethanol and intermediate products. Appl Catal B 119–120:227–233
Meyer M, Melke J, Gerteisen D (2011) Modelling and simulation of a direct ethanol fuel cell considering multistep electrochemical reactions, transport processes and mixed potentials. Electrochim Acta 56(11):4299–4307
Zhiani M, Gasteiger HA, Piana M, Catanorchi S (2011) Comparative study between platinum supported on carbon and non-noble metal cathode catalyst in alkaline direct ethanol fuel cell (ADEFC). Int J Hydrogen Energy 36(8):5110–5116
Li YS, Zhao TS (2012) Understanding the performance degradation of anion-exchange membrane direct ethanol fuel cells. Int J Hydrogen Energy 37(5):4413–4421
Song SQ, Zhou WJ, Zhou ZH, Jiang LH, Sun GQ, Xin Q, Leontidis V, Kontou S, Tsiakaras P (2005) Direct ethanol PEM fuel cells: the case of platinum based anodes. Int J Hydrogen Energy 30(9):995–1001
De Souza RFB, Silva JCM, Simões FC, Calegaro ML, Neto AO, Santos MC (2012) New approaches for the ethanol oxidation reaction of Pt/C on carbon cloth using ATR–FTIR. Int J Electrochem Sci 7:5356–5366
Andreadis G, Tsiakaras P (2006) Ethanol crossover and direct ethanol PEM fuel cell performance modeling and experimental validation. Chem Eng Sci 61(22):7497–7508
Antolini E (2007) Catalysts for direct ethanol fuel cells. J Power Sources 170(1):1–12
Song S, Tsiakaras P (2006) Recent progress in direct ethanol proton exchange membrane fuel cells (DE-PEMFCs). Appl Catal B 63(3–4):187–193
Wang H, Jusys Z, Behm RJ (2004) Ethanol electrooxidation on a carbon-supported Pt catalyst: reaction kinetics and product yields. J Phys Chem B 108(50):19413–19424
Antolini E, Gonzalez ER (2010) A simple model to assess the contribution of alloyed and non-alloyed platinum and tin to the ethanol oxidation reaction on Pt–Sn/C catalysts: application to direct ethanol fuel cell performance. Electrochim Acta 55(22):6485–6490
Lamy C, Belgsir EM, Léger JM (2001) Electrocatalytic oxidation of aliphatic alcohols: application to the direct alcohol fuel cell (DAFC). J Appl Electrochem 31(7):799–809
Andreadis G, Stergiopoulos V, Song S, Tsiakaras P (2010) Direct ethanol fuel cells: the effect of the cell discharge current on the products distribution. Appl Catal B 100(1–2):157–164
Nakagawa N, Kaneda Y, Wagatsuma M, Tsujiguchi T (2012) Product distribution and the reaction kinetics at the anode of direct ethanol fuel cell with Pt/C, PtRu/C and PtRuRh/C. J Power Sources 199:103–109
James DD, Pickup PG (2010) Effects of crossover on product yields measured for direct ethanol fuel cells. Electrochim Acta 55(11):3824–3829
Wang Q, Sun GQ, Jiang LH, Xin Q, Sun SG, Jiang YX, Chen SP, Jusys Z, Behm RJ (2007) Adsorption and oxidation of ethanol on colloid-based Pt/C, PtRu/C and Pt3Sn/C catalysts: in situ FTIR spectroscopy and on-line DEMS studies. Phys Chem Chem Phys 9(21):2686–2696
Li M, Kowal A, Sasaki K, Marinkovic N, Su D, Korach E, Liu P, Adzic RR (2010) Ethanol oxidation on the ternary Pt–Rh–SnO2/C electrocatalysts with varied Pt:rh:sn ratios. Electrochim Acta 55(14):4331–4338
Bergamaski K, Gonzalez ER, Nart FC (2008) Ethanol oxidation on carbon supported platinum–rhodium bimetallic catalysts. Electrochim Acta 53(13):4396–4406
Kowal A, Li M, Shao M, Sasaki K, Vukmirovic MB, Zhang J, Marinkovic NS, Liu P, Frenkel AI, Adzic RR (2009) Ternary Pt/Rh/SnO2 electrocatalysts for oxidizing ethanol to CO2. Nat Mater 8(4):325–330
Tarasevich MR, Karichev ZR, Bogdanovskaya VA, Lubnin EN, Kapustin AV (2005) Kinetics of ethanol electrooxidation at RuNi catalysts. Electrochem Commun 7(2):141–146
Fang X, Wang L, Shen PK, Cui G, Bianchini C (2010) An in situ Fourier transform infrared spectroelectrochemical study on ethanol electrooxidation on Pd in alkaline solution. J Power Sources 195(5):1375–1378
Cui G, Song S, Shen PK, Kowal A, Bianchini C (2009) First-principles considerations on catalytic activity of Pd toward ethanol oxidation. J Phys Chem C 113(35):15639–15642
