Silicate glasses with additions of cerium and titanium oxides are studied. Such glasses are of interest for manufacturing electric lights for automobile headlights and heat-stable light filters. It is established that the characteristic yellow-orange color is due to the formation chromophoric centers containing products from the interaction of cerium and titanium oxides. It is proposed on the basis of optical transmission and photoluminescence measurements as well as XPES data obtained for the composition used in light filters that titanium and cerium are present predominately as the ions Ti4+, Ce3+, and Ce4+.
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References
I. Kotsik, I. Nebrezhenskii, and I. Fanderlik, Coloring Glass [in Russian], Stroiizdat, Moscow (1983).
G. S. Bogdanov, S. L. Antonova, and B. F. Dzhurinskii, “On the mechanism of coloring of glass by cerium and titanium ions,” Izv. Akad. Nauk SSSR. Cer. Neorg. Mater., 6(5), 944–948 (1970).
W. Xu S. Tang and W. Huang, “Fusion of glasses containing ceria and titania,” J. Non-Cryst. Solids, 112, 186–189 (1989).
E. E. Trusova, N. M. Bobkova, V. S. Gurin, and N. I. Gorbachuk, “Formation of coloring complexes in glasses colored by cerium and titanium oxides,” Steklo Keram., No. 10, 13–17 (2007); E. E. Trusova, N. M. Bobkova, V. S. Gurin, and N. I. Gorbachuk, “Formation of coloring complexes in glass colored with cerium and titanium oxides,” Glass Ceram., 64(9–10), 346–348 (2007).
V. I. Nefedov, Handbook of X-Ray Photoelectron Spectroscopy of Chemical Compounds [in Russian], Khimiya, Moscow (1984).
R. Ya. Khodakovskaya, Chemistry of Titanium-Containing Glasses and Sitals [in Russian], Khimiya, Moscow (1978).
G. O. Karapetyan, “Luminescence of glasses containing cerium,” Izv. Akad. Nauk SSSR, Ser. Fiz., 23(11), 1382–1385 (1959).
V. I. Arbuzov and N. B. Belyankina, “Spectroscopic and photochemical properties of cerium in silicate glass,” Fiz. Khim. Stekla, 16(14), 593–604 (1990).
G. O. Karapetyan, “Effect of oxidation–reduction conditions on the absorption and luminescence spectra of cerium ions in glass,” Opt. Spektrosk., 3(6), 641–645 (1957).
A. I. Leonov, High-Temperature Chemistry of Oxygen Compounds of Cerium [in Russian], Nauka, Leningrad (1969).
V. I. Arbuzov, V. Ya. Grabovskii, and Ya. Ya. Dzenis, “Particulars of the excitation of the luminescence of Ce3+ and Tb3+ ions in silicate glass,” Fiz. Khim. Stekla, 18(2), 96–105 (1992).
T. I. Prokhorova and O. M. Ostrogina, “Spectral-luminescence properties of quartz glasses with cerium,” Fiz. Khim. Stekla, 7(6), 678–685 (1981).
N. Karar and H. Chander, “Luminescence properties of cerium doped nanocrystalline yttrium silicate,” J. Phys.: D, 38, 3580–3583 (2005).
R. Kasuya, T. Isobe, H. Kuma, and J. Katano, “Defect structure of rare earth aluminium garnets obtained by the glycothermal method,” J. Phys. Chem.: B, 109, 22126–22130 (2005).
I. M. Batyaev and A. V. Leonov, “Optical properties of potassium-aluminum-phosphate glass activated by trivalent titanium ions,” Opt. Spektrosk., 99(4), 606–608 (2005).
W. J. Konijnendijk and G. Blasse, “On the luminescence of Ti4+ in Mg5SnB2O10 and Mg3ZrB2O8,” Mater. Chem. Phys., 12, 591–599 (1985).
Yu. A. Teterin, A. Yu. Teterin, A. M. Lebedev, and I. O. Utkin, “Structure of x-ray electron spectra of oxygen-containing cerium compounds,” Radiokhimiya, 40, No. 2, 96–102 (1998).
J. Yao, J. Shao, H. He, and Z. Fan, “Optical and electrical properties of TiO x thin films deposited by electron beam evaporation,” Vacuum, 81, 1023–1028 (2007).
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Translated from Steklo i Keramika, No. 7, pp. 9–13, July, 2009.
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Trusova, E.E., Bobkova, N.M., Gurin, V.S. et al. Nature of color centers in silicate glasses with additions of cerium and titanium oxides. Glass Ceram 66, 240 (2009). https://doi.org/10.1007/s10717-009-9173-z
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DOI: https://doi.org/10.1007/s10717-009-9173-z