Skip to main content
SpringerLink
Log in

Effect of Water on the Modular Structure Conformation of “Polikon K” Material

  • Published:
Fibre Chemistry Aims and scope

This paper presents the developed probabilistic spatial model fragments of the structure of polyacrylonitrile fiber, the monomerization composition (condensing components of the polymer matrix), and “Polikon K” – “Polikon K1a” material. The dynamic contact angle of the investigated material was experimentally determined, and the work of adhesion (1.154 mJ/m2) and wetting (73.855 mJ/m2) of the surface material was calculated. The model of the structure of the “Polikon K1a” material indicates the most likely point of interaction of copolymer polyacrylic fiber with reactive CH3– groups of the polymer matrix, namely, the interaction with the C≡N group, by breaking one bond and forming a methylene bridge. The size of the unit cell of the model was estimated: 10.6 × 10.3 × 9.7 Å. The dependence of the torsion angle near the methylene bridge on the concentration of water molecules was investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. M. M. Kardash, I. A. Tyurin, and D. V. Terin, Khim. Volokna, 4, 43-49 (2012).

    Google Scholar 

  2. D. V. Terin, M. M. Kardash, et al., Khim. Volokna, 5, 36-40 (2014).

    Google Scholar 

  3. D. V. Terin, M. M. Kardash, et al., Khim. Volokna, 2, 28-32 (2015).

    Google Scholar 

  4. ThetaLiteOpticalTensiometerTL100 [electronic resource], www.attension.com.

  5. V. I. Roldugin, Physical Chemistry of Surfaces [in Russian], Intellect, Dolgoprudny (2008), p. 568.

    Google Scholar 

  6. U. Burkert and N. L. Allinger, Molecular Mechanics [in Russian], Mir, Moscow (1986) 364 p.

    Google Scholar 

  7. D. M. Schnur, M. V. Grieshaber, and J. P. Bowen, J. Comput. Chem., 12, No. 7, 844-849 (1991).

    Article  CAS  Google Scholar 

Download references

This work was supported by the Russian Foundation for Basic Research. Project No. 14-08-00766 A.

Author information

Authors and Affiliations

  1. Engels Technological Institute of the Saratov State Technical University named after Yuri Gagarin, Svobody. st., 17, city of Engels, Saratov region, 413100, Russia

    D. V. Terin & M. M. Kardash

  2. Saratov Chernyshevsky State University, Saratov, Russia

    D. V. Terin

  3. Graz University of Technology, Graz, Austria

    L. V. Karpenko-Jereb

Authors
  1. D. V. Terin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. M. Kardash
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. V. Karpenko-Jereb
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Khimicheskie Volokna, No. 6, pp. 39-42, November – December, 2015.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Terin, D.V., Kardash, M.M. & Karpenko-Jereb, L.V. Effect of Water on the Modular Structure Conformation of “Polikon K” Material. Fibre Chem 47, 461–464 (2016). https://doi.org/10.1007/s10692-016-9714-5

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10692-016-9714-5

Keywords

Search

Navigation