Lim D-H, Choi D-H, Lee W-D, Lee H-I (2009) A new synthesis of a highly dispersed and CO tolerant Pt–Sn/C electrocatalyst for low-temperature fuel cell; its electrocatalytic activity and long-term durability. Appl Catal B 89(3–4):484–493
Hsieh C-T, Liu Y-Y, Chen W-Y, Hsieh Y-H (2011) Electrochemical activity and durability of Pt–Sn alloys on carbon-based electrodes prepared by microwave-assisted synthesis. Int J Hydrogen Energy 36(24):15766–15774
Su BJ, Wang KW, Cheng TC, Tseng CJ (2012) Preparation of PtSn/C electrocatalysts with improved activity and durability toward oxygen reduction reaction by alcohol-reduction process. Mater Chem Phys 135(2–3):395–400. doi:10.1016/j.matchemphys.2012.04.065
Wan C-H, Chen C-L (2009) Mitigating ethanol crossover in DEFC: a composite anode with a thin layer of Pt50–Sn50 nanoparticles directly deposited into NafionΒ® membrane surface. Int J Hydrogen Energy 34(23):9515–9522
Li YS, Zhao TS, Yang WW (2010) Measurements of water uptake and transport properties in anion-exchange membranes. Int J Hydrogen Energy 35(11):5656–5665
Jablonski A, Lewera A (2012) Electrocatalytic oxidation of ethanol on Pt, Pt–Ru and Pt–Sn nanoparticles in polymer electrolyte membrane fuel cell: role of oxygen permeation. Appl Catal B 115–116:25–30
Antolini E, Gonzalez ER (2011) Effect of synthesis method and structural characteristics of Pt–Sn fuel cell catalysts on the electro-oxidation of CH3OH and CH3CH2OH in acid medium. Catal Today 160(1):28–38
Antolini E, Gonzalez ER (2010) Alkaline direct alcohol fuel cells. J Power Sources 195(11):3431–3450
Yu EH, Krewer U, Scott K (2010) Principles and materials aspects of direct alkaline alcohol fuel cells. Energies 3:1499–1528
Zhao TS, Li YS, Shen SY (2010) Anion-exchange membrane direct ethanol fuel cells: status and perspective. Front Energy Power Eng Chin 4(4):443–458
Arges CG, Parrondo J, Johnson G, Nadhan A, Ramani V (2012) Assessing the influence of different cation chemistries on ionic conductivity and alkaline stability of anion exchange membranes. J Mater Chem 22(9):3733–3744
Energy USDo. http://www1.eere.energy.gov/hydrogenandfuelcells/. Accessed 13 June 2012
U.S. Department of Energy EERE. Accessed 21 May 2012
InfoMine MaIT (1990–2012). http://www.infomine.com/
Mamlouk M, Wang X, Scott K, Horsfall JA, Williams C (2011) Characterization and application of anion exchange polymer membranes with non-platinum group metals for fuel cells. 225. doi:10.1177/2041296710394264
Gurau B, Smotkin ES (2002) Methanol crossover in direct methanol fuel cells: a link between power and energy density. J Power Sources 112(2):339–352
Mahapatra SS, Dutta A, Datta J (2010) Temperature effect on the electrode kinetics of ethanol oxidation on Pd modified Pt electrodes and the estimation of intermediates formed in alkali medium. Electrochim Acta 55(28):9097–9104
Wang Y, Li L, Hu L, Zhuang L, Lu J, Xu B (2003) A feasibility analysis for alkaline membrane direct methanol fuel cell: thermodynamic disadvantages versus kinetic advantages. Electrochem Commun 5(8):662–666
Aricò AS, Baglio V, Antonucci V (2009) Direct methanol fuel cells—history, status and perspectives. In: Electrocatalysis of direct methanol fuel cells. Wiley, New York, p 1–78
Li H, Sun G, Cao L, Jiang L, Xin Q (2007) Comparison of different promotion effect of PtRu/C and PtSn/C electrocatalysts for ethanol electro-oxidation. Electrochim Acta 52(24):6622–6629
Liu J, Ye J, Xu C, Jiang SP, Tong Y (2007) Kinetics of ethanol electrooxidation at Pd electrodeposited on Ti. Electrochem Commun 9(9):2334–2339
Vigier F, Coutanceau C, Hahn F, Belgsir EM, Lamy C (2004) On the mechanism of ethanol electro-oxidation on Pt and PtSn catalysts: electrochemical and in situ IR reflectance spectroscopy studies. J Electroanal Chem 563(1):81–89
