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Synthesis and spectroscopic investigation of iron(III) complexes of N′-(thioaroyl)pyridine-2-carbohydrazides

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Abstract

A new series of iron(III) complexes [Fe(L1)(HL1)], [Fe(L1)Cl]; [H2L1 = N′-(2-methoxythiobenzoyl)pyridine-2-carbohydrazide], [Fe(L2)(acac)], [Fe(HL2)2Cl]; [H2L2 = N′-(4-methoxythiobenzoyl)pyridine-2-carbohydrazide] and [Fe(L3) (acac)]; [H2L3 = N′-(2-hydroxythiobenzoyl)pyridine-2-carbohydrazide] were prepared by stirring/refluxing/mixing the respective ligand with FeCl3/Fe(acac)3 in chloroform/methanol. All the compounds were characterized by elemental analyses, magnetic susceptibility, IR, UV and Mössbauer spectral data. The complexes posses high/ low spin state and have tetrahedral/octahedral geometry.

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References

  1. Singh, N.K., Shrivastva, A., Tripathi, P., George, T., Dimmock, J.R., Sharma, R.K.: Copper(II) and manganese(III) complexes of N′-[(2-hydroxy phenyl) carbonothioyl] pyridine-2-carbohydrazide: novel therapeutic agents for cancer. Biochimie 88(9), 1209–1216 (2006)

    Article  Google Scholar 

  2. Singh, N.K., Kushwaha, S.K., Thomas, M.J.K.: Synthesis, characterization and electrical conductivities of the complexes of oxovanadium(IV), iron(III), copper(II), zinc(II) and cadmium(II) with N-isonicotinoyl-N′-p-hydroxythiobenzhydrazine. Indian J. Chem. 43A(7), 1454–1458 (2004)

    Google Scholar 

  3. Ali, M.A., Livingstone, S.E., Philips, D.J.: Metal chelates of dithiocarbazic acid and its derivatives. III. Complexes of the tridentate Schiff base α-N-methyl-S-methyl-β-N-(2-pyridyl)methylendithiocarbazate with some 3d metal ions. Inorg. Chim. Acta. 6, 11–16 (1972)

    Article  Google Scholar 

  4. Ali, M.A., Livingstone, S.E., Philips, D.J.: Metal chelates of dithiocabazic acid and its derivatives. IV. Complexes of the tridentate Schiff base N-methyl-S-methyl-β-N-(6-methylpyrid-2-yl)methylendithiocarbazate. Inorg. Chim. Acta. 6, 39–44 (1972)

    Article  Google Scholar 

  5. Ali, M.A., Livingstone, S.E., Philips, D.J.: Metal chelates of dithiocarbazic acid and its derivatives. V. Complexes of the NNS ligand 2-(2,3-diaza-4-methylthio-5-thiahexa-1,3-dienyl) pyridine with 3d metal ions. Inorg. Chim. Acta 6, 552–558 (1972)

    Article  Google Scholar 

  6. Livingstone, S.E., Nolan, J.D.: Complexes of manganese(II), iron(II), cobalt(II), and nickel(II) with the new αα α-tri-imine, 2,6-(dibenzothiazol-2-yl)pyridine. J. Chem. Soc., Dalton Trans. 2, 218–223 (1972)

    Article  Google Scholar 

  7. Singh, N.K., Shrivastva, A., Singh, S.M.: Synthesis, characterization and antitumor studies of Mn(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) complexes of N-salicyloyl-N′-o-hydroxythiobenzhydrazide. Bioorg. Med. Chem. 10(4), 887–895 (2002)

    Article  Google Scholar 

  8. Singh, N.K., Srivastava, A.K., Tripathi, P., Shrivastva, A., Sharma, R.K.: Bioactivity of novel transition metal complexes of N′-[(4-methoxy)thiobenzoyl]benzoic acid hydrazide. Eur. J. Med. Chem. 43, 577–583 (2008)

    Article  Google Scholar 

  9. King, M.J., Sharma, R.K.: N-myristoyl transferase assay using phosphocellulose paper binding. Anal. Biochem. 199(2), 149–153 (1991)

    Article  Google Scholar 

  10. Bost, R.W., Shealy, O.L.: β-Dimethylaminoethyl esters of organic dithio acids. II. Esters of aromatic dithio acids. J. Am. Chem. Soc. 73(1), 25–28 (1951)

    Article  Google Scholar 

  11. Jensen, K.A., Pederson, C.: Studies of thioacids and their derivatives. Acta. Chem. Scand. 15, 1087 (1961)

    Article  Google Scholar 

  12. Towbin, H., Staehelin, T., Gordon, J.: Electrophoretic transfer of proteins from polyacrylamide gels to nitrocellulose sheets: procedure and some applications. Proc. Natl. Acad. Sci. USA 76(9), 4350–4354 (1979)

    Article  ADS  Google Scholar 

  13. Moeller, T. (ed.): Inorg. Synth., vol. V. McGraw Hill Book Company (1957)

  14. Lever, A.B.P.: Inorganic Electronic Spectroscopy. Elsevier, Amsterdam (1984)

    Google Scholar 

  15. Nakamoto, K.: Infrared and Raman Spectra of Inorganic and Coordination Compounds. John Wiley & Son (1996)

  16. Singh, N.K., Sharma, U., Agrawal, S., Campbell, M.J.M.: Synthetic, magnetic and spectral studies of iron(III) complexes of thiohydrazides and thiohydrazones. Polyhedron 9(8), 1065–1070 (1990)

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Banaras Hindu University, Varanasi, 221005, India

    N. K. Singh, M. Singh, P. Tripathi & A. K. Srivastava

  2. Department of Chemistry, University of Greenwich, Woolwich, London

    M. J. K. Thomas

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  1. N. K. Singh
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  2. M. Singh
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  3. P. Tripathi
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  4. A. K. Srivastava
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  5. M. J. K. Thomas
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Correspondence to N. K. Singh.

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Singh, N.K., Singh, M., Tripathi, P. et al. Synthesis and spectroscopic investigation of iron(III) complexes of N′-(thioaroyl)pyridine-2-carbohydrazides. Hyperfine Interact 185, 133–137 (2008). https://doi.org/10.1007/s10751-008-9824-4

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  • DOI: https://doi.org/10.1007/s10751-008-9824-4

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