Silva JCM, De Souza RFB, Parreira LS, Neto ET, Calegaro ML, Santos MC (2010) Ethanol oxidation reactions using SnO2@Pt/C as an electrocatalyst. Appl Catal B 99(1–2):265–271
Chang Y-W, Liu C-W, Wei Y-C, Wang K-W (2009) Promotion of PtRu/C anode catalysts for ethanol oxidation reaction by addition of Sn modifier. Electrochem Commun 11(11):2161–2164
Zhou W-P, Axnanda S, White MG, Adzic RR, Hrbek J (2011) Enhancement in Ethanol Electrooxidation by SnOx Nanoislands Grown on Pt(111): effect of metal oxide–metal interface sites. J Phys Chem C 115(33):16467–16473
Liu C-W, Chang Y-W, Wei Y-C, Wang K-W (2011) The effect of oxygen containing species on the catalytic activity of ethanol oxidation for PtRuSn/C catalysts. Electrochim Acta 56(5):2574–2581
Tremiliosi-Filho G, Gonzalez ER, Motheo AJ, Belgsir EM, Léger JM, Lamy C (1998) Electro-oxidation of ethanol on gold: analysis of the reaction products and mechanism. J Electroanal Chem 444(1):31–39
de Lima R, Varela H (2008) Catalytic oxidation of ethanol on gold electrode in alkaline media. Gold Bull 41(1):15–22
Liang ZX, Zhao TS, Xu JB, Zhu LD (2009) Mechanism study of the ethanol oxidation reaction on palladium in alkaline media. Electrochim Acta 54(8):2203–2208
Nguyen ST, Law HM, Nguyen HT, Kristian N, Wang S, Chan SH, Wang X (2009) Enhancement effect of Ag for Pd/C towards the ethanol electro-oxidation in alkaline media. Appl Catal B 91(1–2):507–515
Fujiwara N, Siroma Z, Yamazaki S-i, Ioroi T, Senoh H, Yasuda K (2008) Direct ethanol fuel cells using an anion exchange membrane. J Power Sources 185(2):621–626
Bianchini C, Bambagioni V, Filippi J, Marchionni A, Vizza F, Bert P, Tampucci A (2009) Selective oxidation of ethanol to acetic acid in highly efficient polymer electrolyte membrane-direct ethanol fuel cells. Electrochem Commun 11(5):1077–1080
Hu F, Chen C, Wang Z, Wei G, Shen PK (2006) Mechanistic study of ethanol oxidation on Pd–NiO/C electrocatalyst. Electrochim Acta 52(3):1087–1091
Damjanovic A, Genshaw MA, Bockris JOM (1967) The mechanism of oxygen reduction at platinum in alkaline solutions with special reference to H2O2. 114. doi:10.1149/1.2426425
Damjanovic A, Sepa DB, Vojnovic MV (1979) New evidence supports the proposed mechanism for O2 reduction at oxide free platinum electrodes. Electrochim Acta 24(8):887–889
Morozan A, Jousselme B, Palacin S (2011) Low-platinum and platinum-free catalysts for the oxygen reduction reaction at fuel cell cathodes. Energy Environ Sci 4(4):1238–1254
Simões F, Olivi P (2010) Oxygen Reduction Reaction on Pt–NiOx/C, Pt–CoOx/C and PtSnO2 electrodes in the presence of ethanol. Electrocatalysis 1(2):163–168
Morales-Acosta D, Lopez de la Fuente D, Arriaga LG, Vargas Guitierrez G, Rodriguez Varela FJ (2011) Electrochemical investigation of Pt–Co/MWCNT as an alcohol-tolerant ORR catalyst for direct oxidation fuel cells. Int J Electrochem Sci 6:1835–1854
Rodriguez Varela FJ, Gaona Coronado AA, Loyola JC, Jiang Q-Z, Bartolo Perez P (2011) Pt–CeOx/MWCNT electrocatalysts as ethanol-tolerant ORR catalysts for direct oxidation fuel cells. J New Mater Electrochem Syst 14(2):75–80
Rodriguez Varela FJ, Gonzalez Ramirez SE, Klapco RD (2009) Evaluation of the performance of Ru/C electrocatalysts for the ORR in the absence and presence of C2H5OH: application in direct fuel cells. J New Mat Electr Sys 12(1):9–15
Rao CV, Viswanathan B (2010) Carbon supported Pd–Co–Mo alloy as an alternative to Pt for oxygen reduction in direct ethanol fuel cells. Electrochim Acta 55(8):3002–3007
Savadogo O, Rodriguez Varela FJ (2009) Palladium-alloy catalysts as ethanol-tolerant cathodes for direct alcohol fuel cell applications. J New Mater Electrochem Syst 11(2):69–74
Nekooi P, Akbari M, Amini MK (2010) CoSe nanoparticles prepared by the microwave-assisted polyol method as an alcohol and formic acid tolerant oxygen reduction catalyst. Int J Hydrogen Energy 35(12):6392–6398
Song S, Wang Y, Tsiakaras P, Shen PK (2008) Direct alcohol fuel cells: a novel non-platinum and alcohol inert ORR electrocatalyst. Appl Catal B 78(3–4):381–387
Shen S, Zhao TS, Xu J, Li Y (2011) High performance of a carbon supported ternary PdIrNi catalyst for ethanol electro-oxidation in anion-exchange membrane direct ethanol fuel cells. Energy Environ Sci 4(4):1428–1433
Xu JB, Zhao TS, Shen SY, Li YS (2010) Stabilization of the palladium electrocatalyst with alloyed gold for ethanol oxidation. Int J Hydrogen Energy 35(13):6490–6500
Shen SY, Zhao TS, Xu JB, Li YS (2010) Synthesis of PdNi catalysts for the oxidation of ethanol in alkaline direct ethanol fuel cells. J Power Sources 195(4):1001–1006
Bambagioni V, Bianchini C, Marchionni A, Filippi J, Vizza F, Teddy J, Serp P, Zhiani M (2009) Pd and Pt–Ru anode electrocatalysts supported on multi-walled carbon nanotubes and their use in passive and active direct alcohol fuel cells with an anion-exchange membrane (alcohol = methanol, ethanol, glycerol). J Power Sources 190(2):241–251
Xu JB, Zhao TS, Li YS, Yang WW (2010) Synthesis and characterization of the Au-modified Pd cathode catalyst for alkaline direct ethanol fuel cells. Int J Hydrogen Energy 35(18):9693–9700
Stamenković V, Schmidt TJ, Ross PN, Marković NM (2003) Surface segregation effects in electrocatalysis: kinetics of oxygen reduction reaction on polycrystalline Pt3Ni alloy surfaces. J Electroanal Chem 554–555:191–199
Guo J, Hsu A, Chu D, Chen R (2010) Improving oxygen reduction reaction activities on carbon-supported Ag nanoparticles in alkaline solutions. J Phys Chem C 114(10):4324–4330
Lima FHB, Calegaro ML, Ticianelli EA (2006) Investigations of the catalytic properties of manganese oxides for the oxygen reduction reaction in alkaline media. J Electroanal Chem 590(2):152–160
Xie X-Y, Ma Z-F, Ma X-X, Ren Q, Schmidt VM, Huang L (2007) Preparation and electrochemical characteristics of MnOx–CoTMPP/BP composite catalyst for oxygen reduction reaction in alkaline solution. 154. doi:10.1149/1.2739906
Roche I, Chaînet E, Chatenet M, Vondrák J (2008) Durability of carbon-supported manganese oxide nanoparticles for the oxygen reduction reaction (ORR) in alkaline medium. J Appl Electrochem 38(9):1195–1201
Mao L, Sotomura T, Nakatsu K, Koshiba N, Zhang D, Ohsaka T (2002) Electrochemical characterization of catalytic activities of manganese oxides to oxygen reduction in alkaline aqueous solution. 149. doi:10.1149/1.1461378
Lima FHB, de Castro JFR, Ticianelli EA (2006) Silver-cobalt bimetallic particles for oxygen reduction in alkaline media. J Power Sources 161(2):806–812
Duong HT, Rigsby MA, Zhou W-P, Wieckowski A (2007) Oxygen reduction catalysis of the Pt3Co alloy in alkaline and acidic media studied by X-ray photoelectron spectroscopy and electrochemical methods. J Phys Chem C 111(36):13460–13465
Sugawara M, Ohno M, Matsuki K (1997) Oxygen reduction catalysis of Mn–Co spinel oxides on a graphite electrode in alkaline solution. J Mater Chem 7(5):833–836
Cheng F, Su Y, Liang J, Tao Z, Chen J (2009) MnO2-based nanostructures as catalysts for electrochemical oxygen reduction in alkaline media. Chem Mater 22(3):898–905
Roche I, Chaînet E, Chatenet M, Vondrák J (2006) Carbon-supported manganese oxide nanoparticles as electrocatalysts for the oxygen reduction reaction (ORR) in alkaline medium: physical characterizations and ORR mechanism. J Phys Chem C 111(3):1434–1443
Li B, Prakash J (2009) Oxygen reduction reaction on carbon supported Palladium–Nickel alloys in alkaline media. Electrochem Commun 11(6):1162–1165
Li H, Liu H, Jong Z, Qu W, Geng D, Sun X, Wang H (2011) Nitrogen-doped carbon nanotubes with high activity for oxygen reduction in alkaline media. Int J Hydrogen Energy 36(3):2258–2265
Qu L, Liu Y, Baek J-B, Dai L (2010) Nitrogen-doped graphene as efficient metal-free electrocatalyst for oxygen reduction in fuel cells. ACS Nano 4(3):1321–1326
Oliveira MC, Rego R, Fernandes LS, Tavares PB (2011) Evaluation of the catalytic activity of Pd–Ag alloys on ethanol oxidation and oxygen reduction reactions in alkaline medium. J Power Sources 196(15):6092–6098
Gasteiger HA, Kocha SS, Sompalli B, Wagner FT (2005) Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs. Appl Catal B 56(1–2):9–35
Zhang J, Mo Y, Vukmirovic MB, Klie R, Sasaki K, Adzic RR (2004) Platinum monolayer electrocatalysts for O2 Reduction: pt monolayer on Pd(111) and on carbon-supported Pd nanoparticles. J Phys Chem B 108(30):10955–10964
Aricò AS, Cretì P, Antonucci PL, Antonucci V (1998) Comparison of ethanol and methanol oxidation in a liquid: feed solid polymer electrolyte fuel cell at high temperature. 1. doi:10.1149/1.1390638
Wang J, Wasmus S, Savinell RF (1995) Evaluation of ethanol, 1-propanol, and 2-propanol in a direct oxidation polymer-electrolyte fuel cell: a real-time mass spectrometry study. 142. doi:10.1149/1.2048487
Lobato J, Cañizares P, Rodrigo MA, Linares JJ (2009) Testing a vapour-fed PBI-based direct ethanol fuel cell. Fuel Cells 9(5):597–604
Wang Q, Sun GQ, Cao L, Jiang LH, Wang GX, Wang SL, Yang SH, Xin Q (2008) High performance direct ethanol fuel cell with double-layered anode catalyst layer. J Power Sources 177(1):142–147
Jiang L, Sun G, Sun S, Liu J, Tang S, Li H, Zhou B, Xin Q (2005) Structure and chemical composition of supported Pt–Sn electrocatalysts for ethanol oxidation. Electrochim Acta 50(27):5384–5389
An L, Zhao TS (2011) Performance of an alkaline-acid direct ethanol fuel cell. Int J Hydrogen Energy 36(16):9994–9999
Fatih K, Neburchilov V, Alzate V, Neagu R, Wang H (2010) Synthesis and characterization of quaternary PtRuIrSn/C electrocatalysts for direct ethanol fuel cells. J Power Sources 195(21):7168–7175
Verma A, Basu S (2007) Direct alkaline fuel cell for multiple liquid fuels: anode electrode studies. J Power Sources 174(1):180–185
Zhu M, Sun G, Li H, Cao L, Xin Q (2008) Effect of the Sn(II)/Sn(IV) redox couple on the activity of PtSn/C for ethanol electro-oxidation. Chin J Catal 29(8):765–770
Purgato FLS, Pronier S, Olivi P, de Andrade AR, Léger JM, Tremiliosi-Filho G, Kokoh KB (2012) Direct ethanol fuel cell: electrochemical performance at 90 °C on Pt and PtSn/C electrocatalysts. J Power Sources 198:95–99
Simões FC, dos Anjos DM, Vigier F, Léger JM, Hahn F, Coutanceau C, Gonzalez ER, Tremiliosi-Filho G, de Andrade AR, Olivi P, Kokoh KB (2007) Electroactivity of tin modified platinum electrodes for ethanol electrooxidation. J Power Sources 167(1):1–10
Tsiakaras PE (2007) PtM/C (M = Sn, Ru, Pd, W) based anode direct ethanol–PEMFCs: structural characteristics and cell performance. J Power Sources 171(1):107–112
Tayal J, Rawat B, Basu S (2011) Bi-metallic and tri-metallic Pt–Sn/C, Pt–Ir/C, Pt–Ir–Sn/C catalysts for electro-oxidation of ethanol in direct ethanol fuel cell. Int J Hydrogen Energy 36(22):14884–14897
Perez J, Paganin VA, Antolini E (2011) Particle size effect for ethanol electro-oxidation on Pt/C catalysts in half-cell and in a single direct ethanol fuel cell. J Electroanal Chem 654(1–2):108–115
Liu Z, Ling XY, Su X, Lee JY, Gan LM (2005) Preparation and characterization of Pt/C and PtRu/C electrocatalysts for direct ethanol fuel cells. J Power Sources 149:1–7
Xue X, Ge J, Tian T, Liu C, Xing W, Lu T (2007) Enhancement of the electrooxidation of ethanol on Pt–Sn–P/C catalysts prepared by chemical deposition process. J Power Sources 172(2):560–569
Zhu M, Sun G, Xin Q (2009) Effect of alloying degree in PtSn catalyst on the catalytic behavior for ethanol electro-oxidation. Electrochim Acta 54(5):1511–1518
De Souza RFB, Parreira LS, Rascio DC, Silva JCM, Teixeira-Neto E, Calegaro ML, Spinace EV, Neto AO, Santos MC (2010) Study of ethanol electro-oxidation in acid environment on Pt3Sn/C anode catalysts prepared by a modified polymeric precursor method under controlled synthesis conditions. J Power Sources 195(6):1589–1593
Neto AO, Farias LA, Dias RR, Brandalise M, Linardi M, Spinacé EV (2008) Enhanced electro-oxidation of ethanol using PtSn/CeO2/C electrocatalyst prepared by an alcohol-reduction process. Electrochem Commun 10(9):1315–1317
Silva DF, Geraldes AN, Neto AO, Pino ES, Linardi M, Spinacé EV, Macedo WAA, Ardisson JD (2010) Preparation of PtSnO2/C electrocatalysts using electron beam irradiation. Mater Sci Eng B 175(3):261–265
De Souza RFB, Parreira LS, Silva JCM, Simões FC, Calegaro ML, Giz MJ, Camara GA, Neto AO, Santos MC (2011) PtSnCe/C electrocatalysts for ethanol oxidation: dEFC and FTIR ‘‘in-situ’’ studies. Int J Hydrogen Energy 36(18):11519–11527
Lee E, Murthy A, Manthiram A (2011) Effect of Mo addition on the electrocatalytic activity of Pt–Sn–Mo/C for direct ethanol fuel cells. Electrochim Acta 56(3):1611–1618
Ribeiro J, dos Anjos DM, Kokoh KB, Coutanceau C, Léger JM, Olivi P, de Andrade AR, Tremiliosi-Filho G (2007) Carbon-supported ternary PtSnIr catalysts for direct ethanol fuel cell. Electrochim Acta 52(24):6997–7006
Zignani SC, Baglio V, Linares JJ, Monforte G, Gonzalez ER, Aricò AS (2012) Performance and selectivity of PtxSn/C electro-catalysts for ethanol oxidation prepared by reduction with different formic acid concentrations. Electrochim Acta 70:255–265
Ribadeneira E, Hoyos BA (2008) Evaluation of Pt–Ru–Ni and Pt–Sn–Ni catalysts as anodes in direct ethanol fuel cells. J Power Sources 180(1):238–242
Lycke DR, Gyenge EdL (2007) Electrochemically assisted organosol method for Pt–Sn nanoparticle synthesis and in situ deposition on graphite felt support: extended reaction zone anodes for direct ethanol fuel cells. Electrochim Acta 52(13):4287–4298
Tayal J, Rawat B, Basu S (2012) Effect of addition of rhenium to Pt-based anode catalysts in electro-oxidation of ethanol in direct ethanol PEM fuel cell. Int J Hydrogen Energy 37(5):4597–4605
Datta J, Dutta A, Biswas M (2012) Enhancement of functional properties of PtPd nano catalyst in metal-polymer composite matrix: application in direct ethanol fuel cell. Electrochem Commun 20:56–59
Bartrom AM, Haan JL (2012) The direct formate fuel cell with an alkaline anion exchange membrane. J Power Sources 214:68–74
An L, Zhao TS, Xu JB (2011) A bi-functional cathode structure for alkaline-acid direct ethanol fuel cells. Int J Hydrogen Energy 36(20):13089–13095
An L, Zhao TS, Chen R, Wu QX (2011) A novel direct ethanol fuel cell with high power density. J Power Sources 196(15):6219–6222
Hao L, Deli K, Hui W, Rongfang W (2011) Carbon-supported Pt–RuCo nanoparticles with low-noble-metal content and superior catalysis for ethanol oxidization. Int J Electrochem Soc 6:1058–1065
Yang X, Zheng J, Zhen M, Meng X, Jiang F, Wang T, Shu C, Jiang L, Wang C (2012) A linear molecule functionalized multi-walled carbon nanotubes with well dispersed PtRu nanoparticles for ethanol electro-oxidation. Appl Catal B Environ 121–122:57–64
Zhang H, Hu C, He X, Hong L, Du G, Zhang Y (2011) Pt support of multidimensional active sites and radial channels formed by SnO2 flower-like crystals for methanol and ethanol oxidation. J Power Sources 196(10):4499–4505
Xiao P, Guo X, Guo D-J, Song H-Q, Sun J, Lv Z, Liu Y, Qiu X-P, Zhu W-T, Chen L-Q, Stimming U (2011) Study on the co-catalytic effect of titanium dioxide and titanate nanomaterials on platinum-based catalysts in direct alcohol fuel cells. Electrochim Acta 58:541–550
Sieben JM, Duarte MME (2011) Nanostructured Pt and Pt–Sn catalysts supported on oxidized carbon nanotubes for ethanol and ethylene glycol electro-oxidation. Int J Hydrogen Energy 36(5):3313–3321
Ma J, Sun H, Su F, Chen Y, Tang Y, Lu T, Zheng J (2011) Ethanol electrooxidation on carbon-supported Pt nanoparticles catalyst prepared using complexing self-reduction method. Int J Hydrogen Energy 36(12):7265–7274
Liu B, Chia Z-W, Lee Z-Y, Cheng C-H, Lee J-Y, Liu Z-L (2012) The importance of water in the polyol synthesis of carbon supported platinum-tin oxide catalysts for ethanol electrooxidation. J Power Sources 206:97–102
Du W, Su D, Wang Q, Frenkel AI, Teng X (2011) Promotional effects of bismuth on the formation of platinum-bismuth nanowires network and the electrocatalytic activity toward ethanol oxidation. Cryst Growth Des 11(2):594–599
Tusi MM, Polanco NSO, Da Silva SG, Spinacé EV, Neto AO (2011) The high activity of PtBi/C electrocatalysts for ethanol electro-oxidation in alkaline medium. Electrochem Commun 13(2):143–146
Wang X, Hu C, Xiong Y, Liu H, Du G, He X (2011) Carbon-nanosphere-supported Pt nanoparticles for methanol and ethanol electro-oxidation in alkaline media. J Power Sources 196(4):1904–1908
Dutta A, Mahapatra SS, Datta J (2011) High performance PtPdAu nano-catalyst for ethanol oxidation in alkaline media for fuel cell applications. Int J Hydrogen Energy 36(22):14898–14906
Shen SY, Zhao TS, Xu JB (2010) Carbon supported PtRh catalysts for ethanol oxidation in alkaline direct ethanol fuel cell. Int J Hydrogen Energy 35(23):12911–12917
Xu C, Shen Pk, Liu Y (2007) Ethanol electrooxidation on Pt/C and Pd/C catalysts promoted with oxide. J Power Sources 164(2):527–531
Xu C, Su Y, Tan L, Liu Z, Zhang J, Chen S, Jiang SP (2009) Electrodeposited PtCo and PtMn electrocatalysts for methanol and ethanol electrooxidation of direct alcohol fuel cells. Electrochim Acta 54(26):6322–6326
Xu C, Cheng L, Shen P, Liu Y (2007) Methanol and ethanol electrooxidation on Pt and Pd supported on carbon microspheres in alkaline media. Electrochem Commun 9(5):997–1001
Tamašauskaitė T, Balčiūnaitė A, Vaiciukevičienė A, Selskis A, Pakštas V (2012) Investigation of nanostructured platinum–nickel supported on the titanium surface as electrocatalysts for alkaline fuel cells. J Power Sources 208:242–247
He X, Hu C (2011) Building three-dimensional Pt catalysts on TiO2 nanorod arrays for effective ethanol electrooxidation. J Power Sources 196(6):3119–3123
Chen X-m, Lin Z-j, Jia T-t, Cai Z-m, Huang X-l, Jiang Y-q, Chen X, Chen G-n (2009) A facile synthesis of palladium nanoparticles supported on functional carbon nanotubes and its novel catalysis for ethanol electrooxidation. Anal Chim Acta 650(1):54–58
Cao L, Sun G, Li H, Xin Q (2007) Carbon-supported IrSn catalysts for a direct ethanol fuel cell. Electrochem Commun 9(10):2541–2546
Pandey RK, Lakshminarayanan V (2010) Enhanced electrocatalytic activity of Pd-dispersed 3,4-polyethylenedioxythiophene film in hydrogen evolution and ethanol electro-oxidation reactions. J Phys Chem C 114(18):8507–8514
Nie M, Tang H, Wei Z, Jiang SP, Shen PK (2007) Highly efficient AuPd–WC/C electrocatalyst for ethanol oxidation. Electrochem Commun 9(9):2375–2379
Miao F, Tao B (2011) Methanol and ethanol electrooxidation at 3D ordered silicon microchannel plates electrode modified with nickel-palladium nanoparticles in alkaline. Electrochim Acta 56(19):6709–6714
Wang X, Wang W, Qi Z, Zhao C, Ji H, Zhang Z (2010) Fabrication, microstructure and electrocatalytic property of novel nanoporous palladium composites. J Alloy Compd 508(2):463–470
Dai L, Jiang L-P, Abdel-Halim ES, Zhu J-J (2011) The fabrication of palladium hollow sphere array and application as highly active electrocatalysts for the direct oxidation of ethanol. Electrochem Commun 13(12):1525–1528
Maiyalagan T, Scott K (2010) Performance of carbon nanofiber supported Pd–Ni catalysts for electro-oxidation of ethanol in alkaline medium. J Power Sources 195(16):5246–5251
Hu FP, Shen PK (2007) Ethanol oxidation on hexagonal tungsten carbide single nanocrystal-supported Pd electrocatalyst. J Power Sources 173(2):877–881
Xu C, Tian Z, Shen P, Jiang SP (2008) Oxide (CeO2, NiO, Co3O4 and Mn3O4)-promoted Pd/C electrocatalysts for alcohol electrooxidation in alkaline media. Electrochim Acta 53(5):2610–2618
Qi Z, Geng H, Wang X, Zhao C, Ji H, Zhang C, Xu J, Zhang Z (2011) Novel nanocrystalline PdNi alloy catalyst for methanol and ethanol electro-oxidation in alkaline media. J Power Sources 196(14):5823–5828
Shen SY, Zhao TS, Xu JB (2010) Carbon-supported bimetallic PdIr catalysts for ethanol oxidation in alkaline media. Electrochim Acta 55(28):9179–9184
Hu F, Cui X, Chen W (2010) Ultralong-CNTA-supported Pd-based anodes for ethanol oxidation. J Phys Chem C 114(47):20284–20289
Wang H, Xu C, Cheng F, Jiang S (2007) Pd nanowire arrays as electrocatalysts for ethanol electrooxidation. Electrochem Commun 9(5):1212–1216
Pandey RK, Lakshminarayanan V (2009) Electro-oxidation of formic acid, methanol, and ethanol on electrodeposited Pd-polyaniline nanofiber films in acidic and alkaline medium. J Phys Chem C 113(52):21596–21603
Shen PK, Xu C (2006) Alcohol oxidation on nanocrystalline oxide Pd/C promoted electrocatalysts. Electrochem Commun 8(1):184–188
Ramulifho T, Ozoemena KI, Modibedi RM, Jafta CJ, Mathe MK (2012) Fast microwave-assisted solvothermal synthesis of metal nanoparticles (Pd, Ni, Sn) supported on sulfonated MWCNTs: pd-based bimetallic catalysts for ethanol oxidation in alkaline medium. Electrochim Acta 59:310–320
Zheng HT, Li Y, Chen S, Shen PK (2006) Effect of support on the activity of Pd electrocatalyst for ethanol oxidation. J Power Sources 163(1):371–375
Zhang Z, Xin L, Sun K, Li W (2011) Pd–Ni electrocatalysts for efficient ethanol oxidation reaction in alkaline electrolyte. Int J Hydrogen Energy 36(20):12686–12697
Xu C, Hu Y, Rong J, Jiang SP, Liu Y (2007) Ni hollow spheres as catalysts for methanol and ethanol electrooxidation. Electrochem Commun 9(8):2009–2012
Liang YQ, Cui ZD, Zhu SL, Liu Y, Yang XJ (2011) Silver nanoparticles supported on TiO2 nanotubes as active catalysts for ethanol oxidation. J Catal 278(2):276–287
Nguyen ST, Yang Y, Wang X (2012) Ethanol electro-oxidation activity of Nb-doped-TiO2 supported PdAg catalysts in alkaline media. Appl Catal B 113–114:261–270
Hu G, Nitze F, Barzegar HR, Sharifi T, Miko Ε, ajczuk A, Tai C-W, Borodzinski A, Wågberg T (2012) Palladium nanocrystals supported on helical carbon nanofibers for highly efficient electro-oxidation of formic acid, methanol and ethanol in alkaline electrolytes. J Power Sources 209:236–242
Li G, Jiang L, Jiang Q, Wang S, Sun G (2011) Preparation and characterization of PdxAgy/C electrocatalysts for ethanol electrooxidation reaction in alkaline media. Electrochim Acta 56(22):7703–7711
Acknowledgments
A. Brouzgou is grateful to the Research Funding Program: Heracleitus II which is co-financed by the European Union (European social fund—ESF) and Greek national funds through the operational program “Education and Lifelong Learning” of the National Strategic Reference Framework (NSRF)—Investing in knowledge society through the European social fund. The present research is also partially supported by the “Bilateral R&D Co-operation between Greece-China 2012–2014”, which is co-financed by the European Union and the Greek Ministry of Development-GSRT.
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A. Brouzgou and A. Podias contributed equally to this study.
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Brouzgou, A., Podias, A. & Tsiakaras, P. PEMFCs and AEMFCs directly fed with ethanol: a current status comparative review. J Appl Electrochem 43, 119–136 (2013). https://doi.org/10.1007/s10800-012-0513-2
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DOI: https://doi.org/10.1007/s10800-012-0513-2